| |
Course introduction
|
| 1 |
Vision Statement, Administrative Details - Introduction - Taxonomy of Chemical Species - Origins of Modern Chemistry
|
| 2 |
Classification Schemes for the Elements - Mendeleyev and the Periodic Table - Atomic Structure
|
| 3 |
Rutherford Model of the Atom, Bohr Model of Hydrogen
|
| 4 |
Atomic Spectra of Hydrogen, Matter/Energy Interactions Involving Atomic Hydrogen
|
| 5 |
The Shell Model (Bohr-Sommerfeld Model) and Multi-electron Atoms - Quantum Numbers: n, l, m, s
|
| 6 |
De Broglie, Heisenberg, and Schrödinger - The Aufbau Principle, Pauli Exclusion Principle, and Hund's Rules - Photoelectron Spectroscopy - Average Valence Electron Energy
|
| 7 |
Octet Stability by Electron Transfer: Ionic Bonding - Properties of Ionic Compounds: Crystal Lattice Energy
|
| 8 |
Born-Haber Cycle - Octet Stability by Electron Sharing: Covalent Bonding - Lewis Structures - Hybridization
|
| 9 |
Electronegativity, Partial Charge, Polar Bonds and Polar Molecules - Ionic Character of Covalent Bonds, Pauling's Calculation of Heteronuclear Bond Energies
|
|
Test 1 |
| 10 |
LCAO MO, Energy Level Diagrams for H2, He2, Li2 - Hybridization, Double Bonds and Triple Bonds, Paramagnetism and Diamagetism
|
| 11 |
The Shapes of Molecules, Electron Domain Theory, Secondary Bonding
|
| 12 |
Metallic Bonding, Band Theory of Solids (Heitler and London), Band Gaps in Metals, Semiconductors, and Insulators, Absorption Edge of a Semiconductor
|
| 13 |
Intrinsic and Extrinsic Semiconductors, Doping, Compound Semiconductors, Molten Semiconductors
|
| 14 |
Introduction to the Solid State, the 7 Crystal Systems, the 14 Bravais Lattices
|
| 15 |
Properties of Cubic Crystals: Simple Cubic, Face-centered Cubic, Body-centered Cubic, Diamond Cubic - Crystal Coordinate Systems, Miller Indices
|
| 16 |
Characterization of Atomic Structure: The Generation of X-rays and Moseley's Law
|
| 17 |
X-ray Spectra, Bragg's Law
|
| 18 |
X-ray Diffraction of Crystals: Diffractometry, Debye-Scherrer, Laue - Crystal Symmetry
|
| 19 |
Defects in Crystals: Point Defects, Line Defects, Interfacial Defects, Voids
|
|
Test 2 |
| 20 |
Amorphous Solids, Glass Formation, Inorganic Glasses: Silicates
|
| 21 |
Engineered Glasses: Network Formers, Network Modifiers, Intermediates - Properties of Silicate Glasses - Metallic Glass
|
| 22 |
Chemical Kinetics: The Rate Equation, Order of Reaction, Rate Laws for Zeroth, First, and Second Order Reactions - Temperature Dependence of Rate of Reaction
|
| 23 |
Diffusion: Fick's First Law and Steady-state Diffusion, Dependence of the Diffusion Coefficient on Temperature and on Atomic Arrangement
|
| 24 |
Fick's Second Law (FSL) and Transient-state Diffusion; Error Function Solutions to FSL
|
| 25 |
Solutions: Solute, Solvent, Solution, Solubility Rules, Solubility Product
|
| 26 |
Acids and Bases: Arrhenius, Brønsted-Lowry, and Lewis Definitions, Acid Strength and pH
|
| 27 |
Organic Chemistry: Basic Concepts, Alkanes, Alkenes, Alkynes, Aromatics, Functional Groups, Alcohols and Ethers, Aldehydes and Ketones, Esters, Amines
|
|
Test 3 |
| 28 |
Organic Glasses - Polymers: Synthesis by Addition Polymerization and by Condensation Polymerization
|
| 29 |
Structure-property Relationships in Polymers, Crystalline Polymers
|
| 30 |
Biochemistry: The Amino Acids, Peptides, and Proteins
|
| 31 |
Protein Structure: Primary, Secondary, Tertiary; Denaturing of Proteins
|
| 32 |
Ipids: Self Assembly into Bilayers - Nucleic Acids, DNA, Encoding Information for Protein Synthesis - Electrochemistry of Batteries and Fuel Cells
|
| 33 |
Phase Diagrams - Basic Definitions: Phase, Component, Equilibrium; One-component Phase Diagrams - Two-component Phase Diagrams: Complete Solid Solubility
|
| 34 |
Two-component Phase Diagrams: Limited Solid Solubility - Lever Rule
|
| 35 |
Wrap-up: Closing Remarks about the Course - Student Course Evaluations |
|
Final Exam |