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Reading assignments are from the following textbooks:
[SAB] Silbey, R., R. Alberty, and M. Bawendi. Physical Chemistry. New York, NY: John Wiley & Sons, 2004. ISBN: 9780471215042.
[DB] Dill, Ken A., and Sarina Bromberg. Molecular Driving Forces: Statistical Thermodynamics in Chemistry and Biology. New York, NY: Routledge, 2002. ISBN: 9780815320517.
Course readings.
| LEC # |
TOPICS |
READINGS |
| 1 |
Introduction to Thermo; 0th Law; Temperature; Work; Heat |
SAB 1.1-1.4, 1.8-1.9, 2.1 |
| 2 |
State Functions, 1st Law, Paths |
SAB 2.2-2.6 |
| 3 |
Joule and Joule-Thompson; Heat Capacity |
SAB 2.7-2.9 |
| 4 |
Reversible and Irreversible Processes |
SAB 2.10, 3.1 |
| 5 |
Thermochemistry |
SAB 2.11-2.13 |
| 6 |
2nd Law; Entropy (Boltzmann and Clausius) |
SAB 3.2 |
| 7 |
ΔS for Reversible and Irreversible Processes |
SAB 3.3-3.5 |
| 8 |
Equilibrium; Maxwell Relations; Free Energy |
SAB 4.1-4.2, 4.9
DB 8 |
| 9 |
Chemical Potential; Phase Equilibrium |
SAB 4.3-4.4, 4.6-4.7 |
| 10 |
Chemical Equilibrium; Equilibrium Constant |
SAB 5.1-5.4 |
| 11 |
Standard States; Gibbs-Duhem |
SAB 4.8 |
| 12 |
ΔG0= -RTlnK; Example |
SAB 8.1-8.2 |
|
Hour Exam 1 |
|
| 13 |
Boltzmann Distribution |
DB 6
SAB 3.6, 16.1-16.2 |
| 14 |
Thermo and Boltzmann Distribution |
DB 10 (first half) |
| 15 |
Occupation of States |
DB 10 (second half) |
| 16 |
Third Law |
SAB 3.8 |
| 17 |
Phase Equilibria, Single Component |
SAB 6.1-6.2
DB 14 |
| 18 |
Phase Equilibria II; Clausius Clapeyron |
SAB 6.3 |
| 19 |
Regular Solutions; Mixing Energy; Mean Fields |
DB 15
Class notes |
| 20 |
Nonideal Solutions |
|
| 21 |
Solvation; Colligative Properties |
DB 16
Class notes |
|
Hour Exam 2 |
|
| 22 |
Osmotic Pressure and Phase Partitioning |
DB 16 |
| 23 |
Surface Tension |
DB 14 |
| 24 |
Polymer 1 - Freely Jointed Chain |
DB 31 |
| 25 |
Polymer 2 - Chain Conformation |
DB 31 |
| 26 |
Polymer 3 - Rubber Elasticity |
DB 32 |
| 27 |
Electrolyte Solutions |
|
| 28 |
Electrolytes at Interfaces; Debye Length |
Class notes |
| 29 |
Titration of Polyelectrolytes |
Class notes |
| 30 |
Thermodynamics of DNA Hybridization |
Class notes |
| 31 |
Cooperativity |
DB 26 |
|
Hour Exam 3 |
|
| 32 |
Cooperativity, Part 2 |
DB 28 |
| 33 |
Cooperativity, Part 3 |
|
| 34 |
Driving Forces for Self-Assembly |
|
| 35 |
Special Topic (Coarse Grain/Monte Carlo Model) |
|
| 36 |
Course Review and Evaluations |
|