Pages
Unless otherwise noted, problems assigned by number refer to corresponding problems in the course text: Tester, J. W., and Modell, Michael. Thermodynamics and Its Applications. Upper Saddle River, NJ: Prentice Hall PTR, 1996. ISBN: 9780139153563.
Session numbers indicate due dates for problem sets.
SES # | TOPICS | PROBLEM SETS |
---|---|---|
3 | 1st Law Open Systems | Problem Set 1 (PDF) |
7 | 1st and 2nd Laws Open and Closed Systems | Problem Set 2 (PDF) |
11 | Availability and Calculus of Thermodynamics | Problem Set 3 (PDF) |
17 | Legendre Transforms, Phase Rule, Equilibrium and Stability Criteria | Problem Set 4 (PDF) |
19 | Pure Fluid Properties Coupled to 1st and 2nd Laws, Fugacity, Activity, Gibbs-Duhem |
Problem Set 5 (PDF)
Problem Set 5 Addendum (PDF) |
27 | Introduction to Statistical Mechanics | Problem Set 6 (PDF) |
31 | Intermolecular Forces and Classical Statistical Mechanics | Problem Set 7 (PDF) |
35 | Fluid Property Models from Statistical Mechanics - Virial and VDW EOS, Fluctuations and Light Scattering | Problem Set 8 (PDF) |
37 |
Molecular Simulation Fluid Properties from Statistical Mechanics Departure Functions |
Problem Set 9 (PDF) |
45 | Phase Equilibria | Problem Set 10 (PDF) |
47 | Phase and Chemical Equilibria | Problem Set 11 (PDF) |
SES # | TOPICS | KEY DATES |
---|---|---|
Part I - Fundamental Principles | ||
1 | Course Outline; Motivation to Connect Classical Concepts and Laws to Physical Properties from Macroscopic to Molecular; Definitions; Nomenclature; Exams Plus Homework Policy; Approach to Solving Problems; Constitutive Property Models and the Ideal Gas State; Postulatory Approach; 1st Law Concepts | |
2 |
Postulatory Approach 1st Law Concepts (Work, Heat, and Energy); Closed and Open System Treatments, Including PE Plus KE Effects; Tank Blowdown [Demo - CO2 Fire Extinguisher] |
|
3 | 1st Law Open Systems; Tank Blowdown and Filling - Class Examples; Problem 3.9 | Assignment 1 due |
4 | 2nd Law Concepts; Reversible Heat Engines; Carnot Efficiency; Entropy; Clausius Theorem; Reversibility [Demo - Drinking Bird] | |
5 | Entropy Balance; 1st and 2nd Laws Combined [Demo - Hilsch Vortex Tube] | |
6 | 2nd Law Concepts and Applications; Steady State and Transient Flow Work | |
7 | Availability and Exergy Concepts; Heat Integration and Pinch Analysis; Power Cycle Analysis [Demo - Stirling Engine] | Assignment 2 due |
8 | Calculus of Thermodynamics; Gibbs Fundamental Equation; Graphical Interpretation of Fundamental Surface | |
9 | Derivative Transformation and Manipulation; Maxwell Relations; Jacobian Transformations | |
10 | Legendre Transformations; Equivalent Forms of the Fundamental Equation; Examples | |
11 | Legendre Transforms Continued; Connections to the Gibbs Surface and Other Derived Properties | Assignment 3 due |
12 | Equilibrium Criteria Concepts and Applications - Phase, Chemical, and Membrane; Phase Rule; Examples of Simple Phase Diagrams | |
13 | Stability Criteria, Concepts and Applications; Critical States | |
14 | Pure Component Properties; Fundundamental Equation; Theorem of Corresponding States; Constitutive Property Models - Stress Connections to Molecular Level Interactions and Effects | |
15 | Real Fluid Properties; PVTN Equations of State; Ideal Gas Heat Capacity Cp* | |
16 | Departure Functions; Concepts and Applications; Standard Δ_G°_ and Δ_H°_ of Formation | |
17 | Mixtures; PVTN EOSs; Partial Molar Properties; Gibbs-Duhem Relation; Mixing Functions; Discuss Problem 9.2; Ideal Gas Mixtures and Ideal Solutions; Fugacity and Fugacity Coefficients; Standard States | Assignment 4 due |
18 | Ideal Solution Conditions; Excess Properties; Activity and Activity Coefficients; ΔGEX-γi Models (See Table 11.1); Standard States; Thermodynamic Consistency using the Gibbs-Duhem Relation | |
19 | Mixture Equations of State, Continued and Needs | Assignment 5 due |
20 | Review for Exam 1 | |
Exam I: 2 hours | ||
Part II - Introduction to Statistical Mechanics for the Interpretation of Thermodynamic Functions and the Computation of Thermodynamic Properties | ||
21 | Fundamental Principles of Quantum and Classical Statistical Mechanics - N-body Problem; Phase Space; Statistics and Distribution Functions and Averaging Methods; Boltzmann Distribution | |
22 | Postulates of Statistical Mechanics; Gibbs Ensembles - Micro-canonical and Canonical; States of System; Probabilities | |
23 | Computation of Ideal Gas Properties from Intramolecular Effects - Translation, Rotation, Vibration using Statistical Mechanics I | |
24 | Computation of Ideal Gas Properties from Intramolecular Effects - Translation, Rotation, Vibration using Statistical Mechanics II | |
25 | Classical Statistical Mechanics; Hamiltonian and Ideal Gases; Factoring the Partition Function with the Semi-classical Approximation; PVTN Properties via Configuration Integral from Intermolecular Effects; Grand Canonical Ensemble I | |
26 | Semi-classical Approximation; PVTN Properties via Configuration Integral from Intermolecular Effects; Grand Canonical Ensemble II - Examples | |
27 | Gibbs Ensembles Continued: Micro-canonical Ensemble Revisited, Grand Canonical, NPT, etc., Including Equivalence of Ensembles; Time Averaging and Ergodicity, and Fluctuations; Macroscopic Connection | Assignment 6 due |
28 | Intermolecular Forces and Potentials; Role of Quantum Mechanics; Commonly used Potential Functions; Pairwise Additivity | |
29 | Virial Equation of State and Molecular Corresponding States from Statistical Mechanics; Connection of PVTN Equations of State to Statistical Mechanics and Molecular Simulations | |
30 | Mean Field Theory; Connecting the van der Waals EOS Model to Statistical Mechanics; Hard Sphere Fluids; Perturbed Hard Sphere Fluids; Lattice Models | |
31 | Statistical Mechanical Models of Fluids I - Expanding the Virial EOS to Mixtures; Radial Distribution Functions; Structure of Fluid and Solid Phases; Critical Phenomena (Fluctuations, Critical Opalescence) | Assignment 7 due |
32 | Statistical Mechanical Models of Fluids II - Biological Materials and Protein Applications | |
33 | Foundations of Molecular Simulations - Monte Carlo and Molecular Dynamics | |
34 | Application of Molecular Simulations to Estimating Pure Component and Mixture Properties | |
Part III - Multi-scale Thermodynamics of Pure Fluids and Mixtures - Physical Properties and Phase and Chemical Equilibria | ||
35 | Calculation of Pure Component Properties (Vapor Pressure, Δ Hvap, … etc.) Using Equation of State and Other Models - Departure Functions | Assignment 8 due |
36 | Review of Mixture Thermodynamics; Fugacity; Fugacity Coefficient; Activity; Activity Coefficient; Standard States and Constitutive Models for Capturing Non-Ideal Effects | |
37 | Phase Equilibrium and Stability - Gibbs Phase Rule; Phase Diagrams; Using Constitutive Property Models for Capturing Non-Ideal Effects | Assignment 9 due |
38 | Applications of Mixture Thermodynamics to VLE Phase Equilibria; Minimum Work of Separation, etc. | |
39-40 |
_Review for Exam II
_Review of Statistical Mechanics Principles and Applications, and Pure Fluid and Mixture Properties |
|
Exam II: 2 hours | ||
41 | Phase Equilibria; Differential Approach; Constitutive Property Models Continued; P-T Relationships | |
42 | Phase Equilibria; Integral Approach; Applications; Solubility - Gas - Liquid, Liquid - Liquid, and Solid - Liquid Systems | |
43 | Phase Equilibria Applications - Examples Colligative Properties; Ternary Diagrams; S-L-V Three Phase Monovariant Binary Equilibria; Biological Examples | |
44 | Phase Stability Applications; Spinodal Decomposition; Critical Points; Uses of Equations of State and Gibbs Free Energy Models; Polymer and Materials Examples; Pictures of Crystalization | |
45 | Chemical Equilibrium - General Approach; Nonstoichiometric and Stoichiometric Formulation; Statistical Mechanical Approach | Assignment 10 due |
46 | Equilibrium Constants and Standard States; Gibbs Phase Rule Applications | |
47 | Chemical Equilibria Applications and Example Problems; Combined Phase and Chemical Equilbria | Assignment 11 due |
48 | Review Session | |
Final Exam: 3 hours |
Chapter readings in the table are from the course text, Tester, J. W., and Modell, Michael. Thermodynamics and Its Applications. Upper Saddle River, NJ: Prentice Hall PTR, 1996. ISBN: 9780139153563.
A bibliography of supplementary readings is included below the table.
SES # | TOPICS | READINGS |
---|---|---|
Part I - Fundamental Principles | ||
1 | Course Outline; Motivation to Connect Classical Concepts and Laws to Physical Properties from Macroscopic to Molecular; Definitions; Nomenclature; Exams Plus Homework Policy; Approach to Solving Problems; Constitutive Property Models and the Ideal Gas State; Postulatory Approach; 1st Law Concepts | Handouts |
2 |
Postulatory Approach 1st Law Concepts (Work, Heat, and Energy); Closed and Open System Treatments, Including PE Plus KE Effects; Tank Blowdown [Demo - CO2 Fire Extinguisher] |
1 (all sections), 2 (all sections), 3.1-3.8 |
3 | 1st Law Open Systems; Tank Blowdown and Filling - Class Examples; Problem 3.9 | 3.7-3.9 |
4 | 2nd Law Concepts; Reversible Heat Engines; Carnot Efficiency; Entropy; Clausius Theorem; Reversibility [Demo - Drinking Bird] | 4.1-4.5 |
5 | Entropy Balance; 1st and 2nd Laws Combined [Demo - Hilsch Vortex Tube] | 4.6-4.7 |
6 | 2nd Law Concepts and Applications; Steady State and Transient Flow Work | 4.8-4.9 |
7 | Availability and Exergy Concepts; Heat Integration and Pinch Analysis; Power Cycle Analysis [Demo - Stirling Engine] | 14.1-14.3, 14.5-14.6 |
8 | Calculus of Thermodynamics; Gibbs Fundamental Equation; Graphical Interpretation of Fundamental Surface |
5.1-5.4
Thermodynamic Properties of Pure Materials (PDF) |
9 | Derivative Transformation and Manipulation; Maxwell Relations; Jacobian Transformations | 5.1-5.4 |
10 | Legendre Transformations; Equivalent Forms of the Fundamental Equation; Examples | 5.5-5.7 |
11 | Legendre Transforms Continued; Connections to the Gibbs Surface and Other Derived Properties | 5.5-5.7 |
12 | Equilibrium Criteria Concepts and Applications - Phase, Chemical, and Membrane; Phase Rule; Examples of Simple Phase Diagrams | 6.1-6.7 |
13 | Stability Criteria, Concepts and Applications; Critical States | 7.1-7.2 |
14 | Pure Component Properties; Fundundamental Equation; Theorem of Corresponding States; Constitutive Property Models - Stress Connections to Molecular Level Interactions and Effects | 8.1-8.2 |
15 | Real Fluid Properties; PVTN Equations of State; Ideal Gas Heat Capacity Cp* | 8.3-8.4 |
16 | Departure Functions; Concepts and Applications; Standard Δ_G°_ and Δ_H°_ of Formation | 8.5, 8.7-8.9 |
17 | Mixtures; PVTN EOSs; Partial Molar Properties; Gibbs-Duhem Relation; Mixing Functions; Discuss Problem 9.2; Ideal Gas Mixtures and Ideal Solutions; Fugacity and Fugacity Coefficients; Standard States | 9.1-9.7 |
18 | Ideal Solution Conditions; Excess Properties; Activity and Activity Coefficients; Δ_GEX_-γi Models (See Table 11.1); Standard States; Thermodynamic Consistency using the Gibbs-Duhem Relation | 9.8, 11.2, 11.4, 11.7, 11.9 |
19 | Mixture Equations of State, Continued and Needs | 11.7, 11.9 |
20 | Review for Exam 1 | |
Exam I: 2 hours | ||
Part II - Introduction to Statistical Mechanics for the Interpretation of Thermodynamic Functions and the Computation of Thermodynamic Properties | ||
21 | Fundamental Principles of Quantum and Classical Statistical Mechanics - N-body Problem; Phase Space; Statistics and Distribution Functions and Averaging Methods; Boltzmann Distribution |
10.1, handouts
Fundamental Principles of Quantum and Classical Statistical Mechanics (PDF) |
22 | Postulates of Statistical Mechanics; Gibbs Ensembles - Micro-canonical and Canonical; States of System; Probabilities |
10.1, handouts
Postulates of Statistical Mechanics, Gibbs Ensembles (PDF) |
23 | Computation of Ideal Gas Properties from Intramolecular Effects - Translation, Rotation, Vibration using Statistical Mechanics I |
10.1, handouts
Computation of the Properties of Ideal Gases (PDF) |
24 | Computation of Ideal Gas Properties from Intramolecular Effects - Translation, Rotation, Vibration using Statistical Mechanics II |
10.1, handouts
Computation of the Properties of Ideal Gases (PDF) Appendix to Session 21-24 Statistical Mechanics Readings: Connection to Thermodynamics and Derivation of Boltzmann Distribution (PDF) |
25 | Classical Statistical Mechanics; Hamiltonian and Ideal Gases; Factoring the Partition Function with the Semi-classical Approximation; PVTN Properties via Configuration Integral from Intermolecular Effects; Grand Canonical Ensemble I | 10.1, handouts |
26 | Semi-classical Approximation; PVTN Properties via Configuration Integral from Intermolecular Effects; Grand Canonical Ensemble II - Examples | 10.1, handouts |
27 | Gibbs Ensembles Continued: Micro-canonical Ensemble Revisited, Grand Canonical, NPT, etc., Including Equivalence of Ensembles; Time Averaging and Ergodicity, and Fluctuations; Macroscopic Connection | 10.1, handouts |
28 | Intermolecular Forces and Potentials; Role of Quantum Mechanics; Commonly used Potential Functions; Pairwise Additivity | 10.2-10.3 |
29 | Virial Equation of State and Molecular Corresponding States from Statistical Mechanics; Connection of PVTN Equations of State to Statistical Mechanics and Molecular Simulations | 10.4-10.6 |
30 | Mean Field Theory; Connecting the van der Waals EOS Model to Statistical Mechanics; Hard Sphere Fluids; Perturbed Hard Sphere Fluids; Lattice Models | 10.6, 10.8 |
31 | Statistical Mechanical Models of Fluids I - Expanding the Virial EOS to Mixtures; Radial Distribution Functions; Structure of Fluid and Solid Phases; Critical Phenomena (Fluctuations, Critical Opalescence) | 10.7 |
32 | Statistical Mechanical Models of Fluids II - Biological Materials and Protein Applications | 10.7 |
33 | Foundations of Molecular Simulations - Monte Carlo and Molecular Dynamics | 10.9 |
34 | Application of Molecular Simulations to Estimating Pure Component and Mixture Properties | 10.9 |
Part III - Multi-scale Thermodynamics of Pure Fluids and Mixtures - Physical Properties and Phase and Chemical Equilibria | ||
35 | Calculation of Pure Component Properties (Vapor Pressure, Δ Hvap, … etc.) Using Equation of State and Other Models - Departure Functions | 8.5, 8.7, 8.9 |
36 | Review of Mixture Thermodynamics; Fugacity; Fugacity Coefficient; Activity; Activity Coefficient; Standard States and Constitutive Models for Capturing Non-Ideal Effects | 9.1-9.8 |
37 | Phase Equilibrium and Stability - Gibbs Phase Rule; Phase Diagrams; Using Constitutive Property Models for Capturing Non-Ideal Effects | 15.1-15.2, 15.8 |
38 | Applications of Mixture Thermodynamics to VLE Phase Equilibria; Minimum Work of Separation, etc. | 9.7-9.9, 11.4, 11.7, 11.9 |
39-40 |
_Review for Exam II
_Review of Statistical Mechanics Principles and Applications, and Pure Fluid and Mixture Properties |
|
Exam II: 2 hours | ||
41 | Phase Equilibria; Differential Approach; Constitutive Property Models Continued; P-T Relationships | 15.3-15.4, 11.1-11.7 |
42 | Phase Equilibria; Integral Approach; Applications; Solubility - Gas - Liquid, Liquid - Liquid, and Solid - Liquid Systems | 15.5 |
43 | Phase Equilibria Applications - Examples Colligative Properties; Ternary Diagrams; S-L-V Three Phase Monovariant Binary Equilibria; Biological Examples | |
44 | Phase Stability Applications; Spinodal Decomposition; Critical Points; Uses of Equations of State and Gibbs Free Energy Models; Polymer and Materials Examples; Pictures of Crystalization | 7.1-7.2, 15.6-15.7 |
45 | Chemical Equilibrium - General Approach; Nonstoichiometric and Stoichiometric Formulation; Statistical Mechanical Approach | 16.1-16.4, 16.9 |
46 | Equilibrium Constants and Standard States; Gibbs Phase Rule Applications | 16.5-16.6 |
47 | Chemical Equilibria Applications and Example Problems; Combined Phase and Chemical Equilbria | 17.1-17.3 |
48 | Review Session | |
Final Exam: 3 hours |
Supplementary References*
Classical Thermodynamics
Bejan, Adrian. Advanced Engineering Thermodynamics. New York: Wiley, 1988. ISBN: 9780471830436. [Graduate Level, mechanical engineering emphasis, generalized exergy/availability analysis].*
Bett, K. E., Rowlinson, J. S., and Saville, G. Thermodynamics for Chemical Engineers. Cambridge, MA: The MIT Press, 1975. ISBN: 9780262523981. [General text from a Chemical Engineering perspective].
Callen, Herbert B. Thermodynamics: An Introduction to the Physical Theories of Equilibrium Thermostatistics and Irreversible Thermodynamics. New York: Wiley, 1960. Reprint available: Temecula, CA: Textbook Publishers, 2003. ISBN: 0758103360. [Physics approach, recommended section on Legendre transformations].*
Denbigh, Kenneth. Principles of Chemical Equilibrium. 4th ed. London: Cambridge University Press, 1981. ISBN: 9780521281508. [Well-written, alternative intermediate text from a Chemistry perspective].*
Gibbs, J. W. The Collected Works of J. Willard Gibbs, I: Thermodynamics. Edited by W. R. Logley and R. G. Van Name. New York: Longmans, Green, and Company, 1928. [Historical reference].*
Gyftopoulos, Elias P. and Beretta, Gian Paolo. Thermodynamics: Foundations and Applications. Mineola, NY: Dover, 2005. ISBN: 9780486439327. [Comprehensive mechanical engineering approach, power cycles, availability/exergy analysis].
Hatsopoulous, George N. and Keenan, Joseph H. Principles of General Thermodynamics. New York: Wiley, 1964. Replrint available: Melbourne, FL: Krieger, 1982. ISBN: 9780898743036. [Detailed theoretical, postulatory approach].
Hougen, O. A. and Watson, K. M. Chemical Process Principles, I: Thermodynamics. 2nd ed. Wiley, 1959. [Corresponding-states principle, a classic Chemical Engineering Thermodynamics text].
Keenan, Joseph H. et al . “International System of Units.” In Steam Tables: Thermodynamic Properties of Water Including Vapor, Liquid, and Solid Phases. New York: Wiley, 1969. Reprint available: Melbourne, FL: Krieger, 1992. ISBN: 9780894646850.[Good reference].
Pitzer, Kenneth S. Thermodynamics. 3rd ed. New York: McGraw-Hill, 1995. ISBN: 9780070502215. [Well-written, revision of classic 1923 text by G.N. Lewis and M. Randall, treats electrolytes].
Milora, Stanley L. and Tester, Jefferson W. Geothermal Energy as a Source of Electric Power: Thermodynamics and Economic Design Criteria. Cambridge, MA: The MIT Press, 1976. ISBN: 9780262131230. [Thermodynamic treatment of low-temperature power cycles].
Prausnitz, John M., de Azevedo, Edmundo Gomez, and Lichtenthaler, Rudiger N. Molecular Thermodynamics of Fluid-Phase Equilibria. 3rd ed. East Rutherford, NJ: Prentice-Hall, 1998. ISBN: 9780139777455. [Intermolecular forces, bridges the gap between Classical and Statistical Thermodynamics, presents many practical models for non-ideal behavior].
Prigogine, Ilya and Defay, Raymond. Chemical Thermodynamics. London: Longmans, 1954. ISBN: 0598248242. [Detailed, theoretical, good on mixtures and phase equilibria].
Reid, Robert C., Prausnitz, John M., and Poling, Bruce E. The Properties of Gases and Liquids. 4th ed. New York: McGraw-Hill, 1987. ISBN: 9780070517998. [Essential for estimating thermodynamic properties].
Sandler, Stanley I. Chemical and Engineering Thermodynamics. New York: Wiley, 1998. ISBN: 9780471182108.[Introductory, well-organized].
Smith, J. M. (ed.), van Ness, H. C., and Abbott, M. Introduction to Chemical Engineering Thermodynamics. 5th ed. New York: McGraw-Hill, 1996. ISBN: 9780070592391. [Introductory, classic chemical engineering undergrad text, well-organized].
Tisza, Laszlo. Generalized Thermodynamics. Cambridge, MA: The MIT Press, 1966. ISBN: 9780262200103. [Theoretical, detailed discussion of Legendre transformations].
Walas, Stanley M. Phase Equilibria in Chemical Engineering. New York: Buttersworth, 1985. ISBN: 9780750693134. [Excellent, practical treatment of VLE and LLE].
Weber, Harold C. Thermodynamics for Chemical Engineers. 2nd ed. New York: Wiley, 1957. [Well-written, introductory text].
Statistical Mechanics
Chandler, David G. Introduction to Modern Statistical Mechanics. New York: Oxford University Press: 1987. ISBN: 9780195042771. [Concepts and modern theory, particularly helpful for phase transitions.]
Callen, Herbert B. Thermodynamics: An Introduction to the Physical Theories of Equilibrium Thermostatistics and Irreversible Thermodynamics. New York: Wiley, 1960. Reprint available: Temecula, CA: Textbook Publishers, 2003. ISBN: 0758103360. [Critical-point scaling theories.]
Debenedetti, Pablo G. Metastable Liquids: Concepts and Principles. Princeton, NJ: Princeton University Press, 1996. ISBN: 9780691085951. [Modern treatment of experimental data and theories regarding stability and criticality.]
Hill, Terrell L. Statistical Mechanics: Principles and Selected Applications. Mineola, NY: Dover, 1987. ISBN: 9780486653907. [Advanced text covering basic aspects of liquid state theory.]
Hirschfelder, Joseph L., Bird, R. Byron, and Curtiss, Charles F. Molecular Theory of Gases and Liquids. New York: Wiley, 1964. ISBN: 0471400653. Reprint available: Textbook Publishers, 2003. ISBN: 075810443X. [Excellent comprehensive treatment of theory and early work.]
Huang, Kerson. Statistical Mechanics. New York: Wiley, 1987. ISBN: 9780471815181. [Advanced text with extensive discussion of Ising models.]
McQuarrie, Donald A. Statistical Mechanics. New York: Harper and Row, 1973. ISBN: 9780060443658. Reprint available: Sausalito, CA: University Science Books, 2000. ISBN: 9781891389153. [Good detailed treatment of classical statistical mechanics.]*
Pathria, R. K. Statistical Mechanics. 2nd ed. San Diego, CA: Elsevier Science and Technology Books, 1996. ISBN: 9780750624695. [Intermediate text, with a thorough coverage of phase transitions and condensed matter theory.]
Reed, T. M. and Gubbins, K. E. Applied Statistical Mechanics. New York: McGraw-Hill, 1973. ISBN: 9780070514959. Reprint available: San Diego, CA: Elsevier Science and Technology Books, 1991. ISBN: 9780750691369. [Intermediate level text with a solid treatment of intermolecular potentials and some liquid state theory.]
Reif, Frederick. Fundamentals of Statistical and Thermal Physics. New York: McGraw-Hill, 1965. ISBN: 9780070518001. [Introductory text with clear explanations of basic concepts of statistical mechanics, motivated from probability theory.]
Rowley, Richard L. Statistical Mechanics for Thermophysical Property Calculations. Upper Saddle River, NJ: Prentice-Hall, 1994. ISBN: 9780130308184. [Clear basic treatment, including simulation methods, written by a Chemical Engineer.]
Stanley, H. Eugene. Introduction to Phase Transitions and Critical Phenomena. Oxford: Oxford University Press, 1971. ISBN: 01995014588. [A classic text in its field, with clear discussions of scaling relations and critical exponents.]
Yeomans, J. M. Statistical Mechanics of Phase Transitions. Oxford: Oxford University Press, 1992. ISBN: 9780198517306. [An introductory text, simpler than Stanley, with discussions of a number of techniques commonly used in studying the behavior of many-body systems.]
Molecular Simulations
Allen, M. P. and Tildesley, D. J. Computer Simulation of Liquids. Oxford: Oxford University Press, 1988. ISBN: 9780198553755. Reprint available: Oxford: Oxford University Press, 1989. ISBN: 0198556454. [Classic treatment.]
Frenkel, Daan and Smit, Berend. Understanding Molecular Simulation. San Diego, CA: Elsevier Science and Technology Books, 1996. ISBN: 9780122673702. Reprint available: San Diego, CA: Elsevier Science and Technology Books, 2001. ISBN: 9780122673511. [Good overview with more recent advances than Allen and Tildesley.]
*Starred references are of particular value in supplementing text readings.
Supplementary Notes for Course Text
Tester, J. W., and Modell, Michael. Thermodynamics and Its Applications. Upper Saddle River, NJ: Prentice Hall PTR, 1996. ISBN: 9780139153563.
SES # | CHAPTERS | SUPPLEMENTARY NOTES |
---|---|---|
2 | 1-3 | Ch 1-3 Supplementary Notes (PDF) |
3 | 1-3 (cont.) | Ch 1-3 Supplementary Notes (PDF) |
4 | 4 | Ch 4 Supplementary Notes (PDF) |
5 | 4 (cont.) | Ch 4 Supplementary Notes (PDF) |
6 | 4 (cont.) | Ch 4 Supplementary Notes (PDF) |
7 | 14 | Ch 14 Supplementary Notes (PDF) |
8 | 5 | Ch 5 Supplementary Notes (PDF) |
9 | 5 (cont.) | Ch 5 Supplementary Notes (PDF) |
10 | 5 (cont.) | Ch 5 Supplementary Notes (PDF) |
11 | 5 (cont.) | Ch 5 Supplementary Notes (PDF) |
14 | 8 | Ch 8 Supplementary Notes (PDF) |
15 | 8 (cont.) | Ch 8 Supplementary Notes (PDF) |
16 | 8 (cont.) | Ch 8 Supplementary Notes (PDF) |
17 | 9 | Ch 9 Supplementary Notes (PDF) |
18 | 9 (cont.) | Ch 9 Supplementary Notes (PDF) |
36 | 9 (cont.) | Ch 9 Supplementary Notes (PDF) |
38 | 9 (cont.) | Ch 9 Supplementary Notes (PDF) |
47 | 17 | Ch 17 Supplementary Notes (PDF) |
Additional Topical Notes
Course Primary Nomenclature and Symbols (PDF)
Course Definitions/Glossary (PDF)
Combinatorics (PDF)
Four postulates of Classical Thermodynamics (PDF)
Energy and the 1st Law Treatment: Summary of Mathematical Forms (PDF)
Course Meeting Times
Lectures: 2 sessions / week, 2 hours / session
Vision
The goals of 10.40 are to connect the principles, concepts, and laws/postulates of classical and statistical thermodynamics to applications that require quantitative knowledge of thermodynamic properties from a macroscopic to a molecular level.
Approach
Focus on learning rather than grades. As we are revisiting the core area of thermodynamics now is the time to really gain understanding of key concepts and to bring your problem solving skills to a higher level.
- Your outside preparation: Read assigned material before class. Balance and prioritize your efforts on reading the text and other supplementary references, homework, and review for exams.
- Classtime: Overviews and summaries of topics combined with discussion of problem solving approaches. Interactive format with discussion and inquiry emphasized.
- Homework: Look over problems early. Consider alternative approaches with your classmates, but work out the complete solution individually.
- Exams: Understanding concepts and applying them to solving problems is the key to future success not the individual scores on your tests.
Prerequisites
Thermodynamics and Kinetics (5.60)
Chemical Engineering Thermodynamics (10.213)
Text
Tester, Jefferson W., and Michael Modell. Thermodynamics and its Applications. Upper Saddle River, NJ: Prentice Hall, 1996. ISBN: 9780139153563.
Homework and Exams
Two exams, eleven problem sets, and a final exam are scheduled for the course. The exams will be 2 hours long taken in class and the final will be 3 hours long in a take-home format. Your two exam scores and grade on the final exam will each count equally for a total of 60% of the course grade. Homework will count 30% and participation in class discussions 10%. Discussions with the instructors, teaching fellows, and teaching assistants of approaches to solving homework problems are encouraged. While students are welcome to also discuss problem solving strategies with each other, each student is expected to work independently in arriving at and documenting his or her final solution to submit.