1 00:00:01 --> 00:00:04 The following content is provided by MIT OpenCourseWare 2 00:00:04 --> 00:00:06 under a Creative Commons license. 3 00:00:06 --> 00:00:10 Additional information about our license and MIT 4 00:00:10 --> 00:00:15 OpenCourseWare in general is available at ocw.mit.edu. 5 00:00:15 --> 00:00:17 Great. Well, let's get going. 6 00:00:17 --> 00:00:22 Last time we ended up by discovering the electron. 7 00:00:22 --> 00:00:27 We discovered the fact that the atom was not the most basic 8 00:00:27 --> 00:00:33 constituent of matter. But in 1911 there was another 9 00:00:33 --> 00:00:38 discovery concerning the atom, and this is by Ernest 10 00:00:38 --> 00:00:43 Rutherford in England. And what Rutherford was 11 00:00:43 --> 00:00:49 interested in doing was studying the emission from the newly 12 00:00:49 --> 00:00:54 discovered radioactive elements such as radium. 13 00:00:54 --> 00:00:59 And so he borrowed, or he got, from Marie Curie, 14 00:00:59 --> 00:01:05 some radium bromide. And radium bromide was known to 15 00:01:05 --> 00:01:09 emit something called alpha particles. 16 00:01:09 --> 00:01:14 And they didn't really know what these alpha particles were. 17 00:01:14 --> 00:01:20 Now, they did know that the alpha particles were heavy, 18 00:01:20 --> 00:01:24 they were charged and that they were pretty energetic. 19 00:01:24 --> 00:01:30 That is what was known. Of course, today we know these 20 00:01:30 --> 00:01:34 alpha particles to be nothing other than helium with two 21 00:01:34 --> 00:01:38 electrons removed from the helium, helium double plus. 22 00:01:38 --> 00:01:42 Rutherford is in the lab and has this radium bromide, 23 00:01:42 --> 00:01:47 alpha particles being emitted and has some kind of detector 24 00:01:47 --> 00:01:50 out here to detect those alpha particles. 25 00:01:50 --> 00:01:55 And he measures a rate at which the alpha particles touch his 26 00:01:55 --> 00:02:00 detector. And it is about 132,000 alpha 27 00:02:00 --> 00:02:05 particles per minute. That's nice. 28 00:02:05 --> 00:02:12 Then what he does is takes a piece of gold foil and puts it 29 00:02:12 --> 00:02:19 in between the radium bromide emitter and the detector. 30 00:02:19 --> 00:02:26 And that gold foil is actually really very thin. 31 00:02:26 --> 00:02:32 It is 2x10^-5 inches. Two orders of magnitude thinner 32 00:02:32 --> 00:02:38 than the diameter of your hair. I often wonder how he handled 33 00:02:38 --> 00:02:42 that, but he did it. He put it in the middle here 34 00:02:42 --> 00:02:48 and then went to count the count rate as a result of putting this 35 00:02:48 --> 00:02:54 foil there, and the count rate is 132,000 alpha particles per 36 00:02:54 --> 00:02:57 minute. It didn't seem like that gold 37 00:02:57 --> 00:03:02 foil did anything. The alpha particles were just 38 00:03:02 --> 00:03:05 going right through to the detector. 39 00:03:05 --> 00:03:09 It didn't even seem to matter that there was that gold foil. 40 00:03:09 --> 00:03:13 The post-doc that was working on it, Geiger, 41 00:03:13 --> 00:03:16 of the Geiger Counter, was actually disappointed. 42 00:03:16 --> 00:03:19 Gee, that is a boring experiment. 43 00:03:19 --> 00:03:23 But Geiger was even a little bit more unhappy because he had 44 00:03:23 --> 00:03:27 this undergraduate hanging around the lab, 45 00:03:27 --> 00:03:31 this undergraduate named Marsden. 46 00:03:31 --> 00:03:34 And Marsden was really enthusiastic about doing 47 00:03:34 --> 00:03:37 something in the lab. He really wanted to do 48 00:03:37 --> 00:03:40 something. And Geiger, you know, 49 00:03:40 --> 00:03:42 what am I going to do with this kid? 50 00:03:42 --> 00:03:47 Geiger goes to Rutherford, look, this kid really wants to 51 00:03:47 --> 00:03:50 do something. What should I have him do? 52 00:03:50 --> 00:03:53 And Rutherford said, well, what you should have him 53 00:03:53 --> 00:03:58 do is take this detector and have him build it so that it can 54 00:03:58 --> 00:04:03 be swung around. So that it can be positioned 55 00:04:03 --> 00:04:05 here. So that we can check to see 56 00:04:05 --> 00:04:09 whether or not any of these alpha particles are 57 00:04:09 --> 00:04:12 backscattered, scattered back into the 58 00:04:12 --> 00:04:17 direction from which they came. And Geiger went away and 59 00:04:17 --> 00:04:20 thought, good, this is something to give the 60 00:04:20 --> 00:04:23 undergraduate. This is a ridiculous 61 00:04:23 --> 00:04:27 experiment. We know all the particles are 62 00:04:27 --> 00:04:31 going right through the detector. 63 00:04:31 --> 00:04:33 Okay. But Marsden was real happy. 64 00:04:33 --> 00:04:38 He gets to build this detector. He swings it around and gets 65 00:04:38 --> 00:04:41 Geiger there to do the first experiment. 66 00:04:41 --> 00:04:45 He puts the radium bromide and they listen and hear tick, 67 00:04:45 --> 00:04:48 tick, tick, tick, tick, tick. 68 00:04:48 --> 00:04:50 Geiger says, "Oh, it must just be 69 00:04:50 --> 00:04:53 background. Let me do a control experiment. 70 00:04:53 --> 00:04:58 Let me take the gold foil out of here so that all the 71 00:04:58 --> 00:05:03 particles have to be going in this direction." 72 00:05:03 --> 00:05:07 They take the gold foil out of there and listen, 73 00:05:07 --> 00:05:12 and they hear nothing. They put the gold foil back and 74 00:05:12 --> 00:05:14 they hear tick, tick, tick, tick, 75 00:05:14 --> 00:05:18 tick, tick. And they put a platinum foil in 76 00:05:18 --> 00:05:22 there and they hear tick, tick, tick, tick, 77 00:05:22 --> 00:05:25 tick, tick. Whatever metal they put in 78 00:05:25 --> 00:05:31 there, there were some particles coming off. 79 00:05:31 --> 00:05:35 And they got Rutherford down in the lab. 80 00:05:35 --> 00:05:39 Rutherford looks them over their shoulder. 81 00:05:39 --> 00:05:44 They do this again and again. Hey, it is real. 82 00:05:44 --> 00:05:47 It is real. And what is coming off? 83 00:05:47 --> 00:05:53 Well, the count rate is about 20 particles per minute. 84 00:05:53 --> 00:05:59 Not large but not zero. And the probability here of 85 00:05:59 --> 00:06:05 this backscattering is simply the number of particles 86 00:06:05 --> 00:06:08 backscattered, which is 20, 87 00:06:08 --> 00:06:14 over the total number of particles, or actually the count 88 00:06:14 --> 00:06:19 rate that the particles backscattered over the total 89 00:06:19 --> 00:06:23 incident count rate. That is 2x10^-4. 90 00:06:23 --> 00:06:26 That is not zero. Wow. 91 00:06:26 --> 00:06:32 Rutherford was excited. Rutherford later wrote, 92 00:06:32 --> 00:06:37 "It was quite the most incredible event that has ever 93 00:06:37 --> 00:06:42 happened to me in my life. It was almost as incredible as 94 00:06:42 --> 00:06:48 if you fired a 15 inch shell at a piece of tissue paper and it 95 00:06:48 --> 00:06:53 came back and hit you." What was the interpretation? 96 00:06:53 --> 00:06:59 The interpretation was the gold atoms that make up this foil, 97 00:06:59 --> 00:07:05 they must be mostly empty. Now, they knew that those atoms 98 00:07:05 --> 00:07:10 had some electrons in it because the electron had already been 99 00:07:10 --> 00:07:14 discovered. But these alpha particles seem 100 00:07:14 --> 00:07:19 to be going right through those gold atoms, for the most part. 101 00:07:19 --> 00:07:24 The atom, which he knew to be a diameter of about 10^-10 meters, 102 00:07:24 --> 00:07:30 most of that atom must be empty was the conclusion. 103 00:07:30 --> 00:07:35 But occasionally these helium double plus ions, 104 00:07:35 --> 00:07:40 these alpha particles, hit something massive. 105 00:07:40 --> 00:07:46 And that something massive then scatters those helium ions into 106 00:07:46 --> 00:07:49 the direction from which they came. 107 00:07:49 --> 00:07:55 And since that probability is small, well, the size of this 108 00:07:55 --> 00:08:01 massive part has to be really pretty small. 109 00:08:01 --> 00:08:05 And from knowing the probabilities and knowing 110 00:08:05 --> 00:08:11 roughly what the diameter of the atoms were and how many layers 111 00:08:11 --> 00:08:15 of atoms he had, he was able to back out of 112 00:08:15 --> 00:08:20 those experiments a diameter for this massive part of 10^-14 113 00:08:20 --> 00:08:24 meters. And he called this massive part 114 00:08:24 --> 00:08:28 the nucleus. He called it the nucleus in 115 00:08:28 --> 00:08:33 analogy to the nucleus of a living cell. 116 00:08:33 --> 00:08:36 The heavy part, the dense part in a living 117 00:08:36 --> 00:08:41 cell-- that is where the name "nucleus" comes from. 118 00:08:41 --> 00:08:46 Now, Rutherford also realized that this nucleus here has to be 119 00:08:46 --> 00:08:50 positively charged. He knew about electrons and 120 00:08:50 --> 00:08:55 knew the atoms then were neutral, and so he reasoned this 121 00:08:55 --> 00:09:00 nucleus had to be positively charged. 122 00:09:00 --> 00:09:05 And then he did a bunch more experiments, more sophisticated 123 00:09:05 --> 00:09:10 experiments in which he actually measured here the angular 124 00:09:10 --> 00:09:15 distribution of the helium ion scattered from the nucleus. 125 00:09:15 --> 00:09:20 And from those very detailed measurements of the angular 126 00:09:20 --> 00:09:24 distribution, he was able to back out the 127 00:09:24 --> 00:09:28 fact that this nucleus, the charge on it was actually 128 00:09:28 --> 00:09:34 plus Z times e. Z is the atomic number. 129 00:09:34 --> 00:09:38 e is the unit charge. He did a bunch of different 130 00:09:38 --> 00:09:43 metals and was able to establish that the nucleus had a charge of 131 00:09:43 --> 00:09:48 plus Z times e. His model is that there is a 132 00:09:48 --> 00:09:50 very dense center, 10^-14 meters. 133 00:09:50 --> 00:09:55 This diameter of the nucleus is something that every MIT 134 00:09:55 --> 00:10:01 undergraduate should know. And he realized that then the 135 00:10:01 --> 00:10:05 electrons have to fill out the rest of this volume. 136 00:10:05 --> 00:10:09 That was his interpretation from these results. 137 00:10:09 --> 00:10:14 And think about Marsden, what a great UROP experiment. 138 00:10:14 --> 00:10:17 He discovered the nucleus. Isn't that great? 139 00:10:17 --> 00:10:22 Marsden had a long and successful career as a scientist 140 00:10:22 --> 00:10:26 also after that. Now, I should also tell you 141 00:10:26 --> 00:10:31 that this backscattering experiment is really the essence 142 00:10:31 --> 00:10:36 of how a quark was discovered. Quark are the fundamental 143 00:10:36 --> 00:10:40 elementary particles in protons and neutrons. 144 00:10:40 --> 00:10:42 Essentially, they took a high energy 145 00:10:42 --> 00:10:46 particle, scattered it through the proton or the neutron, 146 00:10:46 --> 00:10:49 and it backscatters. And, in that way, 147 00:10:49 --> 00:10:53 they discovered the quark and measured the diameter of the 148 00:10:53 --> 00:10:55 quark. And this was done by a couple 149 00:10:55 --> 00:11:00 of my colleagues in the Physics Department. 150 00:11:00 --> 00:11:05 Jerry Friedman and Henry Kendall, who has since passed 151 00:11:05 --> 00:11:09 away. Jerry Friedman is still around. 152 00:11:09 --> 00:11:13 He loves to talk to undergraduates, 153 00:11:13 --> 00:11:18 and many of you will get that opportunity. 154 00:11:18 --> 00:11:24 Now it is time for us to do our own Rutherford backscattering 155 00:11:24 --> 00:11:26 experiment. Yeah. 156 00:11:26 --> 00:11:31 [APPLAUSE] Here is our gold lattice. 157 00:11:31 --> 00:11:35 These Styrofoam balls are the gold nuclei. 158 00:11:35 --> 00:11:39 The space around them are the electrons. 159 00:11:39 --> 00:11:44 These things in the center here are just the posts on this 160 00:11:44 --> 00:11:48 frame. [LAUGHTER] This is a piece of 161 00:11:48 --> 00:11:52 equipment from my lab that I pressed into service, 162 00:11:52 --> 00:11:58 and so I couldn't cut these posts away because I would have 163 00:11:58 --> 00:12:04 trouble taking my manipulator out of my machine at a later 164 00:12:04 --> 00:12:08 time. So they are just there. 165 00:12:08 --> 00:12:11 But this is our one monolayer of gold nuclei. 166 00:12:11 --> 00:12:17 And so what are we going to do? Well, what we are going to do 167 00:12:17 --> 00:12:22 is try to measure the diameter of these Styrofoam balls in the 168 00:12:22 --> 00:12:27 same way that Rutherford did. And so we are going to need 169 00:12:27 --> 00:12:34 some alpha particles. What are we going to use for an 170 00:12:34 --> 00:12:39 alpha particle? Well, we have some ping-pong 171 00:12:39 --> 00:12:44 balls for alpha particles. Let's do that. 172 00:12:44 --> 00:12:51 We have 287 alpha particles, or ping-pong balls, 173 00:12:51 --> 00:13:00 and we are going to measure the probability of backscattering. 174 00:13:00 --> 00:13:04 The probability of backscattering will be the 175 00:13:04 --> 00:13:10 number that actually backscatter divided by the number that we 176 00:13:10 --> 00:13:16 throw, or the total number. That is what we are going to 177 00:13:16 --> 00:13:19 measure. But now I have to take this 178 00:13:19 --> 00:13:25 probability and I have to relate it to the diameter of these 179 00:13:25 --> 00:13:30 nuclei. How am I going to do that? 180 00:13:30 --> 00:13:36 Well, that probability is going to be equal to the total surface 181 00:13:36 --> 00:13:42 area of the crystal here. I have already measured the 182 00:13:42 --> 00:13:47 total area. I know that the total area is 183 00:13:47 --> 00:13:52 2,148 square inches. That is in the denominator, 184 00:13:52 --> 00:14:00 but now the numerator is simply the total area of the nuclei. 185 00:14:00 --> 00:14:05 The total area of the nuclei is the area of one nucleus, 186 00:14:05 --> 00:14:09 A sub i, summed over the total number of 187 00:14:09 --> 00:14:13 nuclei, which I have already counted as 119. 188 00:14:13 --> 00:14:19 And so the total area is times the cross-sectional area 189 00:14:19 --> 00:14:25 here of any one of these nuclei. And that is pi d squared over 4. 190 00:14:25 --> 00:14:30 I can solve that equation, 191 00:14:30 --> 00:14:34 for the diameter, in terms of the probability. 192 00:14:34 --> 00:14:40 And when I solve that equation, d is equal to 4.79 times the 193 00:14:40 --> 00:14:45 probability to the one-half power. 194 00:14:45 --> 00:14:50 What we are going to do is measure this probability by 195 00:14:50 --> 00:14:55 throwing the ping-pong balls and calculating and determining how 196 00:14:55 --> 00:15:00 many backscatter. And then we are going to use 197 00:15:00 --> 00:15:05 that to get this diameter of the nuclei. 198 00:15:05 --> 00:15:09 The same experiment that was done to actually measure the 199 00:15:09 --> 00:15:14 diameter of the nucleus. Now you are going to do this 200 00:15:14 --> 00:15:18 experiment. Every one of you are going to 201 00:15:18 --> 00:15:21 get a ping-pong ball from the TAs. 202 00:15:21 --> 00:15:25 TAs, why don't you give out the ping-pong balls, 203 00:15:25 --> 00:15:30 and then I will give you some instructions. 204 00:15:30 --> 00:15:34 All right. The pi d squared over 4 205 00:15:34 --> 00:15:40 is the cross-sectional area in terms of the diameter of 206 00:15:40 --> 00:15:45 these balls. I just wrote it in terms of d 207 00:15:45 --> 00:15:48 instead of r. Yes? 208 00:15:48 --> 00:16:00 209 00:16:00 --> 00:16:02 That is correct. Good point. 210 00:16:02 --> 00:16:06 That balls that we are throwing actually have size compared to 211 00:16:06 --> 00:16:11 in the case of the Rutherford backscattering experiment where 212 00:16:11 --> 00:16:15 the projectile was almost a point compared to the size of 213 00:16:15 --> 00:16:17 the nucleus. In our experiment, 214 00:16:17 --> 00:16:20 you are quite right, our balls are about the 215 00:16:20 --> 00:16:24 diameter there. And so, if we were doing a more 216 00:16:24 --> 00:16:27 exact experiment, we would do a little different 217 00:16:27 --> 00:16:31 calculation. We would take into 218 00:16:31 --> 00:16:37 consideration the size of the actual ball that we were 219 00:16:37 --> 00:16:40 throwing. But we are not going to do 220 00:16:40 --> 00:16:43 that. Because we are not throwing 221 00:16:43 --> 00:16:47 that many balls, we don't really have the 222 00:16:47 --> 00:16:53 statistics to do a more exacting kind of calculation. 223 00:16:53 --> 00:16:57 But you are quite right. Yes? 224 00:16:57 --> 00:17:05 225 00:17:05 --> 00:17:08 Well, he didn't know. Although, he knew the fact that 226 00:17:08 --> 00:17:11 it was backscattering, that it had to be much, 227 00:17:11 --> 00:17:13 much less massive than the nucleus. 228 00:17:13 --> 00:17:18 I think that he also measured the energy of the backscattered 229 00:17:18 --> 00:17:19 particle. And from that, 230 00:17:19 --> 00:17:23 you can back out the fact that it is much less massive than the 231 00:17:23 --> 00:17:26 nucleus. There are a few other details, 232 00:17:26 --> 00:17:29 you are quite right, that I have left out in this 233 00:17:29 --> 00:17:35 discussion that he had to know in order to get this number. 234 00:17:35 --> 00:17:39 Here is the thing. You have to aim your alpha 235 00:17:39 --> 00:17:46 particles at this lattice. And then you have to watch your 236 00:17:46 --> 00:17:50 ball. [LAUGHTER] You have to watch to 237 00:17:50 --> 00:17:56 see if it scatters back at you, because at the end I am going 238 00:17:56 --> 00:18:02 to ask you if your ball backscattered. 239 00:18:02 --> 00:18:07 And we need an accurate count. Now, if you hit one of these 240 00:18:07 --> 00:18:11 things and it backscatters, that doesn't count. 241 00:18:11 --> 00:18:16 Only if it hits the Styrofoam ball does it count. 242 00:18:16 --> 00:18:20 If it hits the Styrofoam ball and goes through, 243 00:18:20 --> 00:18:25 that doesn't count. It literally has to backscatter 244 00:18:25 --> 00:18:30 at you. Was there a question over here? 245 00:18:30 --> 00:18:32 If you miss you miss. [LAUGHTER] Now, 246 00:18:32 --> 00:18:37 I do invite you to come a little closer so that you can at 247 00:18:37 --> 00:18:40 least hit the crystal. Yes? 248 00:18:40 --> 00:18:47 249 00:18:47 --> 00:18:50 That is correct. Well, you have got a defect. 250 00:18:50 --> 00:18:55 These are a little bit lighter. Oh, you have some more here. 251 00:18:55 --> 00:18:57 Oh, okay. You can have a regular one. 252 00:18:57 --> 00:19:01 Anybody need one yet? I have a couple. 253 00:19:01 --> 00:19:03 Oh, all right. You need one? 254 00:19:03 --> 00:19:08 Because I need them all thrown. Did you have a question? 255 00:19:08 --> 00:19:13 256 00:19:13 --> 00:19:15 What is the mean free path? 257 00:19:15 --> 00:19:20 258 00:19:20 --> 00:19:25 That I am going to have to give you an expression for at some 259 00:19:25 --> 00:19:30 other time, but there is certainly a decay pathway. 260 00:19:30 --> 00:19:35 I have another ball here. Now, are you ready? 261 00:19:35 --> 00:19:43 You can come down closer, but now I have one piece of 262 00:19:43 --> 00:19:48 advice for you. That is, only fools aim for 263 00:19:48 --> 00:19:56 their chemistry professor. [LAUGHTER] Go to it. 264 00:19:56 --> 00:20:53 265 00:20:53 --> 00:21:00 Did you throw your balls? You missed the crystal. 266 00:21:00 --> 00:21:05 All right. Has our supply of alpha 267 00:21:05 --> 00:21:11 particles been exhausted? All done? 268 00:21:11 --> 00:21:18 All right. [APPLAUSE] Now comes the big 269 00:21:18 --> 00:21:23 test. How many of you had an alpha 270 00:21:23 --> 00:21:33 particle that backscattered? Let's keep your hand high 271 00:21:33 --> 00:21:37 because I have to count accurately. 272 00:21:37 --> 00:21:42 In this section I see one. Two? 273 00:21:42 --> 00:21:43 Cheater. No. 274 00:21:43 --> 00:21:48 Two, three, four, five, six, seven, 275 00:21:48 --> 00:21:51 eight, nine, ten, eleven, 276 00:21:51 --> 00:21:58 twelve, thirteen. Did I get everybody? 277 00:21:58 --> 00:22:03 278 00:22:03 --> 00:22:04 I got everybody? 13? 279 00:22:04 --> 00:22:09 Right, not deflection. If it hit and went through, 280 00:22:09 --> 00:22:15 that does not count. It has to come back at you. 281 00:22:15 --> 00:22:20 282 00:22:20 --> 00:22:23 Yes. [LAUGHTER] That is right. 283 00:22:23 --> 00:22:27 All right. Does anybody want to change 284 00:22:27 --> 00:22:30 their count? 13 balls? 285 00:22:30 --> 00:22:34 I am sorry? If it just hit it and moved but 286 00:22:34 --> 00:22:38 did not backscatter, it does not count. 287 00:22:38 --> 00:22:43 The nuclei will move. They will move, 288 00:22:43 --> 00:22:48 certainly, because there is a momentum transfer. 289 00:22:48 --> 00:22:51 Well, not quite like that. No. 290 00:22:51 --> 00:22:55 We have 13 balls that backscattered? 291 00:22:55 --> 00:23:00 Okay. Let's see what we got. 292 00:23:00 --> 00:23:05 293 00:23:05 --> 00:23:13 The probability, here, then, is 13 over 287. 294 00:23:13 --> 00:23:16 That probability is equal to 295 00:23:17 --> 00:23:18 296 00:23:19 --> 00:23:29 If I now that this probability and plug it into here, 297 00:23:29 --> 00:23:40 what we are going to get is a diameter of 1.0 inches. 298 00:23:40 --> 00:23:48 And the diameter on the average of those particles is about 0.85 299 00:23:48 --> 00:23:52 inches. You did a really pretty good 300 00:23:52 --> 00:23:56 job. You got the diameter of the 301 00:23:56 --> 00:24:00 nucleus. [APPLAUSE] 302 00:24:00 --> 00:24:04 That is great. And that is the way the nuclear 303 00:24:04 --> 00:24:07 diameter was, in fact, measured and 304 00:24:07 --> 00:24:11 discovered. But now we have the problem 305 00:24:11 --> 00:24:16 that the scientists had in 1912, and that is what is the 306 00:24:16 --> 00:24:21 structure of the atom? We now know it has a nucleus. 307 00:24:21 --> 00:24:25 It has an electron. How do they hang together? 308 00:24:25 --> 00:24:31 Where are they in the atom? We are going to talk about the 309 00:24:31 --> 00:24:35 classical description here of the atom. 310 00:24:35 --> 00:24:39 And the first question that we have to ask is, 311 00:24:39 --> 00:24:45 what is the force that keeps the electron and the nucleus 312 00:24:45 --> 00:24:49 together? What are the four fundamental 313 00:24:49 --> 00:24:51 forces? Gravity is one. 314 00:24:51 --> 00:24:55 And that is the strongest or the weakest? 315 00:24:55 --> 00:24:56 Weakest. Gravity. 316 00:24:56 --> 00:25:01 Next stronger force? Electromagnetic. 317 00:25:01 --> 00:25:05 I will just abbreviate it EM. Next stronger force? 318 00:25:05 --> 00:25:06 Weak force. And the next? 319 00:25:06 --> 00:25:08 Strong. Weak and strong are 320 00:25:08 --> 00:25:12 intranuclear forces. They are operable between the 321 00:25:12 --> 00:25:17 protons, the neutrons and the other elementary particles that 322 00:25:17 --> 00:25:20 make up the nucleus. It does not have a lot of 323 00:25:20 --> 00:25:24 effect, the weak and the strong force, on chemistry, 324 00:25:24 --> 00:25:30 except for beta emission for the radioactive elements. 325 00:25:30 --> 00:25:36 Gravity actually does have no known chemical significance to 326 00:25:36 --> 00:25:40 chemistry. And so all of chemistry is tied 327 00:25:40 --> 00:25:45 up here in the electromagnetic force, which I am, 328 00:25:45 --> 00:25:50 at the moment, going to simplify and just call 329 00:25:50 --> 00:25:55 the Coulomb force. Now, we know how to describe 330 00:25:55 --> 00:26:01 the Coulomb force between charged particles. 331 00:26:01 --> 00:26:03 We know what expression to write down. 332 00:26:03 --> 00:26:06 Let's do that. If we have the nucleus, 333 00:26:06 --> 00:26:09 which is positively charged, and the electron here, 334 00:26:09 --> 00:26:13 which is negatively charged, and they are at some distance r 335 00:26:13 --> 00:26:16 between each other, the expression that describes 336 00:26:16 --> 00:26:20 how that force of interaction changes with distance, 337 00:26:20 --> 00:26:24 this Coulomb's force law, it is just the magnitude of the 338 00:26:24 --> 00:26:28 charge of the electron times the magnitude of the charge on the 339 00:26:28 --> 00:26:31 nucleus over 4 pi epsilon nought times r squared. 340 00:26:31 --> 00:26:36 341 00:26:36 --> 00:26:40 I am going to just treat the force as a scalar, 342 00:26:40 --> 00:26:43 just for simplicity purposes here. 343 00:26:43 --> 00:26:47 Epsilon nought is the permittivity of vacuum. 344 00:26:47 --> 00:26:51 It is a factor in there for unit conversation. 345 00:26:51 --> 00:26:56 r, then, is the distance between the electron and the 346 00:26:56 --> 00:27:00 nucleus. What does this say? 347 00:27:00 --> 00:27:03 Well, this says that when r goes to infinity, 348 00:27:03 --> 00:27:06 what is the force? Zero. 349 00:27:06 --> 00:27:09 The particles are infinitely far apart. 350 00:27:09 --> 00:27:13 There is no force between them. In this case, 351 00:27:13 --> 00:27:16 an attractive force between them. 352 00:27:16 --> 00:27:20 When r is equal to zero, what is the force? 353 00:27:20 --> 00:27:23 Infinite. And anywhere in between, 354 00:27:23 --> 00:27:28 that force is described by this one over r squared 355 00:27:28 --> 00:27:33 dependence. You can see that as the 356 00:27:33 --> 00:27:39 particles come closer and closer together, the force between them 357 00:27:39 --> 00:27:42 gets larger and larger. The closer they get, 358 00:27:42 --> 00:27:47 the larger the force, the more they want to be 359 00:27:47 --> 00:27:50 together. This expression is just telling 360 00:27:50 --> 00:27:56 me, if I held one particle and the other particle in my hand, 361 00:27:56 --> 00:28:02 and I held them at some distance from each other -- 362 00:28:02 --> 00:28:06 That expression is just telling me the force with which I have 363 00:28:06 --> 00:28:09 to kind of exert to keep them apart. 364 00:28:09 --> 00:28:14 But now, if I let them go, you know what is going to 365 00:28:14 --> 00:28:16 happen. They are going to come 366 00:28:16 --> 00:28:19 together. They are going to want to come 367 00:28:19 --> 00:28:23 together because of that force. And what is not in this 368 00:28:23 --> 00:28:27 expression? What is not in that expression 369 00:28:27 --> 00:28:31 is any information about how those particles move under 370 00:28:31 --> 00:28:37 influence of that force. Nowhere in this expression is 371 00:28:37 --> 00:28:42 there an r of t, how that distance changes with 372 00:28:42 --> 00:28:45 time. And so what we need to describe 373 00:28:45 --> 00:28:48 that is a force law. And in 1911, 374 00:28:48 --> 00:28:52 the force law that seemed to describe the motion of all 375 00:28:52 --> 00:28:56 bodies, including astronomical ones, of course, 376 00:28:56 --> 00:29:01 the equation of motion that described how bodies move are 377 00:29:01 --> 00:29:06 Newton's equations of motion. And, in particular, 378 00:29:06 --> 00:29:09 F equals ma. And, of course, 379 00:29:09 --> 00:29:13 I can write that acceleration as a time derivative of the 380 00:29:13 --> 00:29:16 velocity, dv over dt. 381 00:29:16 --> 00:29:19 And that velocity, of course, itself is a change 382 00:29:19 --> 00:29:22 in the position with respect to time. 383 00:29:22 --> 00:29:26 This is m, the second derivative of r with respect to 384 00:29:26 --> 00:29:30 time. 385 00:29:30 --> 00:29:34 If I know the force that is operation, which is this, 386 00:29:34 --> 00:29:39 I can take this and plug it in here, and I am going to have a 387 00:29:39 --> 00:29:44 differential equation. And that differential equation 388 00:29:44 --> 00:29:49 is going to allow me to solve for what r is as a function of 389 00:29:49 --> 00:29:53 time, the distance between the two particles. 390 00:29:53 --> 00:29:58 And it is going to allow me to solve for that distance in a way 391 00:29:58 --> 00:30:03 that we call deterministic, exactly. 392 00:30:03 --> 00:30:06 In other words, if I know where the particles 393 00:30:06 --> 00:30:11 are to start with, using this equation of motion, 394 00:30:11 --> 00:30:14 this force law, I can tell you where those 395 00:30:14 --> 00:30:19 particles are going to be for all future time exactly. 396 00:30:19 --> 00:30:23 It is deterministic, the classical mechanical 397 00:30:23 --> 00:30:26 approach. Now, in order to solve this 398 00:30:26 --> 00:30:31 differential equation, I am going to have to develop a 399 00:30:31 --> 00:30:36 model for the atom. All differential equations, 400 00:30:36 --> 00:30:40 for the most part, describing physical processes 401 00:30:40 --> 00:30:44 are going to need a model. They are going to need some 402 00:30:44 --> 00:30:48 boundary conditions or initial conditions. 403 00:30:48 --> 00:30:52 And the model, of course, that came to mind 404 00:30:52 --> 00:30:55 for the atom, is one in which the nucleus is 405 00:30:55 --> 00:31:00 in the center. And the electron moves around 406 00:31:00 --> 00:31:06 that nucleus with uniform circular motion and with a fixed 407 00:31:06 --> 00:31:09 radius. We are going to call that fixed 408 00:31:09 --> 00:31:14 radius r star. It is a planetary model. 409 00:31:14 --> 00:31:19 That seems like a good guess for the structure of the atom. 410 00:31:19 --> 00:31:25 Now, if you have a particle undergoing uniform circular 411 00:31:25 --> 00:31:30 motion at some well-defined radius here. 412 00:31:30 --> 00:31:34 That particle is being constantly accelerated. 413 00:31:34 --> 00:31:40 And I can write that acceleration a as the linear 414 00:31:40 --> 00:31:45 velocity squared over that radius of its orbit. 415 00:31:45 --> 00:31:51 It is being accelerated because the velocity 416 00:31:51 --> 00:31:55 vector. The direction is changing, 417 00:31:55 --> 00:32:00 so there is a constant acceleration. 418 00:32:00 --> 00:32:02 Now, this expression, for many of you, 419 00:32:02 --> 00:32:06 I pulled out of the air. Some of you have seen it 420 00:32:06 --> 00:32:08 before. It is an 8.01 topic. 421 00:32:08 --> 00:32:13 You are going to see it this semester, but later on and in 422 00:32:13.406 --> 8.01. 423 8.01. --> 00:32:15 You are not responsible for 424 00:32:15 --> 00:32:19 this right now here, but you will recall later on 425 00:32:19 --> 00:32:23 this semester that you have seen it here in 5.112. 426 00:32:23 --> 00:32:26 But, if this is the acceleration, 427 00:32:26 --> 00:32:30 I can take this expression for the acceleration and plug it 428 00:32:30 --> 00:32:36 into here. Plug in my operating force law. 429 00:32:36 --> 00:32:42 And, in so doing, I am going to get -- 430 00:32:42 --> 00:32:50 431 00:32:50 --> 00:32:56 -- e squared over 4 pi epsilon nought r star squared. 432 00:32:56 --> 00:33:00 433 00:33:00 --> 00:33:04 That is the F. Mass times the acceleration, 434 00:33:04 --> 00:33:09 m times v squared over r star. That is my equation of motion 435 00:33:09 --> 00:33:14 particular to this problem of a planetary model. 436 00:33:14 --> 00:33:20 And now I can solve that for v squared, the linear velocity of 437 00:33:20 --> 00:33:23 that electron going around the nucleus. 438 00:33:23 --> 00:33:29 That comes out to be e squared over 4 pi epsilon nought m r 439 00:33:29 --> 00:33:34 star. 440 00:33:34 --> 00:33:39 Now, the reason I wanted to calculate the velocity squared 441 00:33:39 --> 00:33:44 here is because I want to calculate kinetic energy. 442 00:33:44 --> 00:33:47 And that is easy to do. Kinetic energy, 443 00:33:47 --> 00:33:51 I will call K, is one-half m times v squared. 444 00:33:51 --> 00:33:57 If I plug in the v squared right in there, 445 00:33:57 --> 00:34:03 I get one-half e squared over 4 pi epsilon nought r star. 446 00:34:03 --> 00:34:10 So far, everything looks okay. 447 00:34:10 --> 00:34:15 We have a planetary model. Coulomb's law is operable. 448 00:34:15 --> 00:34:21 We know the acceleration. We just calculated the kinetic 449 00:34:21 --> 00:34:26 energy of this electron going around the nucleus. 450 00:34:26 --> 00:34:33 What I want to do now is I want to know the total energy of the 451 00:34:33 --> 00:34:37 system. I just calculated the kinetic 452 00:34:37 --> 00:34:42 energy of the system, but I want to know the total 453 00:34:42 --> 00:34:47 energy of the system. And the total energy of the 454 00:34:47 --> 00:34:52 system, I am going to call this capital E, total energy, 455 00:34:52 --> 00:34:58 is the kinetic energy plus the potential energy. 456 00:34:58 --> 00:35:02 And I want the total energy of the system for two reasons. 457 00:35:02 --> 00:35:06 One is I want to show you that the system is bound, 458 00:35:06 --> 00:35:10 that the total energy is going to be negative, 459 00:35:10 --> 00:35:15 that it is lower than the total energy when the electron and the 460 00:35:15 --> 00:35:19 nucleus are separated. I want to show you that within 461 00:35:19 --> 00:35:23 this classical model, the electron and the nucleus do 462 00:35:23 --> 00:35:26 look bound. To do that, I need to show you 463 00:35:26 --> 00:35:32 the total energy is negative. To do that, I need to calculate 464 00:35:32 --> 00:35:36 the potential energy. That is what I want to do. 465 00:35:36 --> 00:35:41 Secondly, I want to get an expression for the total energy. 466 00:35:41 --> 00:35:47 Because, using that expression, I am going to show you how this 467 00:35:47 --> 00:35:51 classical mechanics fails. How Newton's equations of 468 00:35:51 --> 00:35:55 motion won't work to describe this problem. 469 00:35:55 --> 00:36:01 Now, I have run out of time. I will do that on Monday, 470 00:36:01 --> 00:36:04 but that is where we are going. All right. 471 00:36:04.892 --> 36:07 See you on Monday.