| 1 |
Matrices are useful in spectroscopic theory |
| 2 |
Coupled harmonic oscillators: truncation of an infinite matrix |
| 3 |
Building an effective hamiltonian |
| 4 |
Atoms: 1e- and alkali |
| 5 |
Alkali and many e- atomic spectra |
| 6 |
Many e- atoms |
| 7 |
How to assign an atomic spectrum |
| 8 |
The Born-Oppenheimer approximation |
| 9 |
The Born-Oppenheimer approach to transitions |
| 10 |
The Born-Oppenheimer approach to transitions II |
| 11 |
Pictures of spectra and notation |
| 12 |
Rotational assignment of diatomic electronic spectra I |
| 13 |
Laser schemes for rotational assignment first lines for Ω', Ω" assignments |
| 14 |
Definition of angular momenta and | A α MA >, evaluation of HROT |
| 15 |
2∏ and 2∑ matrices |
| 16 |
Parity and e/f basis for 2∏, 2∑± |
| 17 |
Hund's cases: 2∏, 2∑± examples |
| 18 |
Perturbations |
| 19 |
Second-order effects |
| 20 |
Transformations between basis sets: 3-j, 6-j, and Wigner-Eckart theorem |
| 21 |
Construction of potential curves by the Rydberg-Klein-Rees method (RKR) |
| 22 |
Rotation of polyatomic molecules I |
| 23 |
Asymmetric top |
| 24 |
Pure rotation spectra of polyatomic molecules |
| 25 |
Polyatomic vibrations: normal mode calculations |