WEBVTT

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JUDY HOYT: OK,
maybe we'll go ahead

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and get started, at least
with the announcements.

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Yeah, hopefully
everybody's recovered

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from their Thanksgiving feast.

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And looks like people
are sleeping in today.

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What I'm showing up here is
the schedule to orient us.

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This is lecture 22.

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We'll talk about
silicides, device contacts,

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and I've added in a
new material this year

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on novel gate materials.

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And part of this is covered--

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the first two topics are
covered in chapter 11.

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And then we have
one more lecture,

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which is on strained silicon
and silicon germanium

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growth and processing.

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And then next week we have
two class periods scheduled.

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There'll be four
speakers in each.

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And those will be
the oral reports

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and the student reports given
on Tuesday and Thursday.

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And in fact, I have a slightly
better version of this schedule,

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I think, in this Excel file, and
this is posted up on the web,

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by the way.

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So on December 7th, we
have these four speakers.

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We're going to hear short
presentations, about 16 minutes

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each, from these four
students on everything

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from high k going to diffusion
and gallium arsenide.

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And then on the
Thursday of the ninth,

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we have these four
students scheduled.

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And I just want
to remind people,

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if you're doing an
oral report, you're

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expected to provide handouts,
the same type of handout

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that I use during lecture.

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And if you need help
in making Xerox copies,

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contact my assistant.

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Her contact information
is published on the web.

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Make sure you get
to her early enough.

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Don't give her the job the
same day, that morning,

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but maybe the day
before would be good.

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And also, if you're
doing a written

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report they are due on
Thursday, December 9 in class.

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If you have any questions
about the final project,

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just please email me or
contact me after class.

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OK, so that's the bookkeeping
and to remind people

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about the final project.

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Let's go on and start--

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we can start today's lecture.

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The notes for today's lecture
are given in handout 36.

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And today we want to
talk about a couple

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of devices, a couple of areas--

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the formation of silicides.

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I've referred to silicides a
number of times in the course,

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but we really haven't
gotten a chance

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to talk about what they are.

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Now we'll find out.

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How we make contact, how
we make the structures

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and make good, electrical
contacts and the device.

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And as I mentioned, I've
added a new module this year

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on novel gate materials.

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And we started some
of that last time.

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So far, we've talked
about how to get

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these insulating and doped
regions inside the device.

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We've talked about oxidation,
implantation, diffusion,

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thin film deposition, and
how we etch structures.

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But at this point in the device
fabrication of the seam laws

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flow, we need some way to make
a good electrical contact.

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And I put good electrical
contact in quotes

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because it's somewhat nebulous.

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But we'll see in this
lecture what we mean

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by good electrical contact--

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two doped regions.

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And so this lecture is
kind of the first link

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to the backend
technology course.

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The contact itself
is still generally

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considered part of the
frontend because you're

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contacting the silicon.

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And then beyond,
that everything is

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in the 6.773, which is
the backend technology.

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This is just a
schematic I've shown

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a couple of different times
to point out to you what

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I mean by the contact.

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You're familiar
with this by now.

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We have the silicon source and
the silicon heavily doped drain.

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Here's the gate material.

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And I need some way
of making a contact

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between this electrical
connection here, this metal

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line, and the silicon itself.

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And you can see that can consist
of several different materials.

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In this particular
picture, these sort

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of dark regions
contacting the silicon

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are going to be
made of silicide.

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And we'll talk today about how
you fabricate those silicides.

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Let me also-- I want to talk
about local interconnect.

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Sometimes the contacts
themselves are also

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used for something called
local interconnect.

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And I should point
out here, this

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is an example of a
local interconnect where

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I've got a contact region that
is being used to interconnect,

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say, from one layer to
the next, or locally

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from one part of the device
to a neighboring device,

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but not across the whole chip.

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These are called
global interconnects

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because these wires
go potentially

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across the entire chip up here.

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But this is a
local interconnect.

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It only extends over
a very small distance.

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In fact, on slide number
two of your handout,

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I've got an example of
a local interconnect

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and what it might consist of.

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This is just the
circuit schematic.

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If you have taken electrical
engineering courses,

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you know this is a
bipolar transistor

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with a base and the emitter.

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This little arrow represents
the emitter region.

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And you see in this
circuit schematic

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that the emitter
of this transistor

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is connected by a
wire to a resistor, r.

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Well, this is the
circuit schematic.

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And below is the actual
implementation of this circuit

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in silicon.

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And in fact, if you recognize
that this is an NPN device,

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and this little n region
right here is the emitter--

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this is the P-type base
as shown here in red,

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and this is the
N-type collector.

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And what you see here
is this emitter region

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has a metal contact to it.

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And it is connected locally
to this P-type tube region,

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which is, in fact, a resistor.

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This is a resistor because the
current can flow from this metal

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contact here through the P-type
region-- it has a certain sheet

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resistance, or a
certain resistance--

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and out this other end.

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So this is an example of
using a very short metal wire.

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Might even end up being
silicide or something.

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A very short metal wire
locally on the chip

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to do interconnect from,
say, one neighboring

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device-- in this
case a transistor--

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to another neighboring
device, a resistor.

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So that's what we mean
by local interconnect.

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Talk a little bit
about historically

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about how contacts were made.

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And this is shown on slide 3.

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In the early days, if this
was the drain or the source

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of a transistor, a
MOSFET, people simply

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used aluminum, which was the
metal of choice, directly

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on silicon to make
both the contacts

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and the interconnect material.

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So it was convenient.

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You could contact the
silicon with aluminum,

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and then you could run
wires along the chip.

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And that could interconnect
the various devices.

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The advantages of aluminum
has a low resistivity.

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It's the second lowest of all
the metal candidates, copper

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being the lowest.

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And it has very good adhesion to
silicon and to silicon dioxide.

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It's a very stable metal, and
it makes good electrical contact

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to heavily doped silicon,
as long as the silicon is

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heavily doped.

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Why does it do that?

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Well, aluminum tends to
reduce any native oxide

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present on silicon.

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You know if you take a silicon
wafer and you do an HF dip,

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you'll get rid of
any native oxide.

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But if you let it
sit for any period--

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a few minutes, an
hour or so-- you

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grow a thin, natural
native oxide, SiO2,

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at room temperature on silicon.

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May only be about 10 angstroms
thick, but it's still there.

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The nice thing about
aluminum is that it

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tends to reduce or eat up
that oxide on the silicon,

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and it forms a very
thin layer of Al2O3.

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But this layer is quite
thin, and the aluminum itself

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can diffuse right through it.

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So this enables you to form a
very good electrical contact

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without having an
intervening layer of oxide.

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Some metals you might
put down and they

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won't eat through the silicon
native oxide, the SiO2.

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And then they'll just
be sitting there,

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and you won't get a
good electrical contact.

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Aluminum has this
property that eats

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through that little native
oxide so you get a good contact.

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So it was a convenient
and a good material

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for people to use
for many years.

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Slide 4 just shows you some
of the basic properties

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of interconnect materials
just so you get oriented.

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Here is aluminum on the top.

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Again, one of the most
popular for many years.

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The resistivity is listed
in the second column,

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somewhere around
2.7 to 3 micro ohm

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centimeter for the resistivity.

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Again, the resistivity is
a property of the material.

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And the last column
shows the melting point.

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So it is a low melting
point material.

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The only other
metal of consequence

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that has a lower resistivity
is copper, which is shown here,

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the third one, the third row.

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That's about 1.7 to
2 micron centimeter.

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Copper has a much
high melting point.

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Copper has other difficulties
associated with its integration.

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Copper, if it gets into
silicon, can be a deep level.

00:09:10.470 --> 00:09:13.340 align:middle line:84%
So it can cause
lifetime problems.

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Copper oxidizes very readily,
even at room temperature.

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So you need to protect it,
if you're all aware of that.

00:09:20.640 --> 00:09:24.800 align:middle line:84%
And copper is more difficult
to deposit than aluminum.

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But copper is the material of
choice for today's interconnect.

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I think I brought a wafer
from Intel about halfway

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through the course, a 12-inch
wafer, and showed it to you.

00:09:33.710 --> 00:09:36.020 align:middle line:84%
And you noticed it was
all pretty copper colored.

00:09:36.020 --> 00:09:39.260 align:middle line:84%
It's because the modern
interconnect material is copper.

00:09:39.260 --> 00:09:41.060 align:middle line:84%
A few places are
still using aluminum.

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Aluminum was
historically what's used.

00:09:42.860 --> 00:09:46.850 align:middle line:84%
Copper was introduced in
research in the mid 80s

00:09:46.850 --> 00:09:50.030 align:middle line:84%
and in production about
10 years past that.

00:09:50.030 --> 00:09:54.780 align:middle line:90%


00:09:54.780 --> 00:09:58.380 align:middle line:84%
On slide 4, I'm showing
some basic physics

00:09:58.380 --> 00:10:00.430 align:middle line:84%
that you may or may
not be familiar with.

00:10:00.430 --> 00:10:02.365 align:middle line:84%
But you need to understand
the basics of it

00:10:02.365 --> 00:10:04.740 align:middle line:84%
in order to understand what
we mean by a good electrical.

00:10:04.740 --> 00:10:09.150 align:middle line:84%
Contact their contacts
can, to a semiconductor,

00:10:09.150 --> 00:10:12.210 align:middle line:84%
can be sort of divided
into roughly two classes.

00:10:12.210 --> 00:10:16.680 align:middle line:84%
There's an ohmic contact
and a Schottky contact.

00:10:16.680 --> 00:10:18.690 align:middle line:84%
A Schottky contact
is shown here.

00:10:18.690 --> 00:10:20.190 align:middle line:84%
And if you just
look at the current,

00:10:20.190 --> 00:10:22.440 align:middle line:84%
this little schematic
shows the current

00:10:22.440 --> 00:10:25.470 align:middle line:84%
that flows in the device,
so through the device,

00:10:25.470 --> 00:10:27.690 align:middle line:84%
as a function of the
voltage that you apply.

00:10:27.690 --> 00:10:31.320 align:middle line:90%
Schottky contact is a rectifier.

00:10:31.320 --> 00:10:34.230 align:middle line:84%
It is when you apply
a large voltage

00:10:34.230 --> 00:10:35.940 align:middle line:84%
in one direction, the
reverse direction,

00:10:35.940 --> 00:10:37.510 align:middle line:90%
not much current flows.

00:10:37.510 --> 00:10:41.700 align:middle line:84%
So that's not a very useful way
to make a contact to a device.

00:10:41.700 --> 00:10:43.867 align:middle line:84%
If you apply a small voltage
in the other direction,

00:10:43.867 --> 00:10:45.283 align:middle line:84%
you get a little
current, and then

00:10:45.283 --> 00:10:47.250 align:middle line:84%
you apply above a certain
threshold voltage,

00:10:47.250 --> 00:10:49.090 align:middle line:90%
and you get a lot of current.

00:10:49.090 --> 00:10:50.820 align:middle line:90%
It's basically a diode.

00:10:50.820 --> 00:10:55.020 align:middle line:84%
And the current
transport is by this sort

00:10:55.020 --> 00:10:58.180 align:middle line:84%
of thermionic or thermal
emission over this barrier.

00:10:58.180 --> 00:11:00.120 align:middle line:84%
So this is not considered
desirable for making

00:11:00.120 --> 00:11:01.860 align:middle line:90%
a good contact.

00:11:01.860 --> 00:11:06.390 align:middle line:84%
An ohmic contact on the other
side, or a tunneling contact,

00:11:06.390 --> 00:11:08.605 align:middle line:84%
occurs when you can
actually tunnel right

00:11:08.605 --> 00:11:09.480 align:middle line:90%
through this barrier.

00:11:09.480 --> 00:11:12.350 align:middle line:84%
The barrier is so thin
that you can actually

00:11:12.350 --> 00:11:13.350 align:middle line:90%
tunnel right through it.

00:11:13.350 --> 00:11:15.730 align:middle line:84%
The depletion
region is very thin.

00:11:15.730 --> 00:11:19.500 align:middle line:84%
And if you do make high
doping right near the metal,

00:11:19.500 --> 00:11:22.320 align:middle line:84%
you can reduce this
depletion layer width.

00:11:22.320 --> 00:11:24.450 align:middle line:90%
And it enables this tunneling.

00:11:24.450 --> 00:11:26.890 align:middle line:84%
And so if you look at
the current voltage

00:11:26.890 --> 00:11:29.560 align:middle line:84%
characteristics-- so current
plotted on the y-axis,

00:11:29.560 --> 00:11:31.010 align:middle line:90%
voltage on the x-axis--

00:11:31.010 --> 00:11:32.680 align:middle line:84%
you see it's very
symmetrical, and you

00:11:32.680 --> 00:11:35.350 align:middle line:84%
get a very, very high current
for a very small voltage

00:11:35.350 --> 00:11:36.487 align:middle line:90%
in either direction.

00:11:36.487 --> 00:11:37.820 align:middle line:90%
So this is considered desirable.

00:11:37.820 --> 00:11:38.695 align:middle line:90%
This is what we want.

00:11:38.695 --> 00:11:40.610 align:middle line:90%
We want that ohmic contact.

00:11:40.610 --> 00:11:42.800 align:middle line:84%
And it tends to
happen, particularly

00:11:42.800 --> 00:11:44.930 align:middle line:84%
with aluminum and most
metals, if you make

00:11:44.930 --> 00:11:46.745 align:middle line:90%
the surface doping very high.

00:11:46.745 --> 00:11:50.520 align:middle line:90%


00:11:50.520 --> 00:11:52.800 align:middle line:84%
A concept that we want
to talk about that

00:11:52.800 --> 00:11:56.910 align:middle line:84%
is shown here on slide 6 is
called the specific contact

00:11:56.910 --> 00:11:57.780 align:middle line:90%
resistivity.

00:11:57.780 --> 00:11:59.280 align:middle line:84%
And we usually use
the Greek letter

00:11:59.280 --> 00:12:04.090 align:middle line:84%
rho sub C. The definition
of it is given here.

00:12:04.090 --> 00:12:07.230 align:middle line:84%
It's defined as being
equivalent to the derivative

00:12:07.230 --> 00:12:10.590 align:middle line:84%
of the voltage current
density characteristic

00:12:10.590 --> 00:12:12.270 align:middle line:84%
at a metal
semiconductor contacts.

00:12:12.270 --> 00:12:19.120 align:middle line:84%
So it's partial v, the voltage,
by partial j, basically.

00:12:19.120 --> 00:12:23.880 align:middle line:84%
And so we usually
assume a structure

00:12:23.880 --> 00:12:26.670 align:middle line:84%
where the current density is
uniform across some contact

00:12:26.670 --> 00:12:28.200 align:middle line:90%
area.

00:12:28.200 --> 00:12:31.990 align:middle line:84%
Then you can calculate the
contact resistance R in ohms.

00:12:31.990 --> 00:12:35.910 align:middle line:84%
So R would have the units of
ohms from the specific contact

00:12:35.910 --> 00:12:38.590 align:middle line:84%
resistivity by the
following equation.

00:12:38.590 --> 00:12:41.040 align:middle line:84%
The resistance of a
given contact in ohms

00:12:41.040 --> 00:12:43.410 align:middle line:84%
is just the voltage divided
by the current flowing

00:12:43.410 --> 00:12:45.030 align:middle line:90%
through that contact.

00:12:45.030 --> 00:12:47.970 align:middle line:84%
And you can calculate
it by rho sub C,

00:12:47.970 --> 00:12:51.730 align:middle line:84%
which typically has units of
ohm centimeters squared or ohm

00:12:51.730 --> 00:12:54.580 align:middle line:84%
micron squared-- so it's got
a units of resistance times

00:12:54.580 --> 00:12:55.180 align:middle line:90%
an area--

00:12:55.180 --> 00:12:58.480 align:middle line:84%
and divided by the
area of the contact.

00:12:58.480 --> 00:13:01.810 align:middle line:84%
So if someone tells you,
oh I've made a contact.

00:13:01.810 --> 00:13:05.560 align:middle line:84%
It has a certain specific
contact resistivity,

00:13:05.560 --> 00:13:07.960 align:middle line:84%
10 to the -7 ohm
centimeter squared,

00:13:07.960 --> 00:13:11.430 align:middle line:84%
then you can design
your contact area

00:13:11.430 --> 00:13:16.260 align:middle line:84%
as you need to to get the right
contact resistance in ohms.

00:13:16.260 --> 00:13:18.780 align:middle line:84%
And basically what this tells
you is-- and you notice you

00:13:18.780 --> 00:13:22.650 align:middle line:84%
it's the total resistance
of a contact in ohms

00:13:22.650 --> 00:13:24.550 align:middle line:84%
is inversely
proportional to area.

00:13:24.550 --> 00:13:27.120 align:middle line:84%
So if I make a
smaller contact area

00:13:27.120 --> 00:13:29.520 align:middle line:84%
for a given specific
contact resistivity,

00:13:29.520 --> 00:13:31.275 align:middle line:84%
you're going to have
a higher resistance.

00:13:31.275 --> 00:13:33.150 align:middle line:84%
And this is a problem
if I'm scaling devices.

00:13:33.150 --> 00:13:35.960 align:middle line:84%
If I'm packing more and
more devices on the chip,

00:13:35.960 --> 00:13:38.490 align:middle line:84%
it means I want to make
the total area occupied

00:13:38.490 --> 00:13:40.470 align:middle line:90%
by every device smaller.

00:13:40.470 --> 00:13:43.240 align:middle line:84%
That means I need to make
the contact area smaller.

00:13:43.240 --> 00:13:46.435 align:middle line:84%
But if I leave the contact
resistivity the same,

00:13:46.435 --> 00:13:48.060 align:middle line:84%
I don't do anything
different about how

00:13:48.060 --> 00:13:50.910 align:middle line:84%
I make the contact, then as
I'm scaling these devices,

00:13:50.910 --> 00:13:52.350 align:middle line:84%
of course, the
area of the contact

00:13:52.350 --> 00:13:56.100 align:middle line:84%
is going down to get more
of these devices on a chip.

00:13:56.100 --> 00:14:01.020 align:middle line:84%
That means the resistance is
going up as devices are scaled.

00:14:01.020 --> 00:14:04.020 align:middle line:84%
And we'll see some
specific numbers on this.

00:14:04.020 --> 00:14:06.990 align:middle line:84%
This is a problem as we scale,
unless we scale roh sub c,

00:14:06.990 --> 00:14:10.110 align:middle line:84%
unless we do something to
make better contacts as we

00:14:10.110 --> 00:14:13.080 align:middle line:84%
scale devices, just because
of this geometric factor.

00:14:13.080 --> 00:14:16.590 align:middle line:84%
As I make the area the
current goes through smaller,

00:14:16.590 --> 00:14:18.525 align:middle line:84%
the resistance of
that contact goes up.

00:14:18.525 --> 00:14:22.770 align:middle line:90%


00:14:22.770 --> 00:14:25.410 align:middle line:84%
So the second type
of contact-- again,

00:14:25.410 --> 00:14:27.660 align:middle line:84%
this is one that's not
generally considered desirable,

00:14:27.660 --> 00:14:29.868 align:middle line:84%
but we need to understand
a little bit of the physics

00:14:29.868 --> 00:14:30.480 align:middle line:90%
of it--

00:14:30.480 --> 00:14:32.630 align:middle line:90%
is a Schottky contact.

00:14:32.630 --> 00:14:35.870 align:middle line:84%
And the energy band
diagram for that

00:14:35.870 --> 00:14:39.020 align:middle line:84%
is shown here,
where the metal is

00:14:39.020 --> 00:14:42.470 align:middle line:84%
on the left and the
semiconductor is on the right.

00:14:42.470 --> 00:14:46.250 align:middle line:84%
And a Schottky contact is
governed by thermionic emission.

00:14:46.250 --> 00:14:49.160 align:middle line:84%
So it's a thermionic
process emitting

00:14:49.160 --> 00:14:51.870 align:middle line:90%
carriers over this barrier.

00:14:51.870 --> 00:14:54.140 align:middle line:84%
And we know from the
Richardson equation

00:14:54.140 --> 00:14:57.290 align:middle line:84%
we can write thermionic
emission current density

00:14:57.290 --> 00:15:01.160 align:middle line:84%
J as being proportional
to the temperature

00:15:01.160 --> 00:15:03.140 align:middle line:90%
squared, some constant a star.

00:15:03.140 --> 00:15:05.810 align:middle line:84%
But most importantly,
it goes exponentially

00:15:05.810 --> 00:15:07.100 align:middle line:90%
like the barrier height.

00:15:07.100 --> 00:15:10.220 align:middle line:84%
So it's e to the
minus q phi B over kT

00:15:10.220 --> 00:15:14.060 align:middle line:84%
where the barrier height
is just the band bending.

00:15:14.060 --> 00:15:17.840 align:middle line:84%
It's this barrier between the
Fermi level in the semiconductor

00:15:17.840 --> 00:15:21.483 align:middle line:84%
and the Fermi
level in the metal.

00:15:21.483 --> 00:15:23.150 align:middle line:84%
So that's going to
tend to be a property

00:15:23.150 --> 00:15:24.567 align:middle line:84%
of the doping in
the semiconductor

00:15:24.567 --> 00:15:28.820 align:middle line:84%
and what kind of
metal you put on it.

00:15:28.820 --> 00:15:30.430 align:middle line:90%
So if we take this equation.

00:15:30.430 --> 00:15:32.343 align:middle line:84%
this current equation,
which we know,

00:15:32.343 --> 00:15:33.760 align:middle line:84%
the current voltage
characteristic

00:15:33.760 --> 00:15:36.400 align:middle line:84%
is exponential in
the applied voltage.

00:15:36.400 --> 00:15:39.850 align:middle line:84%
And we just use the
definition of roh sub C,

00:15:39.850 --> 00:15:43.930 align:middle line:84%
you can calculate, as shown
on the bottom here of slide 7,

00:15:43.930 --> 00:15:46.810 align:middle line:84%
what the specific contact
resistivity should look

00:15:46.810 --> 00:15:47.980 align:middle line:90%
like for a Schottky barrier.

00:15:47.980 --> 00:15:49.450 align:middle line:84%
And you see it
goes exponentially,

00:15:49.450 --> 00:15:51.500 align:middle line:90%
like the barrier height.

00:15:51.500 --> 00:15:57.620 align:middle line:84%
So if we change that barrier
height, we can change rho sub C.

00:15:57.620 --> 00:16:04.040 align:middle line:84%
So what we do in practice
is we look at that equation

00:16:04.040 --> 00:16:06.230 align:middle line:84%
and we try to get into
a different regime.

00:16:06.230 --> 00:16:07.760 align:middle line:84%
Instead of being
in the regime where

00:16:07.760 --> 00:16:10.910 align:middle line:84%
we're dominated by
tunneling over this barrier

00:16:10.910 --> 00:16:13.370 align:middle line:84%
by thermionic emission,
rather, excuse me,

00:16:13.370 --> 00:16:16.280 align:middle line:84%
over the barrier, if we make
the barrier distance really

00:16:16.280 --> 00:16:19.820 align:middle line:84%
narrow, really small, you know
from your quantum mechanics

00:16:19.820 --> 00:16:23.000 align:middle line:84%
classes that you can actually
get quantum mechanical tunneling

00:16:23.000 --> 00:16:24.810 align:middle line:90%
through the barrier.

00:16:24.810 --> 00:16:28.880 align:middle line:84%
So here on slide 8, what I've
shown is a tunneling contact.

00:16:28.880 --> 00:16:33.570 align:middle line:84%
It's a Schottky contact in the
limit of very, very high doping.

00:16:33.570 --> 00:16:37.460 align:middle line:84%
So we form these-- you see we
still have this barrier, phi B.

00:16:37.460 --> 00:16:39.560 align:middle line:84%
But the distance,
the depletion layer

00:16:39.560 --> 00:16:42.560 align:middle line:84%
thickness in the semiconductor,
is very, very small.

00:16:42.560 --> 00:16:46.710 align:middle line:84%
And that happens when
you make the doping high.

00:16:46.710 --> 00:16:48.292 align:middle line:84%
So in fact, for a
tunneling contact,

00:16:48.292 --> 00:16:50.000 align:middle line:84%
if you go back to your
quantum mechanics,

00:16:50.000 --> 00:16:54.350 align:middle line:84%
you know if you have a
certain barrier height, phi B,

00:16:54.350 --> 00:17:00.480 align:middle line:84%
and a certain
barrier thickness XD,

00:17:00.480 --> 00:17:02.460 align:middle line:84%
that the tunneling
current is exponentially

00:17:02.460 --> 00:17:03.877 align:middle line:84%
dependent on those
two quantities.

00:17:03.877 --> 00:17:06.359 align:middle line:90%
It looks something like this.

00:17:06.359 --> 00:17:08.329 align:middle line:84%
So how do I make the
depletion layer thickness

00:17:08.329 --> 00:17:12.050 align:middle line:84%
small in the semiconductor when
I put a metal contact to it?

00:17:12.050 --> 00:17:13.819 align:middle line:84%
Well, again, if
you're going back

00:17:13.819 --> 00:17:15.920 align:middle line:84%
to some of your
basic electrostatics,

00:17:15.920 --> 00:17:19.940 align:middle line:84%
XD is inversely proportional to
the doping, or the square root

00:17:19.940 --> 00:17:21.020 align:middle line:90%
of the doping.

00:17:21.020 --> 00:17:23.660 align:middle line:84%
So all I need to do
to make XD small is

00:17:23.660 --> 00:17:25.579 align:middle line:84%
to pump up this
doping very high,

00:17:25.579 --> 00:17:29.010 align:middle line:90%
the doping in the semiconductor.

00:17:29.010 --> 00:17:34.310 align:middle line:84%
So when the doping is high
enough, XD will become small.

00:17:34.310 --> 00:17:37.040 align:middle line:84%
And then when XD
gets less than about,

00:17:37.040 --> 00:17:40.430 align:middle line:84%
say, 2 nanometers or
so in this equation,

00:17:40.430 --> 00:17:43.910 align:middle line:84%
you get a very large
tunneling current, basically.

00:17:43.910 --> 00:17:47.030 align:middle line:84%
So what people do in practice
is you dope very heavily

00:17:47.030 --> 00:17:49.850 align:middle line:84%
above, say, above
mid 10 of the 19th,

00:17:49.850 --> 00:17:51.800 align:middle line:84%
you get quantum
mechanical tunneling.

00:17:51.800 --> 00:17:53.870 align:middle line:84%
And that's really
what's dominating.

00:17:53.870 --> 00:17:57.860 align:middle line:84%
So if you put these
numbers and in here

00:17:57.860 --> 00:18:00.650 align:middle line:84%
and you look at the definition
of the specific contact

00:18:00.650 --> 00:18:02.720 align:middle line:84%
resistivity, you get
an equation like what's

00:18:02.720 --> 00:18:05.250 align:middle line:84%
shown at the bottom
of page 8 here.

00:18:05.250 --> 00:18:07.350 align:middle line:84%
And you can see, again,
it depends exponentially

00:18:07.350 --> 00:18:10.923 align:middle line:84%
on the barrier
height and inversely

00:18:10.923 --> 00:18:12.090 align:middle line:90%
exponentially on the doping.

00:18:12.090 --> 00:18:15.370 align:middle line:84%
So for low contact resistivity,
to get this number down,

00:18:15.370 --> 00:18:16.710 align:middle line:90%
I need a small barrier.

00:18:16.710 --> 00:18:19.920 align:middle line:84%
So you would choose a
particular metal that gives you

00:18:19.920 --> 00:18:21.750 align:middle line:84%
a relatively small
barrier height, phi B.

00:18:21.750 --> 00:18:24.150 align:middle line:84%
And you need, most
importantly, very high doping.

00:18:24.150 --> 00:18:27.660 align:middle line:84%
So you need to pump up the
doping as high as possible.

00:18:27.660 --> 00:18:29.580 align:middle line:84%
And then you will get
an IV characteristic

00:18:29.580 --> 00:18:30.795 align:middle line:90%
that is essentially ohmic.

00:18:30.795 --> 00:18:34.480 align:middle line:90%


00:18:34.480 --> 00:18:41.110 align:middle line:84%
So here I'm just doing a
simple calculation on slide 9.

00:18:41.110 --> 00:18:44.850 align:middle line:84%
Here's an example if
we use the expression

00:18:44.850 --> 00:18:48.240 align:middle line:84%
for the specific contact
resistivity at very high doping

00:18:48.240 --> 00:18:50.710 align:middle line:84%
levels where we have
tunneling dominate.

00:18:50.710 --> 00:18:52.830 align:middle line:84%
So we can write that
expression that I just

00:18:52.830 --> 00:18:56.130 align:middle line:84%
showed on the prior page
saying that rho C is

00:18:56.130 --> 00:18:58.410 align:middle line:84%
rho C zero, some
pre-exponential,

00:18:58.410 --> 00:19:02.390 align:middle line:84%
times the exponential
dependence on phi B and D,

00:19:02.390 --> 00:19:08.420 align:middle line:84%
and where this
exponential multiplier

00:19:08.420 --> 00:19:12.190 align:middle line:84%
C1 is given by this number,
7 times 10 to the 10th.

00:19:12.190 --> 00:19:15.490 align:middle line:84%
So now let's say I assume I
have a metal semiconductor

00:19:15.490 --> 00:19:19.960 align:middle line:84%
contact where the barrier
height is 0.6 electron volts.

00:19:19.960 --> 00:19:24.803 align:middle line:84%
And rho C zero, this number, is
about 10 to the minus 7 ohm--

00:19:24.803 --> 00:19:26.470 align:middle line:84%
that's a little hard
to read, but that's

00:19:26.470 --> 00:19:30.360 align:middle line:84%
ohm centimeter squared for an
aluminum and silicon contact.

00:19:30.360 --> 00:19:34.950 align:middle line:84%
So the question is if I change
the doping from 1e19 to 1e20

00:19:34.950 --> 00:19:37.920 align:middle line:84%
by a factor of 10, how
much does rho C go down?

00:19:37.920 --> 00:19:40.702 align:middle line:84%
Just to give us an example of
how much you benefit yourself.

00:19:40.702 --> 00:19:42.660 align:middle line:84%
And again, this is an
exponential relationship.

00:19:42.660 --> 00:19:44.800 align:middle line:90%
So you expect a big change.

00:19:44.800 --> 00:19:47.730 align:middle line:84%
So in this case, the first
case, I have a doping of 10

00:19:47.730 --> 00:19:48.570 align:middle line:90%
to the 19th.

00:19:48.570 --> 00:19:50.040 align:middle line:90%
You plug in all these numbers.

00:19:50.040 --> 00:19:52.080 align:middle line:84%
You put in the square
root of 10 of 19 down here

00:19:52.080 --> 00:19:55.380 align:middle line:84%
and you get a RHO C
of about 6 times 10

00:19:55.380 --> 00:19:59.090 align:middle line:84%
to the -2 ohm
centimeter squared.

00:19:59.090 --> 00:20:00.840 align:middle line:84%
It's a pretty big
number, as it turns out,

00:20:00.840 --> 00:20:04.830 align:middle line:84%
if you plug in a standard size
of a contact on a silicon chip.

00:20:04.830 --> 00:20:06.420 align:middle line:90%
That's a 10 to the 19.

00:20:06.420 --> 00:20:08.800 align:middle line:84%
At 10 of a 20, you do
the same sort of thing,

00:20:08.800 --> 00:20:12.040 align:middle line:84%
and you do the math, and now you
get about 6 times 10 to the -6

00:20:12.040 --> 00:20:13.780 align:middle line:90%
ohm centimeter squared.

00:20:13.780 --> 00:20:17.370 align:middle line:84%
So that's about a
factor of 9,000 lower.

00:20:17.370 --> 00:20:20.640 align:middle line:84%
So it changed by almost four
orders of magnitude, the contact

00:20:20.640 --> 00:20:25.560 align:middle line:84%
resistivity, just by upping
the doping by a factor of 10.

00:20:25.560 --> 00:20:28.090 align:middle line:84%
She got four orders
of magnitude.

00:20:28.090 --> 00:20:31.890 align:middle line:90%
So that's dramatic difference.

00:20:31.890 --> 00:20:33.462 align:middle line:84%
So this tells you,
you need to have--

00:20:33.462 --> 00:20:35.670 align:middle line:84%
if you're going to get
reasonable contacts in silicon

00:20:35.670 --> 00:20:40.015 align:middle line:84%
technology, unless you want huge
devices where the whole chip is

00:20:40.015 --> 00:20:42.390 align:middle line:84%
dominated by contacts, which
is ridiculous-- you won't be

00:20:42.390 --> 00:20:43.920 align:middle line:84%
able to get enough
devices on your chip--

00:20:43.920 --> 00:20:46.087 align:middle line:84%
you're going to have to get
the doping in the source

00:20:46.087 --> 00:20:49.800 align:middle line:84%
drain regions high, at least
10 to the 20 or higher.

00:20:49.800 --> 00:20:53.910 align:middle line:84%
This number itself is still
considered a little bit

00:20:53.910 --> 00:20:56.880 align:middle line:84%
on the too-high of a side
for a contact resistance.

00:20:56.880 --> 00:20:59.360 align:middle line:84%
But it's just interesting
to look at these numbers.

00:20:59.360 --> 00:21:02.350 align:middle line:84%
And in fact, I've taken
on the next slide figure

00:21:02.350 --> 00:21:03.783 align:middle line:90%
11-7 from your text.

00:21:03.783 --> 00:21:05.200 align:middle line:84%
And you can see
that these numbers

00:21:05.200 --> 00:21:07.700 align:middle line:84%
are in pretty good agreement
with what people have measured.

00:21:07.700 --> 00:21:10.060 align:middle line:90%


00:21:10.060 --> 00:21:12.550 align:middle line:90%
Here on slide 10--

00:21:12.550 --> 00:21:17.560 align:middle line:84%
I took this from your text that
shows the contact resistivity

00:21:17.560 --> 00:21:21.880 align:middle line:84%
in ohm centimeter squared as
a function of doping here.

00:21:21.880 --> 00:21:25.390 align:middle line:84%
And you can see the doping
up on this scale here

00:21:25.390 --> 00:21:28.160 align:middle line:90%
for two different metal systems.

00:21:28.160 --> 00:21:30.670 align:middle line:84%
One is the aluminum
contact to N-type silicon,

00:21:30.670 --> 00:21:33.460 align:middle line:84%
and the other is platinum
silicide to N-type silicon.

00:21:33.460 --> 00:21:37.090 align:middle line:84%
And the data is the bullets
that people have measured,

00:21:37.090 --> 00:21:39.040 align:middle line:84%
like these open squares
are for aluminum

00:21:39.040 --> 00:21:40.510 align:middle line:90%
contacting N-type silicon.

00:21:40.510 --> 00:21:45.550 align:middle line:84%
And the theoretical curve is
shown here with the solid line.

00:21:45.550 --> 00:21:48.220 align:middle line:84%
There you can see there's
reasonable agreement.

00:21:48.220 --> 00:21:52.210 align:middle line:84%
Notice here this
is a log-log scale.

00:21:52.210 --> 00:21:53.980 align:middle line:84%
So we're getting an
exponential dependence

00:21:53.980 --> 00:21:55.430 align:middle line:90%
in the heavily doped regime.

00:21:55.430 --> 00:21:58.780 align:middle line:84%
So again, as doping is
increasing to the left on this

00:21:58.780 --> 00:21:59.600 align:middle line:90%
x-axis--

00:21:59.600 --> 00:22:01.690 align:middle line:84%
so here's a doping
of 10 of a 19th.

00:22:01.690 --> 00:22:03.220 align:middle line:90%
Here's a doping of 10 of the 20.

00:22:03.220 --> 00:22:05.890 align:middle line:84%
And we see a number of
orders of magnitude.

00:22:05.890 --> 00:22:08.230 align:middle line:84%
Basically force
of magnitude drop

00:22:08.230 --> 00:22:11.540 align:middle line:84%
as they go from 10 to
19 to 10 to the 20.

00:22:11.540 --> 00:22:13.195 align:middle line:84%
So you say, OK,
that's not a big deal.

00:22:13.195 --> 00:22:15.460 align:middle line:84%
I just keep increasing the
doping in my source drain

00:22:15.460 --> 00:22:17.770 align:middle line:90%
regions over time.

00:22:17.770 --> 00:22:20.580 align:middle line:84%
The problem is we know that
there are electrical solubility

00:22:20.580 --> 00:22:21.480 align:middle line:90%
limits.

00:22:21.480 --> 00:22:24.660 align:middle line:84%
We cannot just arbitrarily
keep increasing doping.

00:22:24.660 --> 00:22:26.310 align:middle line:84%
We're trying to
find ways to do it.

00:22:26.310 --> 00:22:27.720 align:middle line:84%
But you know if
you do an implant

00:22:27.720 --> 00:22:29.520 align:middle line:84%
and you do a certain
anneal, you get

00:22:29.520 --> 00:22:33.030 align:middle line:84%
doping up to a certain value,
maybe depending on the doping,

00:22:33.030 --> 00:22:34.740 align:middle line:90%
maybe in the low 20s.

00:22:34.740 --> 00:22:36.540 align:middle line:84%
Maybe 2 to 4 times
10 to the negative.

00:22:36.540 --> 00:22:39.220 align:middle line:84%
Beyond that, it's very
hard to go much further.

00:22:39.220 --> 00:22:41.940 align:middle line:84%
So the problem is
that rho C is not

00:22:41.940 --> 00:22:45.440 align:middle line:84%
really scaling because of the
doping electrical solubility

00:22:45.440 --> 00:22:45.940 align:middle line:90%
limit.

00:22:45.940 --> 00:22:50.433 align:middle line:84%
So the contact passivity doesn't
scale as we shrink technology.

00:22:50.433 --> 00:22:51.600 align:middle line:90%
And this is a major problem.

00:22:51.600 --> 00:22:54.540 align:middle line:84%
People are looking for new
methods, new materials,

00:22:54.540 --> 00:22:56.700 align:middle line:84%
whatever, some way of
getting the doping up,

00:22:56.700 --> 00:22:58.167 align:middle line:84%
or a new method
of making contact.

00:22:58.167 --> 00:22:59.625 align:middle line:84%
That's kind of a
fundamental issue.

00:22:59.625 --> 00:23:02.300 align:middle line:90%


00:23:02.300 --> 00:23:06.760 align:middle line:84%
In fact, here on slide 11,
I show that this is really

00:23:06.760 --> 00:23:08.150 align:middle line:90%
one of the concerns.

00:23:08.150 --> 00:23:10.390 align:middle line:84%
This is a table that
I took, table 71a,

00:23:10.390 --> 00:23:13.720 align:middle line:84%
from the 2003
international technology

00:23:13.720 --> 00:23:14.890 align:middle line:90%
roadmap for semiconductors.

00:23:14.890 --> 00:23:17.050 align:middle line:84%
I've shown this
before, but we hadn't

00:23:17.050 --> 00:23:19.240 align:middle line:90%
gotten to this contact stage.

00:23:19.240 --> 00:23:22.160 align:middle line:84%
And just to remind you,
in the upper right corner,

00:23:22.160 --> 00:23:23.840 align:middle line:84%
this is what the
MOSFET looks like.

00:23:23.840 --> 00:23:25.630 align:middle line:84%
And these black
regions are going

00:23:25.630 --> 00:23:29.165 align:middle line:84%
to be silicides, either cobalt
silicides or nickel silicide.

00:23:29.165 --> 00:23:30.290 align:middle line:90%
We'll talk more about that.

00:23:30.290 --> 00:23:31.707 align:middle line:84%
But the point is
they're a contact

00:23:31.707 --> 00:23:34.570 align:middle line:84%
between a metal and a heavily
doped semiconductor, which

00:23:34.570 --> 00:23:36.448 align:middle line:90%
is silicon.

00:23:36.448 --> 00:23:38.240 align:middle line:84%
And if you look at some
of the requirements

00:23:38.240 --> 00:23:41.900 align:middle line:84%
here on the ITRS roadmap, here
we are in, let's say a year ago,

00:23:41.900 --> 00:23:43.310 align:middle line:90%
2003.

00:23:43.310 --> 00:23:46.550 align:middle line:84%
Look at the maximum
contact resistive.

00:23:46.550 --> 00:23:51.350 align:middle line:84%
So this is the rho
C. This right here is

00:23:51.350 --> 00:23:52.850 align:middle line:90%
represented what we call rho C.

00:23:52.850 --> 00:23:58.210 align:middle line:84%
In 2003, they wanted to have
about 2 times 10 to the -7th ohm

00:23:58.210 --> 00:23:59.290 align:middle line:90%
centimeter square.

00:23:59.290 --> 00:24:02.230 align:middle line:84%
And you notice it's sort of
a light orange color, which

00:24:02.230 --> 00:24:04.870 align:middle line:84%
means, according to
our key, that there

00:24:04.870 --> 00:24:09.130 align:middle line:84%
is an interim solution on
how to get to this is known.

00:24:09.130 --> 00:24:12.310 align:middle line:84%
But if you go to 2004,
you want to lower it

00:24:12.310 --> 00:24:15.370 align:middle line:84%
according to ITRS about
1.6 times 10 to -7.

00:24:15.370 --> 00:24:17.500 align:middle line:84%
That's all in
yellow, which means

00:24:17.500 --> 00:24:19.540 align:middle line:84%
their manufacturable
solutions are known.

00:24:19.540 --> 00:24:21.610 align:middle line:84%
They haven't yet
been integrated.

00:24:21.610 --> 00:24:24.160 align:middle line:84%
And when we get to
2008 in the red,

00:24:24.160 --> 00:24:27.940 align:middle line:84%
to get down to about 0.8 times
10 to -7 ohm centimeter squared,

00:24:27.940 --> 00:24:31.130 align:middle line:84%
there aren't any known solutions
that are manufacturable.

00:24:31.130 --> 00:24:33.340 align:middle line:84%
So we're coming up
against the red brick wall

00:24:33.340 --> 00:24:39.220 align:middle line:84%
here because the device
scaling and the need

00:24:39.220 --> 00:24:42.190 align:middle line:84%
to make the contact size
smaller means that we need

00:24:42.190 --> 00:24:44.860 align:middle line:90%
to drop rho C at this rate.

00:24:44.860 --> 00:24:46.690 align:middle line:84%
And it's just
nobody knows yet how

00:24:46.690 --> 00:24:50.380 align:middle line:84%
to make a contact that has
0.8 times 10 to the -7 ohm

00:24:50.380 --> 00:24:53.800 align:middle line:84%
centimeter squared for
the specific resistivity.

00:24:53.800 --> 00:24:56.260 align:middle line:84%
So it's the contacts that
are really hurting us.

00:24:56.260 --> 00:24:59.760 align:middle line:84%
Look at the sheet resistance
you might be concerned about.

00:24:59.760 --> 00:25:02.360 align:middle line:84%
Well, how about the resistance
of the metal itself?

00:25:02.360 --> 00:25:05.420 align:middle line:84%
Resistance of the electrons
flowing through the metal

00:25:05.420 --> 00:25:06.800 align:middle line:90%
is not a real big problem.

00:25:06.800 --> 00:25:09.110 align:middle line:84%
When you look at the
contact silicide sheet

00:25:09.110 --> 00:25:11.840 align:middle line:84%
resistance in ohms
per square, it

00:25:11.840 --> 00:25:16.070 align:middle line:84%
needs to be in this range
of 6 to 10 ohms per square.

00:25:16.070 --> 00:25:17.100 align:middle line:90%
That's not a problem.

00:25:17.100 --> 00:25:19.580 align:middle line:84%
None of that-- that's all
in white, which means people

00:25:19.580 --> 00:25:20.520 align:middle line:90%
know how to do that.

00:25:20.520 --> 00:25:22.580 align:middle line:84%
The real problem is
making these really good

00:25:22.580 --> 00:25:27.210 align:middle line:84%
low resistivity
contacts to the silicon.

00:25:27.210 --> 00:25:29.970 align:middle line:90%


00:25:29.970 --> 00:25:32.220 align:middle line:84%
I just want to show
an example of how--

00:25:32.220 --> 00:25:34.470 align:middle line:84%
so you get a feel for
how the numbers work

00:25:34.470 --> 00:25:37.320 align:middle line:84%
of how one does a contact
resistance calculation.

00:25:37.320 --> 00:25:38.800 align:middle line:90%
This is for a MOSFET.

00:25:38.800 --> 00:25:42.840 align:middle line:84%
This is shown on slide
12 of your handouts.

00:25:42.840 --> 00:25:45.428 align:middle line:84%
Again, this is a cross-section
view of a MOSFET.

00:25:45.428 --> 00:25:47.220 align:middle line:84%
So on the left, you
can imagine this region

00:25:47.220 --> 00:25:48.930 align:middle line:84%
as being the heavily
doped source.

00:25:48.930 --> 00:25:52.590 align:middle line:84%
In the middle shown
in orange is the gate.

00:25:52.590 --> 00:25:54.510 align:middle line:84%
And this is the
heavily doped drain.

00:25:54.510 --> 00:25:57.520 align:middle line:84%
And these black
regions are metal.

00:25:57.520 --> 00:26:00.130 align:middle line:84%
Could be silicide, but
there's a metal region.

00:26:00.130 --> 00:26:03.680 align:middle line:84%
And I'm showing the
dimension of the contact,

00:26:03.680 --> 00:26:05.470 align:middle line:84%
so the region over
which the metal is

00:26:05.470 --> 00:26:08.200 align:middle line:84%
in contact with the
silicon, in this dimension

00:26:08.200 --> 00:26:10.480 align:middle line:90%
is 0.2 microns wide.

00:26:10.480 --> 00:26:13.960 align:middle line:84%
OK, now into the page,
or into the board,

00:26:13.960 --> 00:26:16.150 align:middle line:84%
we're assuming
that it's 1 micron.

00:26:16.150 --> 00:26:17.860 align:middle line:84%
And in fact, this is
a cross-section view

00:26:17.860 --> 00:26:18.620 align:middle line:90%
of the device.

00:26:18.620 --> 00:26:21.730 align:middle line:84%
If you were to look down
on the device, a top view,

00:26:21.730 --> 00:26:23.150 align:middle line:90%
this is what you would see.

00:26:23.150 --> 00:26:26.270 align:middle line:84%
This would be your
source contact region.

00:26:26.270 --> 00:26:28.510 align:middle line:90%
Here's your gate in the orange.

00:26:28.510 --> 00:26:29.440 align:middle line:90%
And here's the drain.

00:26:29.440 --> 00:26:31.240 align:middle line:84%
And again, the
region over which we

00:26:31.240 --> 00:26:32.620 align:middle line:84%
have to make the
metal contact is

00:26:32.620 --> 00:26:35.650 align:middle line:84%
assumed to be 0.2 microns
in this direction in width

00:26:35.650 --> 00:26:38.180 align:middle line:90%
and 1 micron in this direction.

00:26:38.180 --> 00:26:40.180 align:middle line:84%
So the area of this
contact clearly,

00:26:40.180 --> 00:26:42.910 align:middle line:84%
if the current is going
to go flow through it,

00:26:42.910 --> 00:26:46.570 align:middle line:84%
the area is going to be
0.2 times 1 square microns,

00:26:46.570 --> 00:26:49.100 align:middle line:90%
or 0.2 micron squared.

00:26:49.100 --> 00:26:50.440 align:middle line:90%
So that's the area.

00:26:50.440 --> 00:26:55.460 align:middle line:84%
Assuming we go back to ITRS,
assuming we are here roughly

00:26:55.460 --> 00:27:00.300 align:middle line:84%
in 2002 and the contact
resistivity is about times 10

00:27:00.300 --> 00:27:03.180 align:middle line:90%
to -7 ohm centimeter squared--

00:27:03.180 --> 00:27:06.090 align:middle line:84%
OK, so I'm assuming this as a
specific contact resistivity--

00:27:06.090 --> 00:27:09.660 align:middle line:84%
then can calculate the
resistance of just the drain

00:27:09.660 --> 00:27:10.620 align:middle line:90%
contact itself.

00:27:10.620 --> 00:27:12.990 align:middle line:84%
The resistance is just
that rho C divided

00:27:12.990 --> 00:27:14.490 align:middle line:90%
by the area of that contact.

00:27:14.490 --> 00:27:17.370 align:middle line:90%
And you get 100 ohms.

00:27:17.370 --> 00:27:21.450 align:middle line:84%
So the resistance of the current
just to flow through this

00:27:21.450 --> 00:27:24.330 align:middle line:84%
contact is 100 ohms
on the drain side.

00:27:24.330 --> 00:27:26.710 align:middle line:84%
It's going to be 100 ohms
on the source side, as well.

00:27:26.710 --> 00:27:30.810 align:middle line:84%
So that's 200 ohms right there,
just to give you a rough idea.

00:27:30.810 --> 00:27:34.750 align:middle line:84%
And this is equivalent to
the ITRS 2003 requirement.

00:27:34.750 --> 00:27:37.440 align:middle line:84%
So we're talking about 200
ohms of the total resistance

00:27:37.440 --> 00:27:40.140 align:middle line:84%
of the device just being
due to the contacts because

00:27:40.140 --> 00:27:40.860 align:middle line:90%
of the size.

00:27:40.860 --> 00:27:44.160 align:middle line:84%
And that's a reasonably
large resistance.

00:27:44.160 --> 00:27:46.410 align:middle line:84%
So we'll see that the
contact resistance actually

00:27:46.410 --> 00:27:47.492 align:middle line:90%
does dominate.

00:27:47.492 --> 00:27:48.950 align:middle line:84%
Again, what you
could say was, well

00:27:48.950 --> 00:27:51.420 align:middle line:84%
we'll just make the contact
wider, which you can do,

00:27:51.420 --> 00:27:53.710 align:middle line:84%
but that means your chip
ends up being larger.

00:27:53.710 --> 00:27:56.400 align:middle line:84%
You can't put as many
devices on the chip.

00:27:56.400 --> 00:27:58.650 align:middle line:84%
So there's a fundamental
trade-off here,

00:27:58.650 --> 00:28:01.120 align:middle line:84%
unless we can get this
rho C number down.

00:28:01.120 --> 00:28:04.560 align:middle line:84%
And that's exactly why this
number is dropping with time.

00:28:04.560 --> 00:28:06.210 align:middle line:84%
People want it to
drop because they

00:28:06.210 --> 00:28:09.070 align:middle line:84%
want to be able to continue to
scale the area of the device.

00:28:09.070 --> 00:28:10.140 align:middle line:90%
It's a problem, though.

00:28:10.140 --> 00:28:13.220 align:middle line:90%


00:28:13.220 --> 00:28:15.470 align:middle line:84%
On slide 13, I'm
showing you a structure.

00:28:15.470 --> 00:28:18.950 align:middle line:84%
If you are studying contacts
or if you ever make devices,

00:28:18.950 --> 00:28:21.900 align:middle line:84%
you always want to know, what
is my contact resistance?

00:28:21.900 --> 00:28:24.800 align:middle line:84%
And this is a classic
structure to actually measure

00:28:24.800 --> 00:28:26.030 align:middle line:90%
contact resistance.

00:28:26.030 --> 00:28:28.910 align:middle line:90%
It's called a Kelvin structure.

00:28:28.910 --> 00:28:30.410 align:middle line:84%
I took this
particular picture out

00:28:30.410 --> 00:28:33.710 align:middle line:90%
of your textbook, figure 11-35.

00:28:33.710 --> 00:28:36.770 align:middle line:84%
There's a reference to
it in your textbook,

00:28:36.770 --> 00:28:39.140 align:middle line:84%
a paper that an article that
talks about it in much more

00:28:39.140 --> 00:28:42.740 align:middle line:84%
detail on how it's
actually made.

00:28:42.740 --> 00:28:47.090 align:middle line:84%
On the left-hand side is showing
the mask layout in order to make

00:28:47.090 --> 00:28:48.960 align:middle line:90%
one of these structures.

00:28:48.960 --> 00:28:52.340 align:middle line:84%
And what you do is you have
these dark regions here

00:28:52.340 --> 00:28:55.250 align:middle line:84%
that are funny
shaped are considered

00:28:55.250 --> 00:28:58.160 align:middle line:84%
to be the N plus region
that you want to contact.

00:28:58.160 --> 00:29:00.530 align:middle line:84%
So that would be called
the n plus diffusion,

00:29:00.530 --> 00:29:03.050 align:middle line:90%
has this particular shape.

00:29:03.050 --> 00:29:06.855 align:middle line:84%
The dashed lines
represent the metal.

00:29:06.855 --> 00:29:08.230 align:middle line:84%
So that would be
the metal level.

00:29:08.230 --> 00:29:11.040 align:middle line:84%
So this is going to take at
least three masks to powder.

00:29:11.040 --> 00:29:14.460 align:middle line:84%
And these little square regions
with the X's going through them

00:29:14.460 --> 00:29:15.270 align:middle line:90%
are the contacts.

00:29:15.270 --> 00:29:20.700 align:middle line:84%
So that's the region where
one layer contacts the layer

00:29:20.700 --> 00:29:22.710 align:middle line:90%
above it or below it.

00:29:22.710 --> 00:29:24.590 align:middle line:84%
So this is sort
of a planar view.

00:29:24.590 --> 00:29:27.480 align:middle line:84%
If you want more of a bird's-eye
view of actually how it looks,

00:29:27.480 --> 00:29:29.070 align:middle line:84%
you can look on the
right-hand side.

00:29:29.070 --> 00:29:33.260 align:middle line:84%
And these L-shaped
brackets are made of metal.

00:29:33.260 --> 00:29:35.690 align:middle line:84%
So there's one
here and one here.

00:29:35.690 --> 00:29:40.220 align:middle line:84%
And basically you perform a
four-point kind of measurement.

00:29:40.220 --> 00:29:43.610 align:middle line:84%
What you're doing is this little
region here that is square

00:29:43.610 --> 00:29:46.940 align:middle line:84%
in the center that has a
dimension of L in one dimension

00:29:46.940 --> 00:29:49.220 align:middle line:84%
by L in the other-- so
this is an L by L squared--

00:29:49.220 --> 00:29:53.730 align:middle line:84%
the current then comes
through on this leg.

00:29:53.730 --> 00:29:55.760 align:middle line:84%
So the current flows
through the diffusion.

00:29:55.760 --> 00:29:59.300 align:middle line:84%
Then it flows up through the
square, the square contact.

00:29:59.300 --> 00:30:02.900 align:middle line:84%
And then it flows out through
probe number two on the metal.

00:30:02.900 --> 00:30:05.420 align:middle line:90%
So you put an ammeter here.

00:30:05.420 --> 00:30:08.282 align:middle line:84%
You put an ammeter
between probes 2 and 3,

00:30:08.282 --> 00:30:09.740 align:middle line:84%
and you measure
that current that's

00:30:09.740 --> 00:30:12.440 align:middle line:84%
flowing through
that square contact.

00:30:12.440 --> 00:30:17.090 align:middle line:84%
And then you put a volt
meter between probes 1 and 4

00:30:17.090 --> 00:30:20.090 align:middle line:84%
and you measure the voltage
drop across that face.

00:30:20.090 --> 00:30:23.548 align:middle line:84%
And then you just
divide V divided by I,

00:30:23.548 --> 00:30:25.340 align:middle line:84%
whatever you measure--
the measured voltage

00:30:25.340 --> 00:30:28.610 align:middle line:84%
between 1 and 4, divided by the
current flowing between 2 and 3.

00:30:28.610 --> 00:30:30.800 align:middle line:90%
And that is your resistance.

00:30:30.800 --> 00:30:32.720 align:middle line:84%
And that's going to
be equivalent to rho

00:30:32.720 --> 00:30:37.110 align:middle line:84%
C divided by the area of
the contact, L squared.

00:30:37.110 --> 00:30:38.750 align:middle line:84%
So this is a very
common way to do it.

00:30:38.750 --> 00:30:41.510 align:middle line:84%
You might say, well, why do
you go to the effort of having

00:30:41.510 --> 00:30:42.230 align:middle line:90%
separate probes?

00:30:42.230 --> 00:30:49.070 align:middle line:84%
Why don't you just measure
the current and the voltage

00:30:49.070 --> 00:30:51.463 align:middle line:90%
on the same probe points?

00:30:51.463 --> 00:30:53.630 align:middle line:84%
And the reason you do this
is because you don't want

00:30:53.630 --> 00:30:56.750 align:middle line:84%
to have extra contact
resistance, say, of your probes

00:30:56.750 --> 00:30:57.980 align:middle line:90%
going down.

00:30:57.980 --> 00:30:59.850 align:middle line:84%
And there's always a
voltage drop there.

00:30:59.850 --> 00:31:04.223 align:middle line:84%
So the probes through
which you force the current

00:31:04.223 --> 00:31:06.140 align:middle line:84%
are separate from the
probes through which you

00:31:06.140 --> 00:31:07.170 align:middle line:90%
measure the voltage.

00:31:07.170 --> 00:31:08.920 align:middle line:84%
So that, therefore,
you're only measuring,

00:31:08.920 --> 00:31:12.560 align:middle line:84%
really, the voltage drop
across this the contact face,

00:31:12.560 --> 00:31:14.010 align:middle line:90%
the square face.

00:31:14.010 --> 00:31:16.400 align:middle line:84%
So it's a very common
structure, the Kelvin structure,

00:31:16.400 --> 00:31:19.490 align:middle line:84%
you'll find on a lot of
test masks and test circuits

00:31:19.490 --> 00:31:22.370 align:middle line:84%
that people use to measure
the contact resistivity.

00:31:22.370 --> 00:31:25.250 align:middle line:90%


00:31:25.250 --> 00:31:28.820 align:middle line:84%
Here's an example
shown on slide 11

00:31:28.820 --> 00:31:31.250 align:middle line:84%
using a cross-bridge
Kelvin structure.

00:31:31.250 --> 00:31:34.640 align:middle line:84%
And you have a 1 micron
by 1 micron opening.

00:31:34.640 --> 00:31:37.340 align:middle line:84%
You find that you get a
current of 10 microamps

00:31:37.340 --> 00:31:40.550 align:middle line:84%
through the contact,
so that's I23,

00:31:40.550 --> 00:31:44.420 align:middle line:84%
when you measure a voltage
drop of about 320 microvolts.

00:31:44.420 --> 00:31:48.650 align:middle line:84%
What is the specific
contact resistivity?

00:31:48.650 --> 00:31:52.670 align:middle line:84%
So you just divide the voltage
drop divided by the current.

00:31:52.670 --> 00:31:54.560 align:middle line:84%
And that gives you
a resistance number.

00:31:54.560 --> 00:31:56.510 align:middle line:90%
In fact, that's 32 ohms.

00:31:56.510 --> 00:31:59.330 align:middle line:84%
And by definition, that's
equal to rho C divided

00:31:59.330 --> 00:32:01.110 align:middle line:90%
by the area of the contact.

00:32:01.110 --> 00:32:04.850 align:middle line:84%
So you can solve for rho C here
just by multiplying 32 ohms

00:32:04.850 --> 00:32:06.230 align:middle line:90%
by the area of the contact.

00:32:06.230 --> 00:32:10.198 align:middle line:84%
And you get 3.2 times 10 to
-7 ohm centimeter squared.

00:32:10.198 --> 00:32:11.990 align:middle line:84%
It's pretty close to
the ITRS requirements.

00:32:11.990 --> 00:32:13.023 align:middle line:90%
Still a little bit high.

00:32:13.023 --> 00:32:14.690 align:middle line:84%
It's still about a
factor of 2 too high.

00:32:14.690 --> 00:32:16.460 align:middle line:90%
But it just gives you an idea.

00:32:16.460 --> 00:32:19.620 align:middle line:84%
Typically you use several
different dimensions.

00:32:19.620 --> 00:32:23.690 align:middle line:84%
So you either use a 1 by 1, a
5 by 5, and a 10 by 10 square.

00:32:23.690 --> 00:32:25.940 align:middle line:84%
And you make sure you get
the same specific contact

00:32:25.940 --> 00:32:29.420 align:middle line:84%
resistivity number
over all of those

00:32:29.420 --> 00:32:32.480 align:middle line:84%
because sometimes you can
have current crowding effects.

00:32:32.480 --> 00:32:35.450 align:middle line:84%
When I drew it in this
picture here on page 13,

00:32:35.450 --> 00:32:38.120 align:middle line:84%
I said the current is uniformly
going through that face.

00:32:38.120 --> 00:32:39.950 align:middle line:84%
So you can imagine
a flow of water

00:32:39.950 --> 00:32:43.430 align:middle line:84%
uniformly flowing with the
same flux all across the face.

00:32:43.430 --> 00:32:45.170 align:middle line:84%
That may or may not
be true, depending

00:32:45.170 --> 00:32:47.630 align:middle line:84%
on the series resistance
of this N plus diffusion

00:32:47.630 --> 00:32:48.760 align:middle line:90%
and things like that.

00:32:48.760 --> 00:32:51.708 align:middle line:84%
So you want to use
different areas.

00:32:51.708 --> 00:32:54.250 align:middle line:84%
And for different size areas,
you should get the same number.

00:32:54.250 --> 00:32:56.833 align:middle line:84%
If you don't, then you probably
have current crowding effects,

00:32:56.833 --> 00:32:58.210 align:middle line:84%
and you need a
more sophisticated

00:32:58.210 --> 00:33:00.448 align:middle line:90%
two-dimensional model.

00:33:00.448 --> 00:33:02.490 align:middle line:84%
So that's a typical way
that people would measure

00:33:02.490 --> 00:33:05.960 align:middle line:90%
their contact resistance.

00:33:05.960 --> 00:33:08.560 align:middle line:84%
So that sort of introduces
the whole idea of scaling

00:33:08.560 --> 00:33:11.088 align:middle line:90%
and why we want to do this.

00:33:11.088 --> 00:33:12.880 align:middle line:84%
I want to bring up some
other requirements.

00:33:12.880 --> 00:33:14.290 align:middle line:84%
We said it's good,
it's important,

00:33:14.290 --> 00:33:15.665 align:middle line:84%
to make a
low-resistance contact.

00:33:15.665 --> 00:33:18.400 align:middle line:84%
But there are other
requirements besides that.

00:33:18.400 --> 00:33:20.815 align:middle line:84%
So clearly we need to have
a high doping concentration

00:33:20.815 --> 00:33:23.440 align:middle line:84%
at the interface that's going to
allow the electrical tunneling

00:33:23.440 --> 00:33:24.667 align:middle line:90%
to take place.

00:33:24.667 --> 00:33:27.250 align:middle line:84%
You need to be-- the interface
has to be free of contaminants,

00:33:27.250 --> 00:33:28.253 align:middle line:90%
as I mentioned.

00:33:28.253 --> 00:33:29.920 align:middle line:84%
You want to get rid
of the native oxide.

00:33:29.920 --> 00:33:32.890 align:middle line:84%
So you preferably use a metal
that will kind of eat away,

00:33:32.890 --> 00:33:35.710 align:middle line:84%
if there is any little native
oxide, that will eat it away.

00:33:35.710 --> 00:33:37.210 align:middle line:84%
And you clearly
don't want residues.

00:33:37.210 --> 00:33:39.280 align:middle line:84%
You don't want a lot of
excess carbon or other things

00:33:39.280 --> 00:33:40.330 align:middle line:84%
at the interface
because that's going

00:33:40.330 --> 00:33:42.580 align:middle line:84%
to cause an increase in
your contact resistance.

00:33:42.580 --> 00:33:45.670 align:middle line:84%
You don't want nitride
or oxide there.

00:33:45.670 --> 00:33:48.100 align:middle line:84%
That's one thing to get
low-contact resistance.

00:33:48.100 --> 00:33:52.660 align:middle line:84%
The second thing you want
is good thermal stability.

00:33:52.660 --> 00:33:56.380 align:middle line:84%
You don't want the contact
structure to change or degrade

00:33:56.380 --> 00:33:58.000 align:middle line:90%
in some way during the process.

00:33:58.000 --> 00:34:00.605 align:middle line:84%
After all, there will be
subsequent thermal processing.

00:34:00.605 --> 00:34:02.230 align:middle line:84%
Once you make those
contacts, you still

00:34:02.230 --> 00:34:04.870 align:middle line:84%
have to make all that
multi-level metal.

00:34:04.870 --> 00:34:06.760 align:middle line:84%
And those multi-level
metal schemes

00:34:06.760 --> 00:34:11.199 align:middle line:84%
involve annealing
steps or deposition

00:34:11.199 --> 00:34:14.090 align:middle line:84%
steps that could be in the
range of 400 to 500 degrees.

00:34:14.090 --> 00:34:16.090 align:middle line:84%
So you don't want anything
weird happening down

00:34:16.090 --> 00:34:19.420 align:middle line:84%
in your contact when
you heat the thing.

00:34:19.420 --> 00:34:23.469 align:middle line:84%
And in particular, you're also
very concerned about junction

00:34:23.469 --> 00:34:24.159 align:middle line:90%
leakage.

00:34:24.159 --> 00:34:26.889 align:middle line:84%
Remember, this electrical
metal, this metal,

00:34:26.889 --> 00:34:29.650 align:middle line:84%
is making electrical
contact to a PN junction.

00:34:29.650 --> 00:34:32.350 align:middle line:90%
This is an N plus P junction.

00:34:32.350 --> 00:34:34.090 align:middle line:90%
So you want it to be--

00:34:34.090 --> 00:34:35.830 align:middle line:84%
ultimately, this
N plus P junction

00:34:35.830 --> 00:34:39.699 align:middle line:84%
to have good junction
characteristics and low leakage

00:34:39.699 --> 00:34:42.969 align:middle line:84%
in the silicon
underneath the contact.

00:34:42.969 --> 00:34:45.600 align:middle line:84%
So here on slide 15,
I'm showing an example

00:34:45.600 --> 00:34:48.630 align:middle line:84%
of a figure I took out of a
text where something very bad

00:34:48.630 --> 00:34:51.989 align:middle line:84%
has happened, which is
called spiking of the metal.

00:34:51.989 --> 00:34:53.380 align:middle line:90%
And you can see what's happened.

00:34:53.380 --> 00:34:54.239 align:middle line:90%
This is the metal.

00:34:54.239 --> 00:34:56.139 align:middle line:90%
Aluminum is shown here.

00:34:56.139 --> 00:34:59.160 align:middle line:84%
And this is my N
plus drain or source.

00:34:59.160 --> 00:35:04.230 align:middle line:84%
And this chip has
been heated up.

00:35:04.230 --> 00:35:08.340 align:middle line:84%
And the aluminum has actually
spiked through the junction.

00:35:08.340 --> 00:35:10.500 align:middle line:84%
It's actually touching
now the P-type silicon.

00:35:10.500 --> 00:35:13.020 align:middle line:90%
So it's really shorted out.

00:35:13.020 --> 00:35:17.190 align:middle line:84%
It's essentially shorted
out this PN junction.

00:35:17.190 --> 00:35:18.390 align:middle line:90%
It's created a lot of voids.

00:35:18.390 --> 00:35:19.473 align:middle line:90%
And this is a big problem.

00:35:19.473 --> 00:35:23.120 align:middle line:84%
And that's because aluminum has
a finite solubility for silicon.

00:35:23.120 --> 00:35:25.400 align:middle line:84%
The silicon actually gets
sucked into the aluminum

00:35:25.400 --> 00:35:27.380 align:middle line:90%
and causes this spiking effect.

00:35:27.380 --> 00:35:30.440 align:middle line:84%
And this is one reason why, if
you have a very deep junction

00:35:30.440 --> 00:35:33.410 align:middle line:84%
that's many microns deep--
well, it would never

00:35:33.410 --> 00:35:35.510 align:middle line:84%
spike because it
never gets that deep.

00:35:35.510 --> 00:35:37.950 align:middle line:84%
But now the junctions
are very shallow,

00:35:37.950 --> 00:35:39.710 align:middle line:84%
they're 0.1 micron
or less, people never

00:35:39.710 --> 00:35:42.090 align:middle line:84%
put aluminum directly
in contact with silicon.

00:35:42.090 --> 00:35:45.980 align:middle line:84%
So in the old days, this is
the way people made contacts.

00:35:45.980 --> 00:35:48.440 align:middle line:84%
Today if you do this with
any kind of reasonably

00:35:48.440 --> 00:35:51.470 align:middle line:84%
shallow junction, when you
go to heat the thing up

00:35:51.470 --> 00:35:53.063 align:middle line:84%
to do the final
forming gas anneal,

00:35:53.063 --> 00:35:54.480 align:middle line:84%
you're going to
spike the junction

00:35:54.480 --> 00:35:56.105 align:middle line:84%
and you're going to
destroy the device.

00:35:56.105 --> 00:35:58.430 align:middle line:90%


00:35:58.430 --> 00:36:01.660 align:middle line:84%
Here's an example
on slide 16 of what

00:36:01.660 --> 00:36:04.468 align:middle line:84%
happens in some extreme
cases of junction spiking.

00:36:04.468 --> 00:36:06.760 align:middle line:84%
What we're actually looking
at-- what I showed you here

00:36:06.760 --> 00:36:09.250 align:middle line:84%
in the prior slide, this
is a cross-section view.

00:36:09.250 --> 00:36:14.350 align:middle line:84%
You can see the way the aluminum
has spiked into the silicon.

00:36:14.350 --> 00:36:17.200 align:middle line:84%
In fact, if you
look in plan view

00:36:17.200 --> 00:36:19.810 align:middle line:84%
at a tilt angle of
about 45 degrees,

00:36:19.810 --> 00:36:21.220 align:middle line:90%
this is a contact region.

00:36:21.220 --> 00:36:24.580 align:middle line:90%
And around it is oxide.

00:36:24.580 --> 00:36:26.470 align:middle line:90%
These are 5 by 5 micron holes.

00:36:26.470 --> 00:36:28.360 align:middle line:90%
So they're fairly large.

00:36:28.360 --> 00:36:30.787 align:middle line:84%
These were annealed by
rapid thermal processing.

00:36:30.787 --> 00:36:32.620 align:middle line:84%
And then the aluminum
layer was removed just

00:36:32.620 --> 00:36:34.690 align:middle line:90%
to see what happened.

00:36:34.690 --> 00:36:37.600 align:middle line:84%
And in fact, this was annealed
for 10 minutes at 425.

00:36:37.600 --> 00:36:40.120 align:middle line:84%
So this was aluminum directly
in contact with silicon

00:36:40.120 --> 00:36:41.530 align:middle line:90%
at 10 minutes at 425.

00:36:41.530 --> 00:36:45.550 align:middle line:84%
You can see it's created all
these voids because there's

00:36:45.550 --> 00:36:47.950 align:middle line:84%
a solubility of
silicon in aluminum.

00:36:47.950 --> 00:36:49.750 align:middle line:84%
Silicon from the
substrate has actually

00:36:49.750 --> 00:36:51.130 align:middle line:90%
gone up into the aluminum.

00:36:51.130 --> 00:36:54.280 align:middle line:84%
And it leaves
behind voids, which

00:36:54.280 --> 00:36:56.860 align:middle line:84%
end up being filled by
the overlying aluminum.

00:36:56.860 --> 00:36:59.720 align:middle line:84%
And when you etch the aluminum
off, you see all these holes.

00:36:59.720 --> 00:37:02.500 align:middle line:90%


00:37:02.500 --> 00:37:04.510 align:middle line:84%
And if you do RTP at a
lower temperature here,

00:37:04.510 --> 00:37:07.960 align:middle line:84%
350 for ten seconds, you don't
see nearly as many spikes,

00:37:07.960 --> 00:37:09.280 align:middle line:90%
nearly as many holes.

00:37:09.280 --> 00:37:11.320 align:middle line:84%
But 350 for ten
seconds is really

00:37:11.320 --> 00:37:14.250 align:middle line:84%
too low for any
backend processing.

00:37:14.250 --> 00:37:16.630 align:middle line:84%
So this is why you never
put aluminum directly

00:37:16.630 --> 00:37:19.272 align:middle line:84%
in contact with
silicon unless you're

00:37:19.272 --> 00:37:21.730 align:middle line:84%
making a really deep junction,
like a micron-deep junction,

00:37:21.730 --> 00:37:22.938 align:middle line:90%
you have some kind of device.

00:37:22.938 --> 00:37:26.080 align:middle line:84%
But in MOSFETs today, the
typical source drain junctions

00:37:26.080 --> 00:37:28.460 align:middle line:90%
are 0.1 microns.

00:37:28.460 --> 00:37:34.362 align:middle line:84%
So this is sort of a classic
case of junction spiking.

00:37:34.362 --> 00:37:36.070 align:middle line:84%
There are a couple of
different solutions

00:37:36.070 --> 00:37:37.737 align:middle line:84%
people have come up
with over the years.

00:37:37.737 --> 00:37:40.480 align:middle line:84%
One of them is shown
here on slide 17,

00:37:40.480 --> 00:37:41.800 align:middle line:90%
although it's not perfect.

00:37:41.800 --> 00:37:45.640 align:middle line:84%
People had the idea of, well,
don't use pure aluminum.

00:37:45.640 --> 00:37:50.170 align:middle line:84%
Use an alloy of aluminum
with 1% to 2% silicon.

00:37:50.170 --> 00:37:51.820 align:middle line:84%
And since we said
that the silicon is

00:37:51.820 --> 00:37:56.210 align:middle line:84%
soluble in the aluminum, if you
put silicon in the metal itself,

00:37:56.210 --> 00:37:58.570 align:middle line:84%
so when you sputter, you
don't sputter pure aluminum.

00:37:58.570 --> 00:38:00.940 align:middle line:84%
You sputter an alloy of
aluminum and silicon.

00:38:00.940 --> 00:38:03.190 align:middle line:84%
Then you think, well,
OK, it won't suck up

00:38:03.190 --> 00:38:05.500 align:middle line:84%
any silicon from the
substrate because it's already

00:38:05.500 --> 00:38:07.450 align:middle line:90%
in equilibrium.

00:38:07.450 --> 00:38:11.500 align:middle line:84%
It's already got all the silicon
it needs, the aluminum eutectic.

00:38:11.500 --> 00:38:12.610 align:middle line:90%
So it's not a problem.

00:38:12.610 --> 00:38:17.800 align:middle line:84%
But it's still a bit of an
issue is that the silicon itself

00:38:17.800 --> 00:38:20.860 align:middle line:84%
can actually precipitate out
of the aluminum as an example.

00:38:20.860 --> 00:38:27.010 align:middle line:84%
It's been heated, and then
they remove the aluminum film.

00:38:27.010 --> 00:38:28.990 align:middle line:84%
And you get these little
silica precipitates,

00:38:28.990 --> 00:38:31.750 align:middle line:84%
which can increase the specific
contact resistance, especially

00:38:31.750 --> 00:38:32.500 align:middle line:90%
in N-type silicon.

00:38:32.500 --> 00:38:36.460 align:middle line:84%
So it's making an aluminum
1% silicon contact

00:38:36.460 --> 00:38:38.650 align:middle line:84%
to silicon, which was,
again, after pure aluminum,

00:38:38.650 --> 00:38:41.950 align:middle line:84%
people did the aluminum
1% silicon solution.

00:38:41.950 --> 00:38:43.993 align:middle line:84%
Was a solution
maybe in the 1980s

00:38:43.993 --> 00:38:46.660 align:middle line:84%
or so, but again, it's still not
something that people typically

00:38:46.660 --> 00:38:49.790 align:middle line:84%
do because you're going to get
a higher contact resistance.

00:38:49.790 --> 00:38:51.280 align:middle line:90%
And you can still get spiking.

00:38:51.280 --> 00:38:55.100 align:middle line:90%
It's not a perfect solution.

00:38:55.100 --> 00:38:59.980 align:middle line:84%
But that was one solution that
people did use at one point.

00:38:59.980 --> 00:39:02.318 align:middle line:84%
The way people go
today is to form

00:39:02.318 --> 00:39:03.610 align:middle line:90%
what they call a barrier layer.

00:39:03.610 --> 00:39:06.250 align:middle line:84%
And a barrier layer does
exactly what the name says.

00:39:06.250 --> 00:39:11.290 align:middle line:84%
It forms a barrier between
this aluminum and the silicon.

00:39:11.290 --> 00:39:15.250 align:middle line:84%
The barrier has a very low
specific contact resistivity.

00:39:15.250 --> 00:39:16.870 align:middle line:84%
So it still makes
a good contact,

00:39:16.870 --> 00:39:19.210 align:middle line:84%
but it doesn't allow the
aluminum or the silicon

00:39:19.210 --> 00:39:20.360 align:middle line:90%
to talk to each other.

00:39:20.360 --> 00:39:22.690 align:middle line:84%
So you cannot get
this void formation.

00:39:22.690 --> 00:39:24.100 align:middle line:90%
You can't get the spiking.

00:39:24.100 --> 00:39:28.780 align:middle line:84%
So typical barrier layers might
be a thin layer of titanium,

00:39:28.780 --> 00:39:32.260 align:middle line:84%
say 1,000 angstroms of
titanium is often used,

00:39:32.260 --> 00:39:36.370 align:middle line:84%
or use sputter tie tungsten
or maybe tie silicide.

00:39:36.370 --> 00:39:38.590 align:middle line:84%
So in between the
heavily doped silicon,

00:39:38.590 --> 00:39:42.460 align:middle line:84%
you now have an inter
layer of this material

00:39:42.460 --> 00:39:43.580 align:middle line:90%
that forms a barrier.

00:39:43.580 --> 00:39:45.670 align:middle line:84%
So this prevents the
chemical interdiffusion

00:39:45.670 --> 00:39:48.220 align:middle line:84%
between the silicon
and the aluminum.

00:39:48.220 --> 00:39:50.380 align:middle line:90%
Generally has low stress.

00:39:50.380 --> 00:39:52.390 align:middle line:84%
You pick a material
that has good adhesion

00:39:52.390 --> 00:39:54.700 align:middle line:90%
so it doesn't peel off.

00:39:54.700 --> 00:39:58.240 align:middle line:84%
And of course, good electrical
conductivity and low contact

00:39:58.240 --> 00:39:59.720 align:middle line:90%
resistance silicon aluminum.

00:39:59.720 --> 00:40:02.100 align:middle line:84%
So that's to satisfy
all of these things.

00:40:02.100 --> 00:40:06.500 align:middle line:84%
And these materials,
titanium and tungsten,

00:40:06.500 --> 00:40:08.300 align:middle line:84%
have reasonable
contact resistivity.

00:40:08.300 --> 00:40:11.420 align:middle line:84%
They are still not low enough
to meet a lot of the ITRS

00:40:11.420 --> 00:40:14.780 align:middle line:84%
requirements in the future,
but today they're good enough.

00:40:14.780 --> 00:40:17.880 align:middle line:90%


00:40:17.880 --> 00:40:19.350 align:middle line:90%
Oh, this is just--

00:40:19.350 --> 00:40:22.470 align:middle line:84%
on slide 19, I took from
a different textbook.

00:40:22.470 --> 00:40:24.600 align:middle line:84%
This is a figure
from Mayer and Lau.

00:40:24.600 --> 00:40:27.210 align:middle line:84%
I had mentioned Mayer--Lau
textbook at the very beginning

00:40:27.210 --> 00:40:27.970 align:middle line:90%
of this course.

00:40:27.970 --> 00:40:30.160 align:middle line:90%
So you have a reference to it.

00:40:30.160 --> 00:40:33.480 align:middle line:84%
And this is just an
example of in his book

00:40:33.480 --> 00:40:37.398 align:middle line:84%
how he's saying titanium may
work as a sacrificial barrier.

00:40:37.398 --> 00:40:38.940 align:middle line:84%
May or may not
exactly work this way,

00:40:38.940 --> 00:40:41.760 align:middle line:84%
but it's one
potential methodology.

00:40:41.760 --> 00:40:43.860 align:middle line:84%
You can imagine having
a thin layer of titanium

00:40:43.860 --> 00:40:46.050 align:middle line:90%
with aluminum on top.

00:40:46.050 --> 00:40:48.870 align:middle line:84%
When you heat the
structure, you may

00:40:48.870 --> 00:40:54.510 align:middle line:84%
get formation of TiAl3
for some time and portion.

00:40:54.510 --> 00:40:56.250 align:middle line:84%
And then you heat it
a little bit longer

00:40:56.250 --> 00:41:00.390 align:middle line:84%
and all the titanium
is consumed.

00:41:00.390 --> 00:41:03.330 align:middle line:84%
And then here at
this point in D,

00:41:03.330 --> 00:41:06.840 align:middle line:84%
you can start to get
the aluminum incursion.

00:41:06.840 --> 00:41:09.510 align:middle line:84%
So the idea is you put
down enough titanium

00:41:09.510 --> 00:41:12.520 align:middle line:84%
that you're not going to end
up with a spiking problem.

00:41:12.520 --> 00:41:16.500 align:middle line:84%
And typically, if you want to
anneal a typical forming gas

00:41:16.500 --> 00:41:19.650 align:middle line:84%
anneal, 450 or so, 1,000
angstroms of titanium

00:41:19.650 --> 00:41:21.990 align:middle line:84%
seems to be adequate
barrier layer.

00:41:21.990 --> 00:41:24.795 align:middle line:84%
But again, it depends on
your backend thermal budget.

00:41:24.795 --> 00:41:28.660 align:middle line:90%


00:41:28.660 --> 00:41:30.760 align:middle line:84%
Slide 20 is just
another example saying

00:41:30.760 --> 00:41:33.520 align:middle line:84%
that depending on the barrier
layer that you choose,

00:41:33.520 --> 00:41:35.450 align:middle line:90%
you have to be careful.

00:41:35.450 --> 00:41:37.750 align:middle line:84%
A lot of these materials
for barrier layers.

00:41:37.750 --> 00:41:41.500 align:middle line:84%
Ti-tungsten or Ti-nitride
are very often--

00:41:41.500 --> 00:41:43.480 align:middle line:84%
they're polycrystalline,
basically.

00:41:43.480 --> 00:41:45.520 align:middle line:84%
And what can happen
if you're not careful

00:41:45.520 --> 00:41:49.210 align:middle line:84%
is the aluminum can actually
diffuse through the long grain

00:41:49.210 --> 00:41:52.570 align:middle line:84%
boundaries and can still
make its way to the silicon

00:41:52.570 --> 00:41:54.830 align:middle line:90%
and end up causing problems.

00:41:54.830 --> 00:41:57.580 align:middle line:84%
So people often, when they
deposit these material,

00:41:57.580 --> 00:42:00.280 align:middle line:84%
they sometimes sputter
them in an ambient

00:42:00.280 --> 00:42:02.500 align:middle line:90%
that has some impurity.

00:42:02.500 --> 00:42:04.750 align:middle line:84%
Could be nitrogen, is
one of the most common.

00:42:04.750 --> 00:42:08.710 align:middle line:84%
Sometimes people actually
do sputter Ti-tungsten,

00:42:08.710 --> 00:42:12.190 align:middle line:84%
and then they expose it to air
for a period, a few minutes

00:42:12.190 --> 00:42:13.030 align:middle line:90%
or half an hour.

00:42:13.030 --> 00:42:14.680 align:middle line:84%
Then they put the
aluminum on top.

00:42:14.680 --> 00:42:18.460 align:middle line:84%
The idea is that these either
nitrogen or oxygen impurities

00:42:18.460 --> 00:42:21.190 align:middle line:84%
are going to end up being
very high concentration

00:42:21.190 --> 00:42:23.470 align:middle line:90%
in these grain boundaries.

00:42:23.470 --> 00:42:25.090 align:middle line:84%
This is called a
stuffed barrier.

00:42:25.090 --> 00:42:26.740 align:middle line:84%
By stuffing the
grain boundaries,

00:42:26.740 --> 00:42:29.590 align:middle line:84%
it helps prevent the
aluminum from diffusing down

00:42:29.590 --> 00:42:32.230 align:middle line:90%
in and getting to the silicon.

00:42:32.230 --> 00:42:34.122 align:middle line:84%
So again, we're going
to do a heat treatment.

00:42:34.122 --> 00:42:35.830 align:middle line:84%
You're going to put
aluminum on top here.

00:42:35.830 --> 00:42:39.640 align:middle line:84%
You need to try to prevent
the incursion of the aluminum.

00:42:39.640 --> 00:42:42.715 align:middle line:84%
So how do you do the
sputtering of the barrier layer

00:42:42.715 --> 00:42:43.840 align:middle line:90%
is actually very important.

00:42:43.840 --> 00:42:45.760 align:middle line:84%
What ambient you
use will determine

00:42:45.760 --> 00:42:48.190 align:middle line:84%
whether it's a good barrier
layer or a poor barrier layer

00:42:48.190 --> 00:42:50.320 align:middle line:84%
and how long it's
going to stand up.

00:42:50.320 --> 00:42:54.725 align:middle line:84%
So a lot of it's quasi
empirical, just testing of what

00:42:54.725 --> 00:42:55.225 align:middle line:90%
works.

00:42:55.225 --> 00:42:58.720 align:middle line:90%


00:42:58.720 --> 00:43:03.520 align:middle line:84%
On this page 21, I'm
showing a classic process

00:43:03.520 --> 00:43:05.770 align:middle line:84%
that was developed a
number of years ago called

00:43:05.770 --> 00:43:06.825 align:middle line:90%
the salicide process.

00:43:06.825 --> 00:43:08.950 align:middle line:84%
And this is something you
need to be familiar with.

00:43:08.950 --> 00:43:14.980 align:middle line:84%
Salicide stands for-- the sal
comes from self-aligned silicide

00:43:14.980 --> 00:43:15.610 align:middle line:90%
process.

00:43:15.610 --> 00:43:17.110 align:middle line:84%
And you'll see when
we go through it

00:43:17.110 --> 00:43:19.270 align:middle line:90%
what we mean by self-aligned.

00:43:19.270 --> 00:43:23.245 align:middle line:84%
So we start here with our naked
device ready to be contacted.

00:43:23.245 --> 00:43:24.370 align:middle line:90%
We don't have any contacts.

00:43:24.370 --> 00:43:26.200 align:middle line:84%
We just have N plus
source and drain.

00:43:26.200 --> 00:43:29.870 align:middle line:84%
And you have a heavily
doped polysilicon layer.

00:43:29.870 --> 00:43:32.000 align:middle line:90%
We then form our oxide spacers.

00:43:32.000 --> 00:43:34.010 align:middle line:84%
So you know how to form
sidewall spacers now.

00:43:34.010 --> 00:43:38.510 align:middle line:84%
You deposit a conformal layer of
SiO2, say low temperature oxide,

00:43:38.510 --> 00:43:41.330 align:middle line:84%
and then you etch it
back anisotropically.

00:43:41.330 --> 00:43:44.060 align:middle line:84%
So you end up with these little
stringers on the edges, which

00:43:44.060 --> 00:43:45.290 align:middle line:90%
we call sidewalls.

00:43:45.290 --> 00:43:47.450 align:middle line:90%
OK, those are critical.

00:43:47.450 --> 00:43:51.140 align:middle line:84%
So they're going to form sort
of a blocking region, which

00:43:51.140 --> 00:43:53.660 align:middle line:84%
will be critical in
the salicide process.

00:43:53.660 --> 00:43:56.270 align:middle line:84%
We then deposit metal,
M, over everything.

00:43:56.270 --> 00:43:58.850 align:middle line:84%
So you can do some
kind of PBD deposition.

00:43:58.850 --> 00:44:01.970 align:middle line:84%
And here's your titanium layer
that goes everywhere, obviously

00:44:01.970 --> 00:44:03.480 align:middle line:90%
across the whole wafer.

00:44:03.480 --> 00:44:07.230 align:middle line:84%
And then you do a magic anneal
at the right temperature.

00:44:07.230 --> 00:44:10.110 align:middle line:84%
And this anneal is
such that wherever

00:44:10.110 --> 00:44:12.690 align:middle line:84%
the metal, the titanium,
is contacting the silicon,

00:44:12.690 --> 00:44:16.777 align:middle line:84%
you form a metal
silicide, say TiSi2.

00:44:16.777 --> 00:44:18.360 align:middle line:84%
So it only forms
where it's in contact

00:44:18.360 --> 00:44:20.730 align:middle line:84%
with silicon, which is right
here, this dark region,

00:44:20.730 --> 00:44:21.840 align:middle line:90%
and on top of the gate.

00:44:21.840 --> 00:44:24.390 align:middle line:84%
So on the source, gate, and
drains where it's in contact

00:44:24.390 --> 00:44:27.780 align:middle line:84%
with silicon-- remember, the
polysilicon gate will also

00:44:27.780 --> 00:44:29.160 align:middle line:90%
react--

00:44:29.160 --> 00:44:31.320 align:middle line:90%
you have titanium disilicide.

00:44:31.320 --> 00:44:35.460 align:middle line:84%
Everywhere else you have still
remaining some unreacted metal.

00:44:35.460 --> 00:44:37.350 align:middle line:90%
So it's still sitting there.

00:44:37.350 --> 00:44:41.580 align:middle line:84%
Now, a key to the processes that
you dip it in some solution--

00:44:41.580 --> 00:44:44.910 align:middle line:84%
sometimes it's HF,
sometimes it's sulfuric--

00:44:44.910 --> 00:44:48.300 align:middle line:84%
that removes unreacted
metal but that does not

00:44:48.300 --> 00:44:51.670 align:middle line:90%
etch the silicide itself.

00:44:51.670 --> 00:44:55.050 align:middle line:84%
So we've created a material, a
titanium di silicide or a metal

00:44:55.050 --> 00:44:59.580 align:middle line:84%
disilicide, that because of
the virtue of its chemical

00:44:59.580 --> 00:45:02.730 align:middle line:84%
structure, it now stands
up to the etch, which will

00:45:02.730 --> 00:45:04.260 align:middle line:90%
remove the unreacted metal.

00:45:04.260 --> 00:45:07.050 align:middle line:84%
So the reason it's
called self-aligned,

00:45:07.050 --> 00:45:10.110 align:middle line:84%
you notice I did not have
to do any photolithography

00:45:10.110 --> 00:45:12.060 align:middle line:90%
to pattern this metal.

00:45:12.060 --> 00:45:14.550 align:middle line:84%
The metal was deposited
over the entire chip.

00:45:14.550 --> 00:45:17.280 align:middle line:84%
It was reacted with the
silicon, and then it was just

00:45:17.280 --> 00:45:18.870 align:middle line:90%
etched off in a blanket etch.

00:45:18.870 --> 00:45:23.350 align:middle line:84%
So there's no photoresist step
here to pattern this metal.

00:45:23.350 --> 00:45:25.720 align:middle line:84%
That's why it's self-aligned
because wherever there's

00:45:25.720 --> 00:45:28.570 align:middle line:84%
exposed silicon, you
will end up with a metal

00:45:28.570 --> 00:45:31.030 align:middle line:84%
contact, a line to
that exposed silicon,

00:45:31.030 --> 00:45:34.970 align:middle line:84%
without having to do
another lithography step.

00:45:34.970 --> 00:45:37.900 align:middle line:84%
So this was a really
great invention.

00:45:37.900 --> 00:45:40.160 align:middle line:84%
You would save yourself
an alignment tolerance.

00:45:40.160 --> 00:45:42.190 align:middle line:90%
So it's very good alignment.

00:45:42.190 --> 00:45:45.190 align:middle line:84%
You form a low resistance
contact to the source drain

00:45:45.190 --> 00:45:47.650 align:middle line:90%
and to the gate simultaneously.

00:45:47.650 --> 00:45:49.390 align:middle line:84%
So this kind of a
salicide process

00:45:49.390 --> 00:45:53.350 align:middle line:84%
was a big breakthrough
in CMOS technology,

00:45:53.350 --> 00:45:55.045 align:middle line:90%
say around the 80s or so.

00:45:55.045 --> 00:45:58.360 align:middle line:90%


00:45:58.360 --> 00:46:01.480 align:middle line:84%
Slide 22, I just took
from a different text.

00:46:01.480 --> 00:46:03.430 align:middle line:84%
It has a slightly
different type of drawing.

00:46:03.430 --> 00:46:04.810 align:middle line:90%
Maybe it's easier to understand.

00:46:04.810 --> 00:46:07.210 align:middle line:84%
They have a little
different notation.

00:46:07.210 --> 00:46:08.480 align:middle line:90%
It's the exact same process.

00:46:08.480 --> 00:46:09.970 align:middle line:90%
It's the basic salicide process.

00:46:09.970 --> 00:46:11.620 align:middle line:84%
You have an N plus
source and drain.

00:46:11.620 --> 00:46:14.170 align:middle line:90%
You form your spacers.

00:46:14.170 --> 00:46:16.510 align:middle line:90%
You react the metal.

00:46:16.510 --> 00:46:17.530 align:middle line:90%
It does not react.

00:46:17.530 --> 00:46:20.050 align:middle line:84%
Hopefully it does not
creep up the sidewall,

00:46:20.050 --> 00:46:21.400 align:middle line:90%
which is a problem.

00:46:21.400 --> 00:46:24.460 align:middle line:84%
You then selectively remove
the unreacted metal form,

00:46:24.460 --> 00:46:26.200 align:middle line:84%
put your dielectric
down everywhere else,

00:46:26.200 --> 00:46:28.510 align:middle line:90%
and put in your metal contacts.

00:46:28.510 --> 00:46:33.475 align:middle line:84%
So that's a basic metal contact
scheme that people use today.

00:46:33.475 --> 00:46:36.270 align:middle line:90%


00:46:36.270 --> 00:46:37.290 align:middle line:90%
What do people use?

00:46:37.290 --> 00:46:38.780 align:middle line:84%
Which materials
are commonly used?

00:46:38.780 --> 00:46:41.930 align:middle line:84%
Well, some of them are
shown here on slide 23.

00:46:41.930 --> 00:46:47.090 align:middle line:84%
The first one that was used
historically was Ti-silicide.

00:46:47.090 --> 00:46:50.300 align:middle line:84%
Ti-silicide was very good
because it has a low resistivity

00:46:50.300 --> 00:46:51.770 align:middle line:90%
phase.

00:46:51.770 --> 00:46:56.870 align:middle line:84%
And we're talking about maybe
a 15 micro ohm centimeter

00:46:56.870 --> 00:47:00.440 align:middle line:84%
for a particular phase that's
formed on a particular type

00:47:00.440 --> 00:47:03.140 align:middle line:90%
of annealing.

00:47:03.140 --> 00:47:04.860 align:middle line:84%
There's a little
difficulty, though.

00:47:04.860 --> 00:47:07.940 align:middle line:84%
As people make the polysilicon
gate length shorter,

00:47:07.940 --> 00:47:11.115 align:middle line:84%
it's harder and harder to get
this particular phase to form.

00:47:11.115 --> 00:47:13.490 align:middle line:84%
This is called the narrow line
effect or the narrow width

00:47:13.490 --> 00:47:14.150 align:middle line:90%
effect.

00:47:14.150 --> 00:47:16.280 align:middle line:90%
Usually the narrow line effect.

00:47:16.280 --> 00:47:18.773 align:middle line:84%
Ti-silicide also has a
tendency to agglomerate

00:47:18.773 --> 00:47:20.940 align:middle line:84%
when it's very thin at
higher annealing temperature.

00:47:20.940 --> 00:47:22.460 align:middle line:84%
So it's not that
thermally stable.

00:47:22.460 --> 00:47:25.250 align:middle line:84%
So for a number of reasons,
particularly the narrow line

00:47:25.250 --> 00:47:28.760 align:middle line:84%
effect, industry moved
a number of years

00:47:28.760 --> 00:47:31.730 align:middle line:84%
ago primarily from Ti-silicide,
although some people may still

00:47:31.730 --> 00:47:33.620 align:middle line:90%
use it, to cobalt bisilicide.

00:47:33.620 --> 00:47:36.330 align:middle line:84%
It does not have that
narrow line effect,

00:47:36.330 --> 00:47:40.472 align:middle line:84%
but it gives you a slightly
higher resistivity.

00:47:40.472 --> 00:47:42.680 align:middle line:84%
It's a little more sensitive
to surface contaminants.

00:47:42.680 --> 00:47:45.830 align:middle line:84%
The beauty of Ti is,
again, the titanium

00:47:45.830 --> 00:47:47.780 align:middle line:84%
eats its way through
things, through oxides,

00:47:47.780 --> 00:47:48.860 align:middle line:90%
sort of reduce oxides.

00:47:48.860 --> 00:47:53.660 align:middle line:84%
So cobalt, you have to have
a really clean interface.

00:47:53.660 --> 00:47:55.880 align:middle line:84%
Cobalt has a little less
lateral encroachment

00:47:55.880 --> 00:47:57.080 align:middle line:90%
over the oxide spacer.

00:47:57.080 --> 00:47:59.400 align:middle line:90%
And I'll show pictures of that.

00:47:59.400 --> 00:48:02.630 align:middle line:84%
So cobalt was used and is
still used in some processes.

00:48:02.630 --> 00:48:05.240 align:middle line:84%
The latest silicide that people
are exploring in research

00:48:05.240 --> 00:48:07.640 align:middle line:84%
and development-- and at
some point will probably

00:48:07.640 --> 00:48:11.230 align:middle line:84%
be in production--
is nickel silicide.

00:48:11.230 --> 00:48:13.660 align:middle line:84%
Nickel silicide has the
lowest silicon consumption.

00:48:13.660 --> 00:48:15.310 align:middle line:84%
In order to do this,
you need to react

00:48:15.310 --> 00:48:17.170 align:middle line:84%
and you need to consume
some of the silicon.

00:48:17.170 --> 00:48:18.400 align:middle line:84%
And you don't want
to consume very much

00:48:18.400 --> 00:48:19.760 align:middle line:90%
of that shallow junction.

00:48:19.760 --> 00:48:21.700 align:middle line:84%
So nickel is good
because of that.

00:48:21.700 --> 00:48:23.920 align:middle line:84%
It can be formed at
very low temperatures.

00:48:23.920 --> 00:48:27.370 align:middle line:84%
And it doesn't have very bad
narrow line effect for silicide

00:48:27.370 --> 00:48:28.120 align:middle line:90%
in the gate.

00:48:28.120 --> 00:48:31.588 align:middle line:84%
Big problem with
nickel is you have

00:48:31.588 --> 00:48:33.130 align:middle line:84%
to be careful of
your thermal budget.

00:48:33.130 --> 00:48:34.172 align:middle line:90%
And watch out for nickel.

00:48:34.172 --> 00:48:36.430 align:middle line:84%
Nickel is a very fast
diffuser, remember, in silicon.

00:48:36.430 --> 00:48:39.190 align:middle line:90%
Nickel is also a deep level.

00:48:39.190 --> 00:48:43.510 align:middle line:84%
So nickel contamination of
equipment and of the wafers

00:48:43.510 --> 00:48:44.470 align:middle line:90%
is an issue.

00:48:44.470 --> 00:48:46.090 align:middle line:84%
And people need
to deal with this.

00:48:46.090 --> 00:48:49.690 align:middle line:84%
But nickel silicide is
becoming more and more

00:48:49.690 --> 00:48:52.540 align:middle line:84%
prevalent in research
and development.

00:48:52.540 --> 00:48:55.140 align:middle line:90%


00:48:55.140 --> 00:48:58.590 align:middle line:84%
I mentioned there was a
problem with this encroachment

00:48:58.590 --> 00:48:59.880 align:middle line:90%
over the spacer.

00:48:59.880 --> 00:49:05.280 align:middle line:84%
And this is illustrated
on slide 24.

00:49:05.280 --> 00:49:07.170 align:middle line:84%
On the left-hand
side, I'm showing

00:49:07.170 --> 00:49:12.690 align:middle line:84%
the case of a cobalt
disilicide formation

00:49:12.690 --> 00:49:14.730 align:middle line:84%
where it's the
metal that diffuses.

00:49:14.730 --> 00:49:17.340 align:middle line:84%
So you can imagine that
you have this metal that's

00:49:17.340 --> 00:49:18.402 align:middle line:90%
deposited everywhere.

00:49:18.402 --> 00:49:20.610 align:middle line:84%
And you're going to form a
reaction between the metal

00:49:20.610 --> 00:49:22.130 align:middle line:90%
and the silicon.

00:49:22.130 --> 00:49:24.560 align:middle line:84%
The question is, how
does the reaction occur?

00:49:24.560 --> 00:49:27.140 align:middle line:84%
Does the metal
diffuse in and meet

00:49:27.140 --> 00:49:30.180 align:middle line:84%
the silicon down at this
interface or vice versa?

00:49:30.180 --> 00:49:34.760 align:middle line:84%
Well, it depends on the
particular type of silicide.

00:49:34.760 --> 00:49:36.350 align:middle line:84%
In the case of
cobalt disilicide,

00:49:36.350 --> 00:49:40.010 align:middle line:84%
the metal diffuses through the
silicide into this interface

00:49:40.010 --> 00:49:43.590 align:middle line:90%
here and then reacts.

00:49:43.590 --> 00:49:46.740 align:middle line:84%
So you get silicide reaction or
formation at the bottom here.

00:49:46.740 --> 00:49:49.890 align:middle line:84%
So you're less likely
to have creep up.

00:49:49.890 --> 00:49:52.800 align:middle line:84%
In the case of
titanium disilicide,

00:49:52.800 --> 00:49:54.810 align:middle line:84%
in fact, what happens
is the silicon

00:49:54.810 --> 00:49:57.210 align:middle line:84%
is what's the fast diffuser
through the Ti-silicide.

00:49:57.210 --> 00:49:59.770 align:middle line:84%
It diffuses up and
meets the metal.

00:49:59.770 --> 00:50:02.460 align:middle line:84%
So if you do it long
enough and if you

00:50:02.460 --> 00:50:04.710 align:middle line:84%
have a short enough spacer,
you can see the disilicide

00:50:04.710 --> 00:50:07.680 align:middle line:84%
can creep and grow
up from the source

00:50:07.680 --> 00:50:09.570 align:middle line:90%
and drain down from the gate.

00:50:09.570 --> 00:50:11.700 align:middle line:84%
And eventually you
may actually bridge.

00:50:11.700 --> 00:50:13.950 align:middle line:84%
And then you have a big
problem because then your gate

00:50:13.950 --> 00:50:15.992 align:middle line:84%
is electrically shorted
to your source and drain.

00:50:15.992 --> 00:50:18.240 align:middle line:90%
And then your device is dead.

00:50:18.240 --> 00:50:21.540 align:middle line:84%
So titanium disilicide
has a little more tendency

00:50:21.540 --> 00:50:24.600 align:middle line:84%
to do this than the
cobalt disilicide.

00:50:24.600 --> 00:50:28.110 align:middle line:84%
This is part of the reason
people went to cobalt despite,

00:50:28.110 --> 00:50:30.900 align:middle line:84%
the fact, it has a slightly
higher resistivity.

00:50:30.900 --> 00:50:34.230 align:middle line:90%


00:50:34.230 --> 00:50:36.960 align:middle line:84%
Slide 25 is just kind
of an illustration

00:50:36.960 --> 00:50:38.520 align:middle line:84%
of some of the
kinetics of what's

00:50:38.520 --> 00:50:43.770 align:middle line:84%
happening when you have titanium
on silicon that's reacting.

00:50:43.770 --> 00:50:46.110 align:middle line:84%
Here we have a certain
thickness of Ti-silicide

00:50:46.110 --> 00:50:47.970 align:middle line:90%
that's already formed.

00:50:47.970 --> 00:50:49.110 align:middle line:90%
People do model this.

00:50:49.110 --> 00:50:52.620 align:middle line:84%
There are silicide
models in SUPREM-IV.

00:50:52.620 --> 00:50:54.700 align:middle line:84%
Not necessarily
perfectly accurate,

00:50:54.700 --> 00:50:57.360 align:middle line:84%
but what people model
is the diffusion

00:50:57.360 --> 00:51:00.330 align:middle line:84%
of the silicon from the
bulk through the titanium

00:51:00.330 --> 00:51:04.050 align:middle line:84%
disilicide up here to this
top interface and form

00:51:04.050 --> 00:51:08.590 align:middle line:84%
a new layer of
titanium disilicide.

00:51:08.590 --> 00:51:12.250 align:middle line:84%
So this is what might
happen in an inert ambient.

00:51:12.250 --> 00:51:15.310 align:middle line:84%
Now, if you do the anneal
in a nitriding ambient,

00:51:15.310 --> 00:51:17.680 align:middle line:84%
so in an ambient that has
nitrogen, at the same time,

00:51:17.680 --> 00:51:20.440 align:middle line:84%
you're forming Ti-silicide
at this interface,

00:51:20.440 --> 00:51:21.520 align:middle line:90%
you can be reacting.

00:51:21.520 --> 00:51:22.900 align:middle line:90%
The titanium is fairly reactive.

00:51:22.900 --> 00:51:25.450 align:middle line:84%
You can be reacting
in form Ti-nitrite

00:51:25.450 --> 00:51:27.230 align:middle line:90%
up here at the top interface.

00:51:27.230 --> 00:51:29.260 align:middle line:84%
So this would be in
a nitrogen ambient,

00:51:29.260 --> 00:51:32.440 align:middle line:84%
you can get simultaneous
formation of Ti-silicide

00:51:32.440 --> 00:51:37.261 align:middle line:84%
down here and then Ti-nitride
on top of the titanium.

00:51:37.261 --> 00:51:39.490 align:middle line:84%
Titanium is very
reactive, so it's not

00:51:39.490 --> 00:51:41.680 align:middle line:84%
unusual to try to
form a Ti-nitride

00:51:41.680 --> 00:51:43.360 align:middle line:90%
to prevent it from oxidizing.

00:51:43.360 --> 00:51:47.720 align:middle line:90%


00:51:47.720 --> 00:51:51.560 align:middle line:84%
Slide 26 shows you some of
the different uses of silicide

00:51:51.560 --> 00:51:52.850 align:middle line:90%
in silicon technology.

00:51:52.850 --> 00:51:54.260 align:middle line:90%
And I've actually updated it.

00:51:54.260 --> 00:51:55.700 align:middle line:90%
I added a fourth one.

00:51:55.700 --> 00:51:58.670 align:middle line:84%
So silicide are used, as you
can see, to strap the poly.

00:51:58.670 --> 00:52:00.170 align:middle line:84%
And the reason you
do that is you're

00:52:00.170 --> 00:52:02.003 align:middle line:84%
trying to reduce the
resistance of the gate.

00:52:02.003 --> 00:52:05.630 align:middle line:84%
So you form a little silicide
during the salicide process.

00:52:05.630 --> 00:52:06.857 align:middle line:90%
Strap the junctions.

00:52:06.857 --> 00:52:07.940 align:middle line:90%
Well, what does that mean?

00:52:07.940 --> 00:52:09.920 align:middle line:84%
Again, you're going
to reduce the sheet

00:52:09.920 --> 00:52:13.350 align:middle line:84%
resistance of this junction
by forming a thin layer.

00:52:13.350 --> 00:52:15.330 align:middle line:84%
It also forms a barrier
layer, as we mentioned.

00:52:15.330 --> 00:52:16.955 align:middle line:84%
It can be used as a
local interconnect.

00:52:16.955 --> 00:52:20.600 align:middle line:84%
Here the silicide has actually
been formed above this oxide.

00:52:20.600 --> 00:52:26.020 align:middle line:84%
So some silicon must have
been deposited prior to that.

00:52:26.020 --> 00:52:28.850 align:middle line:84%
And finally, it can be
used as a gate material.

00:52:28.850 --> 00:52:30.940 align:middle line:84%
And at the end, I've
added a few slides

00:52:30.940 --> 00:52:33.580 align:middle line:84%
that show you that people
are actually using silicides

00:52:33.580 --> 00:52:36.070 align:middle line:90%
as metal gates.

00:52:36.070 --> 00:52:38.950 align:middle line:84%
This is a table here
shown on slide 26

00:52:38.950 --> 00:52:40.960 align:middle line:84%
of some of the common
silicides and some

00:52:40.960 --> 00:52:43.160 align:middle line:90%
of their important properties.

00:52:43.160 --> 00:52:46.060 align:middle line:84%
So here you notice
for Ti-silicide there

00:52:46.060 --> 00:52:47.900 align:middle line:90%
are two phases.

00:52:47.900 --> 00:52:50.210 align:middle line:84%
There is a phase
called the C49 phase.

00:52:50.210 --> 00:52:52.110 align:middle line:90%
That forms at low temperatures.

00:52:52.110 --> 00:52:54.110 align:middle line:84%
So if you were
anneal the titanium

00:52:54.110 --> 00:52:57.860 align:middle line:84%
and react it with silicon,
say between 500 to 700,

00:52:57.860 --> 00:52:58.910 align:middle line:90%
say around 600--

00:52:58.910 --> 00:53:02.000 align:middle line:84%
you get a resistivity of about
60 to 70 micro ohm centimeter.

00:53:02.000 --> 00:53:07.010 align:middle line:84%
That's too high for
the film resistivity

00:53:07.010 --> 00:53:08.340 align:middle line:90%
for most applications.

00:53:08.340 --> 00:53:11.850 align:middle line:84%
So people typically do
a low temperature anneal

00:53:11.850 --> 00:53:13.560 align:middle line:90%
to form the C49 phase.

00:53:13.560 --> 00:53:16.410 align:middle line:84%
They then etch off all
the unreacted titanium.

00:53:16.410 --> 00:53:20.460 align:middle line:84%
They put it back in the RTA and
they pop it up to 800 or 900

00:53:20.460 --> 00:53:25.440 align:middle line:84%
to do a high temperature anneal
to form the C54 phase, which has

00:53:25.440 --> 00:53:28.990 align:middle line:90%
a much lower sheet resistance.

00:53:28.990 --> 00:53:31.870 align:middle line:84%
Nice thing about Ti-silicide,
it's reasonably stable, maybe up

00:53:31.870 --> 00:53:36.130 align:middle line:84%
to about 800, 900 degrees,
something like that.

00:53:36.130 --> 00:53:38.870 align:middle line:84%
It does consume a fair
amount of silicon.

00:53:38.870 --> 00:53:43.060 align:middle line:84%
So it consumes 2.2 or
2.3 or so nanometers

00:53:43.060 --> 00:53:46.885 align:middle line:84%
of silicon per every nanometer
of metal that's consumed.

00:53:46.885 --> 00:53:49.510 align:middle line:84%
But depending on how thick of a
silicide you're trying to form,

00:53:49.510 --> 00:53:50.890 align:middle line:90%
you may eat into your junction.

00:53:50.890 --> 00:53:53.348 align:middle line:84%
If you have a very shallow
junction, you have to watch out.

00:53:53.348 --> 00:53:55.600 align:middle line:84%
You don't want to
eat in too far.

00:53:55.600 --> 00:53:59.260 align:middle line:84%
So cobalt disilicide is
another example here.

00:53:59.260 --> 00:54:04.360 align:middle line:84%
You can see it's got a
somewhat higher resistivity.

00:54:04.360 --> 00:54:06.860 align:middle line:84%
This is the temperature
at which it's formed.

00:54:06.860 --> 00:54:13.140 align:middle line:84%
It consumes a little bit less
than the case of titanium.

00:54:13.140 --> 00:54:15.510 align:middle line:84%
The modern silicide
that I mentioned here

00:54:15.510 --> 00:54:18.750 align:middle line:90%
is this nickel silicide, NiSi.

00:54:18.750 --> 00:54:23.160 align:middle line:84%
It's formed at very low
temperatures, 450 or 500.

00:54:23.160 --> 00:54:27.510 align:middle line:84%
And it has a low consumption,
only 1.8 nanometers

00:54:27.510 --> 00:54:30.253 align:middle line:84%
of silicon consumed
per nanometer of metal.

00:54:30.253 --> 00:54:32.670 align:middle line:84%
One thing about this, though,
if you look at the stability

00:54:32.670 --> 00:54:34.545 align:middle line:84%
temperature-- look at
this column here called

00:54:34.545 --> 00:54:35.820 align:middle line:90%
stable on silicon.

00:54:35.820 --> 00:54:36.930 align:middle line:90%
Be very careful.

00:54:36.930 --> 00:54:38.760 align:middle line:84%
People have listed
nickel silicide

00:54:38.760 --> 00:54:41.280 align:middle line:90%
as being stable up to about 650.

00:54:41.280 --> 00:54:42.780 align:middle line:84%
It may not even be
stable that high.

00:54:42.780 --> 00:54:43.920 align:middle line:90%
Maybe 600 or so.

00:54:43.920 --> 00:54:46.710 align:middle line:84%
So unlike some of
these others, which

00:54:46.710 --> 00:54:48.540 align:middle line:84%
you can heat up
Ti-silicide or platinum,

00:54:48.540 --> 00:54:50.023 align:middle line:90%
you can heat up to 800 or so.

00:54:50.023 --> 00:54:51.690 align:middle line:84%
You cannot do that
with nickel silicide.

00:54:51.690 --> 00:54:53.740 align:middle line:84%
So if you're using a
nickel silicide process,

00:54:53.740 --> 00:54:57.720 align:middle line:84%
you're going to be limited to
a lower backend temperature.

00:54:57.720 --> 00:55:00.990 align:middle line:84%
But you can get reasonably
low sheet resistance.

00:55:00.990 --> 00:55:05.510 align:middle line:90%


00:55:05.510 --> 00:55:08.180 align:middle line:84%
Slide 27, I just want
to show you an example.

00:55:08.180 --> 00:55:10.640 align:middle line:84%
And we'll go through
these calculations

00:55:10.640 --> 00:55:11.730 align:middle line:90%
at the end of the lecture.

00:55:11.730 --> 00:55:16.670 align:middle line:84%
But I want to go on and do
the gate material work first.

00:55:16.670 --> 00:55:21.210 align:middle line:84%
But what this is is a
cross section of a MOSFET.

00:55:21.210 --> 00:55:25.590 align:middle line:84%
And we've seen this
cross-section a number of times

00:55:25.590 --> 00:55:26.520 align:middle line:90%
now in our class.

00:55:26.520 --> 00:55:29.220 align:middle line:84%
We now have enough ammunition
that we can actually

00:55:29.220 --> 00:55:31.770 align:middle line:84%
go sit down and calculate
all these resistances

00:55:31.770 --> 00:55:37.450 align:middle line:84%
or estimate them given a
geometry of a particular device.

00:55:37.450 --> 00:55:39.575 align:middle line:84%
So the resistance
that we really,

00:55:39.575 --> 00:55:41.700 align:middle line:84%
when we scale the channel
length, what we're really

00:55:41.700 --> 00:55:44.220 align:middle line:84%
trying to scale is the
channel resistance, R chan.

00:55:44.220 --> 00:55:46.110 align:middle line:90%
OK, that's fine.

00:55:46.110 --> 00:55:49.500 align:middle line:84%
We make the channel shorter,
we can reduce that resistance.

00:55:49.500 --> 00:55:52.380 align:middle line:84%
But the problem is, what happens
to-- if we don't do something

00:55:52.380 --> 00:55:54.195 align:middle line:84%
to all these other
parasitic resistances,

00:55:54.195 --> 00:55:56.370 align:middle line:84%
the net resistance of
the device is really not

00:55:56.370 --> 00:55:58.540 align:middle line:90%
going to go down by very much.

00:55:58.540 --> 00:56:00.300 align:middle line:84%
So there are three
resistances we really

00:56:00.300 --> 00:56:02.200 align:middle line:90%
want to be able to think about.

00:56:02.200 --> 00:56:04.330 align:middle line:84%
One is this little
resistor right here,

00:56:04.330 --> 00:56:07.110 align:middle line:84%
which is the resistance
associated with the source drain

00:56:07.110 --> 00:56:08.430 align:middle line:90%
extension.

00:56:08.430 --> 00:56:10.440 align:middle line:84%
It has a certain
sheet resistance.

00:56:10.440 --> 00:56:11.807 align:middle line:90%
It's doped to a certain level.

00:56:11.807 --> 00:56:13.140 align:middle line:90%
It has a certain junction depth.

00:56:13.140 --> 00:56:15.130 align:middle line:90%
It's usually very shallow.

00:56:15.130 --> 00:56:17.700 align:middle line:84%
So this resistance of the
source drain extension

00:56:17.700 --> 00:56:19.980 align:middle line:84%
is one resistance we
have to calculate.

00:56:19.980 --> 00:56:25.413 align:middle line:84%
The second one is the resistance
of this region here, R, that--

00:56:25.413 --> 00:56:27.330 align:middle line:84%
and generally, this
region has been silicided.

00:56:27.330 --> 00:56:28.872 align:middle line:84%
You notice the source
drain extension

00:56:28.872 --> 00:56:30.910 align:middle line:84%
is under the spacer
by definition,

00:56:30.910 --> 00:56:32.250 align:middle line:90%
so it's not silicided.

00:56:32.250 --> 00:56:35.440 align:middle line:84%
So the current has to flow
strictly through the silicon.

00:56:35.440 --> 00:56:37.620 align:middle line:84%
So it will have a certain
higher resistivity.

00:56:37.620 --> 00:56:39.787 align:middle line:84%
In this case, this
region is blue.

00:56:39.787 --> 00:56:40.620 align:middle line:90%
It's been silicided.

00:56:40.620 --> 00:56:42.370 align:middle line:84%
So it's going to have
a lower resistivity.

00:56:42.370 --> 00:56:44.200 align:middle line:90%
It's got a metal on top of it.

00:56:44.200 --> 00:56:46.680 align:middle line:84%
So that's the second resistor
we need to calculate.

00:56:46.680 --> 00:56:49.240 align:middle line:84%
The third one is the resistance
of the contact itself.

00:56:49.240 --> 00:56:52.050 align:middle line:84%
So it's the contact resistance
from the current flowing

00:56:52.050 --> 00:56:55.540 align:middle line:84%
through the silicon
up into the metal.

00:56:55.540 --> 00:56:57.190 align:middle line:84%
And that would
calculate if we know

00:56:57.190 --> 00:56:59.620 align:middle line:84%
the area and the specific
contact resistivity.

00:56:59.620 --> 00:57:01.810 align:middle line:84%
So all three of these--
the source drain extension

00:57:01.810 --> 00:57:05.230 align:middle line:84%
resistance, the silicide
resistance, and the contact

00:57:05.230 --> 00:57:07.720 align:middle line:84%
resistance-- all three are
going to add up and give us

00:57:07.720 --> 00:57:09.950 align:middle line:84%
different contributions
depending on the geometry.

00:57:09.950 --> 00:57:12.035 align:middle line:84%
So I want to go through
a calculation of this.

00:57:12.035 --> 00:57:13.660 align:middle line:84%
I'm going to hold
off for now because I

00:57:13.660 --> 00:57:18.070 align:middle line:84%
want to make sure we cover the
novel gate material aspects.

00:57:18.070 --> 00:57:20.080 align:middle line:90%
But we'll come back to this.

00:57:20.080 --> 00:57:22.090 align:middle line:84%
And you should be able
to sit down at this point

00:57:22.090 --> 00:57:23.715 align:middle line:84%
and calculate all
three of these things

00:57:23.715 --> 00:57:28.350 align:middle line:84%
and see what they look
like for modern technology.

00:57:28.350 --> 00:57:30.810 align:middle line:90%
Let's go on for now to slide--

00:57:30.810 --> 00:57:33.540 align:middle line:84%
there's one more--
by the way, I sort of

00:57:33.540 --> 00:57:35.280 align:middle line:90%
didn't tell you the whole truth.

00:57:35.280 --> 00:57:37.750 align:middle line:84%
I said there are three
resistors, this one, this one,

00:57:37.750 --> 00:57:38.580 align:middle line:90%
and this one.

00:57:38.580 --> 00:57:39.773 align:middle line:90%
It's not quite that simple.

00:57:39.773 --> 00:57:41.940 align:middle line:84%
These back-of-the-envelope
calculations are terrific

00:57:41.940 --> 00:57:44.880 align:middle line:84%
because you can do them in
five minutes in class or in 10

00:57:44.880 --> 00:57:46.440 align:middle line:84%
minutes in your
office or whatever.

00:57:46.440 --> 00:57:49.710 align:middle line:84%
There is another resistance
called the spreading resistance.

00:57:49.710 --> 00:57:53.970 align:middle line:84%
And that's actually pictured--
it cannot be calculated by hand,

00:57:53.970 --> 00:57:58.430 align:middle line:84%
but it's actually
pictured on page 28 here,

00:57:58.430 --> 00:57:59.570 align:middle line:90%
just to give you an idea.

00:57:59.570 --> 00:58:05.450 align:middle line:84%
This first was discussed by Ming
and Lynch back in the late 80s.

00:58:05.450 --> 00:58:08.300 align:middle line:84%
But what it is is you
have this channel region

00:58:08.300 --> 00:58:09.680 align:middle line:90%
that's very, very thin.

00:58:09.680 --> 00:58:12.620 align:middle line:84%
Typically the channel where
the electrons are the holes

00:58:12.620 --> 00:58:14.300 align:middle line:84%
are traversing
across and they're

00:58:14.300 --> 00:58:17.660 align:middle line:84%
going across the gate length,
that's maybe only 30 angstroms

00:58:17.660 --> 00:58:18.920 align:middle line:90%
thick.

00:58:18.920 --> 00:58:21.500 align:middle line:84%
So that's where the current
is all flowing in the channel.

00:58:21.500 --> 00:58:23.570 align:middle line:84%
It's a very, very high
density of carriers.

00:58:23.570 --> 00:58:28.460 align:middle line:84%
The current then spreads out as
it goes into the source drain

00:58:28.460 --> 00:58:28.970 align:middle line:90%
extension.

00:58:28.970 --> 00:58:30.200 align:middle line:90%
This is such an old paper.

00:58:30.200 --> 00:58:31.610 align:middle line:84%
It's before they had
source drain extensions.

00:58:31.610 --> 00:58:33.650 align:middle line:84%
But you can imagine it
then spreads out here

00:58:33.650 --> 00:58:36.050 align:middle line:84%
into this region over
certain distance.

00:58:36.050 --> 00:58:38.900 align:middle line:84%
And how far it spreads out
and exactly how it spreads out

00:58:38.900 --> 00:58:42.350 align:middle line:84%
depends on the doping and the
geometry of the structure.

00:58:42.350 --> 00:58:44.030 align:middle line:84%
It's a very
two-dimensional problem.

00:58:44.030 --> 00:58:45.360 align:middle line:90%
You can't calculate it by hand.

00:58:45.360 --> 00:58:48.410 align:middle line:84%
So this that's
called the RSP here

00:58:48.410 --> 00:58:51.440 align:middle line:84%
in this little diagram
where he wrote down

00:58:51.440 --> 00:58:53.160 align:middle line:90%
the different resistances.

00:58:53.160 --> 00:58:56.540 align:middle line:84%
So our spreading is
one that generally

00:58:56.540 --> 00:58:59.120 align:middle line:84%
has to be computed either by
a two-dimensional simulator

00:58:59.120 --> 00:59:02.850 align:middle line:84%
or you have to get it out
of test devices or some kind

00:59:02.850 --> 00:59:03.720 align:middle line:90%
of test structures.

00:59:03.720 --> 00:59:05.887 align:middle line:84%
It's not something you can
simply calculate by hand.

00:59:05.887 --> 00:59:07.610 align:middle line:84%
But it is a major
contributor-- it

00:59:07.610 --> 00:59:11.040 align:middle line:84%
can be a major contribution to
the total series resistance.

00:59:11.040 --> 00:59:13.730 align:middle line:84%
So it's something we need
to be concerned about.

00:59:13.730 --> 00:59:16.670 align:middle line:84%
But I just want to point
out, so those three

00:59:16.670 --> 00:59:18.422 align:middle line:84%
resistances we can
calculate by hand,

00:59:18.422 --> 00:59:20.880 align:middle line:84%
that gives you the minimum
series resistance of the device.

00:59:20.880 --> 00:59:22.380 align:middle line:84%
There will always
be a little extra,

00:59:22.380 --> 00:59:25.940 align:middle line:84%
which is spreading resistance,
which you have to simulate

00:59:25.940 --> 00:59:27.860 align:middle line:90%
in a two-dimensional simulator.

00:59:27.860 --> 00:59:31.113 align:middle line:90%


00:59:31.113 --> 00:59:32.280 align:middle line:90%
That's how we make contacts.

00:59:32.280 --> 00:59:35.670 align:middle line:84%
I just wanted to go on and
spend most of the remaining

00:59:35.670 --> 00:59:39.450 align:middle line:84%
time of the lecture and talk
about something else that's

00:59:39.450 --> 00:59:43.260 align:middle line:84%
come up in the last three or
four years, which is related

00:59:43.260 --> 00:59:46.770 align:middle line:84%
directly to the contacts
because it turns out we can also

00:59:46.770 --> 00:59:48.780 align:middle line:84%
use silicides not
only for the contacts,

00:59:48.780 --> 00:59:50.940 align:middle line:84%
but we can also fully
silicide the gate

00:59:50.940 --> 00:59:52.110 align:middle line:90%
and use it for the gate.

00:59:52.110 --> 00:59:56.010 align:middle line:84%
And I think I showed you this
slide last time, page 29.

00:59:56.010 --> 00:59:58.050 align:middle line:84%
It was taken directly
from the last lecture.

00:59:58.050 --> 00:59:59.820 align:middle line:84%
I just wanted to
remind you that there

00:59:59.820 --> 01:00:03.170 align:middle line:84%
are some new gate materials
that are coming along.

01:00:03.170 --> 01:00:06.500 align:middle line:84%
This is the more classical
older technology,

01:00:06.500 --> 01:00:08.480 align:middle line:90%
the traditional technology.

01:00:08.480 --> 01:00:11.060 align:middle line:84%
This is a photo from
an Intel device.

01:00:11.060 --> 01:00:13.580 align:middle line:90%
It's a somewhat older photo now.

01:00:13.580 --> 01:00:17.853 align:middle line:84%
This was published back in
about five years ago in 2000.

01:00:17.853 --> 01:00:20.520 align:middle line:84%
And what it shows is what we've
just exactly been talking about.

01:00:20.520 --> 01:00:22.160 align:middle line:90%
Here's the polysilicon gate.

01:00:22.160 --> 01:00:23.537 align:middle line:90%
These are the sidewall spacers.

01:00:23.537 --> 01:00:24.620 align:middle line:90%
You know how to form them.

01:00:24.620 --> 01:00:27.003 align:middle line:84%
And this is the
silicide in the source.

01:00:27.003 --> 01:00:29.420 align:middle line:84%
You can see it looks very dark
because it's been silicide.

01:00:29.420 --> 01:00:31.220 align:middle line:90%
And the silicide in the drain.

01:00:31.220 --> 01:00:33.830 align:middle line:84%
And the silicide that's
been formed on the gate.

01:00:33.830 --> 01:00:35.780 align:middle line:84%
So that was the
salicide processed just

01:00:35.780 --> 01:00:38.000 align:middle line:84%
by the process exactly
what we just talked about.

01:00:38.000 --> 01:00:41.860 align:middle line:84%
That's the classical
type of structure.

01:00:41.860 --> 01:00:44.890 align:middle line:84%
We talked last time, though,
that polysilicon can only

01:00:44.890 --> 01:00:47.280 align:middle line:90%
be doped so high.

01:00:47.280 --> 01:00:49.860 align:middle line:84%
Maybe you can get it to 10 to
the 20 or mid 10 to the 20.

01:00:49.860 --> 01:00:52.170 align:middle line:84%
But that's not enough
carriers to prevent

01:00:52.170 --> 01:00:56.670 align:middle line:84%
depletion of the polysilicon
at very high gate biases.

01:00:56.670 --> 01:00:58.600 align:middle line:84%
And you get a polysilicon
depletion effect.

01:00:58.600 --> 01:01:00.510 align:middle line:90%
So people are concerned.

01:01:00.510 --> 01:01:03.040 align:middle line:84%
They want to get rid of
poly as the gate material.

01:01:03.040 --> 01:01:04.500 align:middle line:90%
It doesn't have enough carriers.

01:01:04.500 --> 01:01:07.080 align:middle line:84%
Polysilicon may only
have maybe 5 times 10

01:01:07.080 --> 01:01:09.960 align:middle line:84%
to the 20 electrons
per cubic centimeter.

01:01:09.960 --> 01:01:12.480 align:middle line:84%
They would like to replace
the poly with a gate,

01:01:12.480 --> 01:01:14.460 align:middle line:90%
with a metal gate.

01:01:14.460 --> 01:01:16.360 align:middle line:90%
A metal has 10 to the 23rd.

01:01:16.360 --> 01:01:18.510 align:middle line:84%
So it's three orders of
magnitude higher carriers.

01:01:18.510 --> 01:01:20.820 align:middle line:84%
So it's not going
to get depleted.

01:01:20.820 --> 01:01:23.640 align:middle line:84%
So they want to remove the
semiconductor from the gate.

01:01:23.640 --> 01:01:26.790 align:middle line:84%
But poly is an extremely
easy material to integrate.

01:01:26.790 --> 01:01:28.500 align:middle line:90%
People know how to etch it.

01:01:28.500 --> 01:01:31.110 align:middle line:90%
It's not reactive with SiO2.

01:01:31.110 --> 01:01:32.920 align:middle line:90%
That's not the case for metals.

01:01:32.920 --> 01:01:34.110 align:middle line:90%
So here's an example.

01:01:34.110 --> 01:01:36.030 align:middle line:84%
Last time, in fact, I
went through a process

01:01:36.030 --> 01:01:38.250 align:middle line:84%
called the replacement
gate process where we

01:01:38.250 --> 01:01:40.200 align:middle line:90%
showed they actually used poly.

01:01:40.200 --> 01:01:42.450 align:middle line:84%
They dug it out at the
very end of the process.

01:01:42.450 --> 01:01:45.030 align:middle line:84%
They etched out the poly,
and they replaced it

01:01:45.030 --> 01:01:48.040 align:middle line:84%
with a high-K material
like hafnium dioxide

01:01:48.040 --> 01:01:50.662 align:middle line:90%
and a Ti-nitride gate.

01:01:50.662 --> 01:01:52.120 align:middle line:84%
So this was an
example of something

01:01:52.120 --> 01:01:53.810 align:middle line:90%
published about six months ago.

01:01:53.810 --> 01:01:56.050 align:middle line:84%
So people are thinking
of replacing poly,

01:01:56.050 --> 01:01:59.520 align:middle line:84%
but it's got a lot of
complex process integration.

01:01:59.520 --> 01:02:02.910 align:middle line:84%
An easier process integration
that people are considering

01:02:02.910 --> 01:02:05.512 align:middle line:84%
is rather than
digging the poly out--

01:02:05.512 --> 01:02:06.970 align:middle line:84%
and whenever you
etch out the poly,

01:02:06.970 --> 01:02:11.010 align:middle line:84%
you always expose the very
sensitive oxide silicon

01:02:11.010 --> 01:02:11.510 align:middle line:90%
interface.

01:02:11.510 --> 01:02:14.020 align:middle line:84%
So that's typically, from an
integration point of view,

01:02:14.020 --> 01:02:15.928 align:middle line:84%
digging out the poly
is not that desirable.

01:02:15.928 --> 01:02:18.220 align:middle line:84%
They said, well, why don't
we just take the polysilicon

01:02:18.220 --> 01:02:21.910 align:middle line:84%
and fully react it with a metal
and convert it from polysilicon

01:02:21.910 --> 01:02:24.690 align:middle line:90%
into a silicide?

01:02:24.690 --> 01:02:26.800 align:middle line:84%
Put enough metal there,
instead of, in this case,

01:02:26.800 --> 01:02:28.550 align:middle line:84%
they only put a very
thin amount of metal,

01:02:28.550 --> 01:02:30.960 align:middle line:84%
so it only reacts to form
maybe several hundred

01:02:30.960 --> 01:02:32.852 align:middle line:90%
angstroms of silicide.

01:02:32.852 --> 01:02:34.310 align:middle line:84%
People are saying,
all right, we'll

01:02:34.310 --> 01:02:39.223 align:middle line:84%
put enough metal on top of that,
make it really thick metal,

01:02:39.223 --> 01:02:40.640 align:middle line:84%
so that it reacts--
and it reacted

01:02:40.640 --> 01:02:42.682 align:middle line:84%
at a high enough temperature
for long enough time

01:02:42.682 --> 01:02:44.675 align:middle line:84%
that the metal
reaction takes place

01:02:44.675 --> 01:02:45.800 align:middle line:90%
throughout the entire poly.

01:02:45.800 --> 01:02:49.760 align:middle line:84%
And you get a silicide all the
way down to the gate interface.

01:02:49.760 --> 01:02:53.960 align:middle line:84%
And here's an example of nickel
silicide, fully silicided gate

01:02:53.960 --> 01:02:57.020 align:middle line:84%
that was published about
six months ago by annealing

01:02:57.020 --> 01:03:00.660 align:middle line:84%
at 450 degrees and using a
thick enough layer of nickel.

01:03:00.660 --> 01:03:03.320 align:middle line:84%
So not only are silicides being
used in the source and drain,

01:03:03.320 --> 01:03:06.620 align:middle line:84%
but they're also being
used fully in the gate.

01:03:06.620 --> 01:03:09.670 align:middle line:84%
Now, this is different
from the salicide process.

01:03:09.670 --> 01:03:14.140 align:middle line:84%
One reason would be is the
gate's usually reasonably tall.

01:03:14.140 --> 01:03:16.990 align:middle line:84%
The gate may be 1,000 angstroms
tall, something like that.

01:03:16.990 --> 01:03:18.490 align:middle line:84%
So you need to put
enough metal down

01:03:18.490 --> 01:03:21.485 align:middle line:84%
that you can silicide all the
way through 1,000 angstroms.

01:03:21.485 --> 01:03:22.860 align:middle line:84%
Now, on the source
and drain, you

01:03:22.860 --> 01:03:25.050 align:middle line:84%
don't want to be siliciding
down 1,000 angstroms

01:03:25.050 --> 01:03:27.700 align:middle line:84%
because I said the junction
depth is about 1,000 angstroms.

01:03:27.700 --> 01:03:31.290 align:middle line:84%
So if you're going to do a
FUSI process for the gate,

01:03:31.290 --> 01:03:33.907 align:middle line:84%
you actually need to have two
different siliciding steps.

01:03:33.907 --> 01:03:35.490 align:middle line:84%
You need to have a
step when you would

01:03:35.490 --> 01:03:37.770 align:middle line:84%
silicide with a very
thin amount of metal

01:03:37.770 --> 01:03:39.600 align:middle line:84%
with silicide the
source and drain.

01:03:39.600 --> 01:03:42.690 align:middle line:84%
You need to cover them and
protect them then, and then

01:03:42.690 --> 01:03:45.870 align:middle line:84%
open up the gate and use
a thick amount of metal

01:03:45.870 --> 01:03:47.520 align:middle line:84%
to try to fully
silicide the gate.

01:03:47.520 --> 01:03:49.120 align:middle line:84%
So it's a little--
it's still tricky.

01:03:49.120 --> 01:03:52.710 align:middle line:84%
It's not as simple as using the
old fashioned salicide process

01:03:52.710 --> 01:03:54.875 align:middle line:84%
where the thickness that
you silicide on the gate

01:03:54.875 --> 01:03:56.250 align:middle line:84%
was the same as
the thickness you

01:03:56.250 --> 01:03:57.510 align:middle line:90%
went in the source and drain.

01:03:57.510 --> 01:03:58.950 align:middle line:90%
It's different from that.

01:03:58.950 --> 01:04:00.390 align:middle line:84%
But it's not quite
as complicated

01:04:00.390 --> 01:04:04.545 align:middle line:84%
as completely replacing the
gate in the etch-out process.

01:04:04.545 --> 01:04:07.280 align:middle line:90%


01:04:07.280 --> 01:04:08.840 align:middle line:90%
In fact, I've got here--

01:04:08.840 --> 01:04:13.040 align:middle line:84%
showing here you on slide 30
some fairly recent results

01:04:13.040 --> 01:04:16.700 align:middle line:84%
from the last couple of years
of how people have made nickel

01:04:16.700 --> 01:04:18.350 align:middle line:90%
silicide FUSI.

01:04:18.350 --> 01:04:22.370 align:middle line:84%
FUSI is the acronym for
fully silicided gate.

01:04:22.370 --> 01:04:24.920 align:middle line:84%
How they've made this--
and this particular article

01:04:24.920 --> 01:04:30.790 align:middle line:90%
came out two years ago from AMD.

01:04:30.790 --> 01:04:33.890 align:middle line:84%
And what they're showing here
is a method to form this.

01:04:33.890 --> 01:04:38.070 align:middle line:84%
And so they do the standard
transistor fabrication or flow

01:04:38.070 --> 01:04:38.570 align:middle line:90%
here.

01:04:38.570 --> 01:04:40.990 align:middle line:90%
So this is their poly gate.

01:04:40.990 --> 01:04:43.660 align:middle line:84%
And here they've actually
formed a little bit of silicide

01:04:43.660 --> 01:04:46.630 align:middle line:84%
in the source and drain and a
little bit on top of the gate.

01:04:46.630 --> 01:04:50.510 align:middle line:84%
So they did the standard
salicide process at this point.

01:04:50.510 --> 01:04:52.440 align:middle line:84%
Now they have to do
a plan arising step.

01:04:52.440 --> 01:04:55.070 align:middle line:84%
So to get from here to
here, what they had to do is

01:04:55.070 --> 01:04:57.500 align:middle line:84%
they had to put
a metal and maybe

01:04:57.500 --> 01:04:59.420 align:middle line:90%
some other harder material--

01:04:59.420 --> 01:05:00.590 align:middle line:90%
no, sorry.

01:05:00.590 --> 01:05:03.650 align:middle line:84%
They had to put, yeah, contact
material, and then maybe

01:05:03.650 --> 01:05:05.990 align:middle line:84%
a dielectric over
the entire thing,

01:05:05.990 --> 01:05:08.600 align:middle line:84%
and then CNP it down
so it's planarized

01:05:08.600 --> 01:05:11.180 align:middle line:84%
because you know they're going
to get deposition everywhere.

01:05:11.180 --> 01:05:14.210 align:middle line:90%
So they planarized it.

01:05:14.210 --> 01:05:17.270 align:middle line:84%
And they expose, then-- in
the plane rising process,

01:05:17.270 --> 01:05:20.900 align:middle line:84%
they expose the
polysilicon gate.

01:05:20.900 --> 01:05:22.760 align:middle line:84%
And they can then
put down metal here,

01:05:22.760 --> 01:05:25.580 align:middle line:84%
and a thick layer of metal,
and react it all the way

01:05:25.580 --> 01:05:27.030 align:middle line:90%
to the interface.

01:05:27.030 --> 01:05:30.560 align:middle line:84%
So here they have
this very thick region

01:05:30.560 --> 01:05:32.570 align:middle line:84%
where the entire gate
has been silicided.

01:05:32.570 --> 01:05:36.170 align:middle line:84%
And you notice during this
last process here on the right,

01:05:36.170 --> 01:05:39.380 align:middle line:84%
there's no siliciding happening
down in the source and drain

01:05:39.380 --> 01:05:43.600 align:middle line:84%
because that's all been
protected during this process.

01:05:43.600 --> 01:05:46.420 align:middle line:84%
So it's certainly easier
than the replacement gate

01:05:46.420 --> 01:05:47.890 align:middle line:90%
scheme that showed last time.

01:05:47.890 --> 01:05:50.740 align:middle line:84%
And it also avoids the PVD
damage to the gate oxide.

01:05:50.740 --> 01:05:53.230 align:middle line:84%
If I'm going to
etch this gate out

01:05:53.230 --> 01:05:55.570 align:middle line:84%
and I have to deposit
a metal by PVD,

01:05:55.570 --> 01:05:59.200 align:middle line:84%
your PVD processes
can be very energetic.

01:05:59.200 --> 01:06:02.590 align:middle line:84%
You often use some kind of
sputtering where you have ions.

01:06:02.590 --> 01:06:05.170 align:middle line:84%
And you can cause damage
to the gate oxide.

01:06:05.170 --> 01:06:07.240 align:middle line:84%
This doesn't have that
at all because when

01:06:07.240 --> 01:06:10.420 align:middle line:84%
you deposit the nickel, the
nickel is going on up here.

01:06:10.420 --> 01:06:13.000 align:middle line:84%
And then it diffuses
in a siliciding process

01:06:13.000 --> 01:06:15.900 align:middle line:90%
to get down to the bottom.

01:06:15.900 --> 01:06:19.290 align:middle line:84%
Here's an example of an
electron micrograph of one

01:06:19.290 --> 01:06:20.220 align:middle line:90%
of those devices.

01:06:20.220 --> 01:06:21.960 align:middle line:84%
This gate has been
fully silicided.

01:06:21.960 --> 01:06:23.670 align:middle line:90%
So this is all nickel silicide.

01:06:23.670 --> 01:06:28.260 align:middle line:84%
This very thin white layer
is the gate oxide, very thin.

01:06:28.260 --> 01:06:30.600 align:middle line:84%
And this layer here is
the silicon channel.

01:06:30.600 --> 01:06:32.850 align:middle line:90%
This is an SOI device.

01:06:32.850 --> 01:06:34.770 align:middle line:90%
So this is a silicon channel.

01:06:34.770 --> 01:06:38.510 align:middle line:84%
And this is the buried
insulator, the buried oxide.

01:06:38.510 --> 01:06:42.100 align:middle line:84%
And these are sidewall
spacer layers.

01:06:42.100 --> 01:06:45.270 align:middle line:90%


01:06:45.270 --> 01:06:47.970 align:middle line:84%
This is just another
image here on slide 31,

01:06:47.970 --> 01:06:49.650 align:middle line:90%
another image of that gate.

01:06:49.650 --> 01:06:53.340 align:middle line:84%
They've made a very short
channel device, only something

01:06:53.340 --> 01:06:56.340 align:middle line:90%
between 35 and 40 nanometers.

01:06:56.340 --> 01:07:00.290 align:middle line:84%
It's a very ultra-thin body
device, or reasonably thin body

01:07:00.290 --> 01:07:00.790 align:middle line:90%
device.

01:07:00.790 --> 01:07:04.510 align:middle line:84%
This is an SOI, it's
only 25 nanometers thick.

01:07:04.510 --> 01:07:08.497 align:middle line:84%
And they have oxide and
nitride spacers on either side.

01:07:08.497 --> 01:07:10.330 align:middle line:84%
The point they were
trying to make with this

01:07:10.330 --> 01:07:12.580 align:middle line:84%
was that the nickel did not
diffuse in to the silicon.

01:07:12.580 --> 01:07:14.990 align:middle line:84%
Of course, it's a little
hard to tell from this.

01:07:14.990 --> 01:07:18.010 align:middle line:84%
The nice thing about it, if you
zoom in at this point right here

01:07:18.010 --> 01:07:20.470 align:middle line:84%
and you zoom in on
the gate oxide--

01:07:20.470 --> 01:07:24.040 align:middle line:84%
so this is the gate
dielectric, which is shown here

01:07:24.040 --> 01:07:25.520 align:middle line:90%
by this amorphous material.

01:07:25.520 --> 01:07:27.670 align:middle line:90%
It's about 2.1 nanometers thick.

01:07:27.670 --> 01:07:28.990 align:middle line:90%
That's their gate dielectric.

01:07:28.990 --> 01:07:31.420 align:middle line:84%
This is the metal gate
now it's nickel silicide.

01:07:31.420 --> 01:07:33.507 align:middle line:84%
It went down and it stopped
at the gate stopped,

01:07:33.507 --> 01:07:34.840 align:middle line:90%
reacting at the gate dielectric.

01:07:34.840 --> 01:07:37.280 align:middle line:84%
And this is the
silicon channel region.

01:07:37.280 --> 01:07:39.250 align:middle line:90%
It's reasonably smooth.

01:07:39.250 --> 01:07:41.440 align:middle line:84%
People were concerned that
the nickel might diffuse

01:07:41.440 --> 01:07:43.150 align:middle line:90%
in and react with the oxide.

01:07:43.150 --> 01:07:46.270 align:middle line:84%
But according to this
particular temperature and time

01:07:46.270 --> 01:07:49.300 align:middle line:84%
that they did, they get a
reasonably smooth interface.

01:07:49.300 --> 01:07:52.655 align:middle line:90%


01:07:52.655 --> 01:07:54.030 align:middle line:84%
Remember, you can
care about that

01:07:54.030 --> 01:07:54.960 align:middle line:84%
because it's going
to be the channel.

01:07:54.960 --> 01:07:56.938 align:middle line:84%
The carriers are going
to be flowing right

01:07:56.938 --> 01:07:58.230 align:middle line:90%
in the silicon underneath this.

01:07:58.230 --> 01:08:02.440 align:middle line:84%
So you don't want to get any
nickel into that channel.

01:08:02.440 --> 01:08:07.220 align:middle line:84%
This is, on slide
32, that same paper.

01:08:07.220 --> 01:08:10.330 align:middle line:84%
They also did some
Auger analysis.

01:08:10.330 --> 01:08:12.490 align:middle line:84%
Remember, we talked
about Auger spectroscopy

01:08:12.490 --> 01:08:15.640 align:middle line:84%
as being a means of
measuring the composition

01:08:15.640 --> 01:08:17.510 align:middle line:90%
by going through a device.

01:08:17.510 --> 01:08:21.740 align:middle line:84%
So this is a vertical
scan through the device.

01:08:21.740 --> 01:08:25.710 align:middle line:84%
So what they're actually
doing is going back here,

01:08:25.710 --> 01:08:28.569 align:middle line:84%
they're the Auger
experiment, and they're

01:08:28.569 --> 01:08:29.819 align:middle line:90%
sputtering right through here.

01:08:29.819 --> 01:08:31.277 align:middle line:84%
And through the
center of the gate,

01:08:31.277 --> 01:08:36.359 align:middle line:84%
they're looking at what
comes off, what they see,

01:08:36.359 --> 01:08:39.000 align:middle line:84%
what Auger electrons
as they sputter.

01:08:39.000 --> 01:08:43.810 align:middle line:84%
So here we see atomic
concentration in percent

01:08:43.810 --> 01:08:45.500 align:middle line:84%
as a function of
depth, essentially.

01:08:45.500 --> 01:08:46.960 align:middle line:84%
So this is the
surface over here.

01:08:46.960 --> 01:08:49.330 align:middle line:84%
And you can see that the
red line is the nickel.

01:08:49.330 --> 01:08:51.250 align:middle line:90%
The blue is the silicon.

01:08:51.250 --> 01:08:53.140 align:middle line:84%
This is the
thickness of the gate

01:08:53.140 --> 01:08:57.310 align:middle line:84%
from the surface here to this
point here, to the gate oxide.

01:08:57.310 --> 01:09:02.740 align:middle line:84%
And what you see is there's
quite a bit of silicidation.

01:09:02.740 --> 01:09:06.160 align:middle line:90%
This is mostly nickel silicide.

01:09:06.160 --> 01:09:08.979 align:middle line:84%
It looks like here there's
a little bit of silicon--

01:09:08.979 --> 01:09:12.790 align:middle line:84%
or here you have the
silicon in the SiO2.

01:09:12.790 --> 01:09:17.050 align:middle line:84%
And then this is
the oxide beneath.

01:09:17.050 --> 01:09:18.267 align:middle line:90%
So you just get some idea.

01:09:18.267 --> 01:09:20.350 align:middle line:84%
This looks like it's fairly
stoichiometric, almost

01:09:20.350 --> 01:09:22.300 align:middle line:90%
1 to 1 silicon to nickel.

01:09:22.300 --> 01:09:24.840 align:middle line:90%
Maybe a little bit nickel-rich.

01:09:24.840 --> 01:09:26.640 align:middle line:84%
Again, using the
types of techniques

01:09:26.640 --> 01:09:29.009 align:middle line:84%
we talked about in our
characterization lectures.

01:09:29.009 --> 01:09:32.307 align:middle line:90%


01:09:32.307 --> 01:09:33.390 align:middle line:90%
This is a different paper.

01:09:33.390 --> 01:09:38.510 align:middle line:84%
This is a paper-- that last
paper was from IEDM 2002

01:09:38.510 --> 01:09:41.510 align:middle line:90%
applied by AMD.

01:09:41.510 --> 01:09:46.460 align:middle line:84%
IBM the same year also published
at the same conference nickel

01:09:46.460 --> 01:09:48.529 align:middle line:90%
silicide FUSI gates.

01:09:48.529 --> 01:09:51.920 align:middle line:84%
This time they did them not
only on fully depleted SOI.

01:09:51.920 --> 01:09:54.260 align:middle line:84%
I just showed you a
silicon insulator device.

01:09:54.260 --> 01:09:56.720 align:middle line:84%
They also did it on a device,
which is called a FinFET.

01:09:56.720 --> 01:09:58.580 align:middle line:84%
We haven't had any
time, really, to go

01:09:58.580 --> 01:10:01.608 align:middle line:84%
into these new types
of devices, but there

01:10:01.608 --> 01:10:03.650 align:middle line:84%
are silicon MOSFETs these
days that are not being

01:10:03.650 --> 01:10:06.360 align:middle line:90%
made in a planar structure.

01:10:06.360 --> 01:10:08.400 align:middle line:84%
There's a device that
emits very non-planar

01:10:08.400 --> 01:10:11.190 align:middle line:84%
called the FinFET, when in
fact, people form a fin.

01:10:11.190 --> 01:10:15.010 align:middle line:84%
And the channel of the device
is actually into the page.

01:10:15.010 --> 01:10:16.110 align:middle line:90%
So it's into the board.

01:10:16.110 --> 01:10:19.390 align:middle line:84%
And the electrons actually
flow along the side walls.

01:10:19.390 --> 01:10:21.270 align:middle line:84%
Electrons actually
flow right along here.

01:10:21.270 --> 01:10:23.153 align:middle line:84%
And you have a gate
on the right side

01:10:23.153 --> 01:10:24.320 align:middle line:90%
and a gate on the left side.

01:10:24.320 --> 01:10:26.640 align:middle line:84%
In fact, the gate
kind of wraps around.

01:10:26.640 --> 01:10:29.220 align:middle line:84%
So this whole thing
ends up being a channel.

01:10:29.220 --> 01:10:31.990 align:middle line:84%
And the source and drain
are into the board.

01:10:31.990 --> 01:10:35.520 align:middle line:84%
This is a device that has
some advantages, although it's

01:10:35.520 --> 01:10:36.900 align:middle line:90%
a little tricky to make.

01:10:36.900 --> 01:10:38.410 align:middle line:90%
It's a double gate device.

01:10:38.410 --> 01:10:42.355 align:middle line:84%
You end up getting two channels
in this thin silicon film.

01:10:42.355 --> 01:10:44.230 align:middle line:84%
So they may have FinFET
and they demonstrated

01:10:44.230 --> 01:10:47.890 align:middle line:84%
they could make a nickel
silicide gate going

01:10:47.890 --> 01:10:50.180 align:middle line:90%
all the way around that fin.

01:10:50.180 --> 01:10:52.180 align:middle line:84%
In fact, this is the gate
dielectric shown here,

01:10:52.180 --> 01:10:55.630 align:middle line:84%
this amorphous-looking
region with nickel silicide

01:10:55.630 --> 01:10:56.770 align:middle line:90%
on the outside.

01:10:56.770 --> 01:11:00.100 align:middle line:84%
Again, using a FUSI process
where they put poly everywhere,

01:11:00.100 --> 01:11:03.710 align:middle line:84%
put down the appropriate amount
of nickel, and then reacted it.

01:11:03.710 --> 01:11:06.610 align:middle line:84%
And the reaction stopped right
when it hit the gate dielectric.

01:11:06.610 --> 01:11:10.240 align:middle line:90%


01:11:10.240 --> 01:11:11.770 align:middle line:84%
An interesting
thing that was also

01:11:11.770 --> 01:11:13.300 align:middle line:84%
done in this paper,
if you end up

01:11:13.300 --> 01:11:18.407 align:middle line:84%
wanting to do research in this
area, is shown here on slide 34.

01:11:18.407 --> 01:11:20.740 align:middle line:84%
This is something called gate
work function engineering.

01:11:20.740 --> 01:11:24.253 align:middle line:84%
We hadn't really talked about
it, but the work function

01:11:24.253 --> 01:11:25.045 align:middle line:90%
between the metal--

01:11:25.045 --> 01:11:28.450 align:middle line:84%
I think we may have talked
about threshold voltage control.

01:11:28.450 --> 01:11:31.660 align:middle line:84%
The work function, which is a
property of the metal material,

01:11:31.660 --> 01:11:32.530 align:middle line:90%
to a certain extent.

01:11:32.530 --> 01:11:35.190 align:middle line:84%
And the silicon, that
determines the threshold voltage

01:11:35.190 --> 01:11:37.690 align:middle line:84%
of the transistor, the voltage
at which the transistor turns

01:11:37.690 --> 01:11:38.900 align:middle line:90%
on.

01:11:38.900 --> 01:11:40.960 align:middle line:84%
So that's a very
important property.

01:11:40.960 --> 01:11:44.140 align:middle line:84%
People have been using N
plus poly and P plus poly

01:11:44.140 --> 01:11:47.380 align:middle line:84%
on N FETs and P FETs for years
because it has the right work

01:11:47.380 --> 01:11:48.840 align:middle line:90%
function.

01:11:48.840 --> 01:11:50.590 align:middle line:84%
The problem with poly,
as we've mentioned,

01:11:50.590 --> 01:11:52.020 align:middle line:84%
is it doesn't have
enough carries.

01:11:52.020 --> 01:11:52.853 align:middle line:90%
It tends to deplete.

01:11:52.853 --> 01:11:54.180 align:middle line:90%
So people want to use metals.

01:11:54.180 --> 01:11:56.790 align:middle line:84%
The problem with metals is,
what work function do they have?

01:11:56.790 --> 01:11:59.160 align:middle line:84%
Well, they have the work
function, typically,

01:11:59.160 --> 01:12:01.342 align:middle line:84%
of the metal, which is
a property of the metal.

01:12:01.342 --> 01:12:03.300 align:middle line:84%
And there are only so
many metals in the world.

01:12:03.300 --> 01:12:05.850 align:middle line:84%
There are only so many
silicides in the world.

01:12:05.850 --> 01:12:08.880 align:middle line:84%
But what IBM has shown
in this particular paper

01:12:08.880 --> 01:12:12.570 align:middle line:84%
is that they can adjust
slightly the effective work

01:12:12.570 --> 01:12:17.190 align:middle line:84%
function of that gate
stack, so the effect of work

01:12:17.190 --> 01:12:21.870 align:middle line:84%
function in between this metal
gate and the silicon material.

01:12:21.870 --> 01:12:24.510 align:middle line:84%
They said they can adjust
it to a certain extent

01:12:24.510 --> 01:12:29.040 align:middle line:84%
by how much they dope
the polysilicon prior

01:12:29.040 --> 01:12:30.810 align:middle line:90%
to the silicide reaction.

01:12:30.810 --> 01:12:34.050 align:middle line:84%
And this is just a table that
I took right out of that paper.

01:12:34.050 --> 01:12:36.770 align:middle line:84%
For the case of nickel
silicide, what they found is,

01:12:36.770 --> 01:12:39.810 align:middle line:84%
depending exactly on how much
doping they put into the gate

01:12:39.810 --> 01:12:42.810 align:middle line:84%
to begin with-- say
if they don't dope it,

01:12:42.810 --> 01:12:46.860 align:middle line:84%
or if they put in
1e20, 2e20, or 4e20,

01:12:46.860 --> 01:12:50.220 align:middle line:84%
the effect of work function
that they measure with respect

01:12:50.220 --> 01:12:52.450 align:middle line:84%
to the silicon conduction
band is shown here.

01:12:52.450 --> 01:12:56.840 align:middle line:84%
It can be varied, maybe
by about 100 millivolts.

01:12:56.840 --> 01:12:58.400 align:middle line:90%
Maybe a little more.

01:12:58.400 --> 01:12:59.390 align:middle line:90%
Something like that.

01:12:59.390 --> 01:13:01.130 align:middle line:84%
I guess the nickel
silicide was 0.

01:13:01.130 --> 01:13:03.505 align:middle line:84%
So it's a little more, maybe
a couple hundred millivolts,

01:13:03.505 --> 01:13:06.710 align:middle line:84%
it can be varied by whether
you put doping in or not

01:13:06.710 --> 01:13:08.270 align:middle line:90%
and by how much doping.

01:13:08.270 --> 01:13:11.690 align:middle line:84%
And this is important because
you need this flexibility

01:13:11.690 --> 01:13:13.710 align:middle line:84%
in being able to adjust
your threshold voltage.

01:13:13.710 --> 01:13:16.430 align:middle line:84%
So FUSI gates are
also interesting,

01:13:16.430 --> 01:13:18.050 align:middle line:84%
not just because
it's a little easier

01:13:18.050 --> 01:13:19.857 align:middle line:90%
to integrate the processing.

01:13:19.857 --> 01:13:22.190 align:middle line:84%
The frontend processing is
what we're all familiar with.

01:13:22.190 --> 01:13:23.780 align:middle line:84%
Everyone knows how
to etch a poly gate

01:13:23.780 --> 01:13:27.050 align:middle line:84%
and make a good poly gate, and
you can convert it to silicide.

01:13:27.050 --> 01:13:28.550 align:middle line:84%
But depending on
how you dope it,

01:13:28.550 --> 01:13:30.770 align:middle line:84%
you may be able
to control the PT

01:13:30.770 --> 01:13:33.170 align:middle line:90%
or adjust the PT a little bit.

01:13:33.170 --> 01:13:35.780 align:middle line:84%
It's still a very
tricky process.

01:13:35.780 --> 01:13:39.670 align:middle line:84%
The reaction temperature or the
thermal stability temperature

01:13:39.670 --> 01:13:40.970 align:middle line:90%
is reasonably low.

01:13:40.970 --> 01:13:43.850 align:middle line:84%
So you cannot take these and
then take them to a backend

01:13:43.850 --> 01:13:46.290 align:middle line:90%
process that is too hot.

01:13:46.290 --> 01:13:47.720 align:middle line:90%
So they're very much a research.

01:13:47.720 --> 01:13:49.845 align:middle line:84%
It was only published by
IBM a couple of years ago.

01:13:49.845 --> 01:13:52.280 align:middle line:84%
It's certainly not
ready necessarily

01:13:52.280 --> 01:13:53.570 align:middle line:90%
for manufacturing right now.

01:13:53.570 --> 01:13:55.070 align:middle line:84%
Perhaps in the near
future, but just

01:13:55.070 --> 01:13:57.780 align:middle line:84%
to give you an idea
of the types of things

01:13:57.780 --> 01:14:02.057 align:middle line:84%
that people are concerned
about with siliciding.

01:14:02.057 --> 01:14:03.640 align:middle line:84%
Before I go through
the summary, let's

01:14:03.640 --> 01:14:05.270 align:middle line:84%
take a few minutes,
because we have

01:14:05.270 --> 01:14:06.520 align:middle line:90%
a couple of minutes right now.

01:14:06.520 --> 01:14:08.920 align:middle line:84%
I just want to go through
with you very briefly,

01:14:08.920 --> 01:14:16.720 align:middle line:84%
if we back up a little bit
here onto slide number 27.

01:14:16.720 --> 01:14:19.937 align:middle line:84%
And you can sit down and do this
back-of-the-envelope calculation

01:14:19.937 --> 01:14:21.520 align:middle line:84%
yourself over the
next couple of days.

01:14:21.520 --> 01:14:23.937 align:middle line:84%
It's not a homework assignment,
but I think it's something

01:14:23.937 --> 01:14:24.850 align:middle line:90%
you should do--

01:14:24.850 --> 01:14:29.110 align:middle line:84%
how to calculate these
three resistances.

01:14:29.110 --> 01:14:31.832 align:middle line:84%
And then we can talk about it
and go through it next time.

01:14:31.832 --> 01:14:33.290 align:middle line:84%
But what I want
you to calculate is

01:14:33.290 --> 01:14:36.280 align:middle line:84%
you're given everything you
need to calculate the contact

01:14:36.280 --> 01:14:37.150 align:middle line:90%
resistance.

01:14:37.150 --> 01:14:40.060 align:middle line:84%
You're given the specific
contact resistivity rho C.

01:14:40.060 --> 01:14:41.810 align:middle line:84%
And you're given the
area of the contact.

01:14:41.810 --> 01:14:43.330 align:middle line:84%
So you know exactly
how to calculate that.

01:14:43.330 --> 01:14:44.650 align:middle line:90%
You just do a simple division.

01:14:44.650 --> 01:14:47.410 align:middle line:84%
And you can calculate
this resistor, the contact

01:14:47.410 --> 01:14:48.610 align:middle line:90%
resistance.

01:14:48.610 --> 01:14:50.800 align:middle line:84%
You're given the sheet
resistance of the silicide,

01:14:50.800 --> 01:14:51.730 align:middle line:90%
this blue region.

01:14:51.730 --> 01:14:56.380 align:middle line:84%
You have its sheet resistance,
or it's resistivity, I'm sorry--

01:14:56.380 --> 01:14:58.900 align:middle line:84%
15 times 10 to the
-6 ohm centimeter.

01:14:58.900 --> 01:15:00.280 align:middle line:90%
And you know its thickness.

01:15:00.280 --> 01:15:03.010 align:middle line:84%
So resistivity
divided by thickness,

01:15:03.010 --> 01:15:04.240 align:middle line:90%
you can get sheet resistance.

01:15:04.240 --> 01:15:07.300 align:middle line:84%
And then you can figure out
how many squares the current

01:15:07.300 --> 01:15:08.290 align:middle line:90%
has to flow through.

01:15:08.290 --> 01:15:11.320 align:middle line:84%
So you should be able to
calculate this resistance

01:15:11.320 --> 01:15:12.910 align:middle line:90%
of the silicided regions.

01:15:12.910 --> 01:15:14.290 align:middle line:84%
And then the little
resistor here

01:15:14.290 --> 01:15:18.400 align:middle line:84%
of the source drain
extensions, we

01:15:18.400 --> 01:15:21.560 align:middle line:84%
are given their resistivity,
and again, its thickness.

01:15:21.560 --> 01:15:23.770 align:middle line:84%
So we should be able to
calculate a sheet resistance,

01:15:23.770 --> 01:15:25.493 align:middle line:84%
and from that
figure out-- so you

01:15:25.493 --> 01:15:27.410 align:middle line:84%
get the ohms square and
the number of squares.

01:15:27.410 --> 01:15:28.430 align:middle line:90%
And you get a resistor.

01:15:28.430 --> 01:15:31.750 align:middle line:84%
So one, two, and three
resistors corresponding

01:15:31.750 --> 01:15:34.362 align:middle line:84%
to this contact
resistance, the resistance

01:15:34.362 --> 01:15:36.070 align:middle line:84%
of the current flowing
through the sheet,

01:15:36.070 --> 01:15:38.440 align:middle line:84%
and the resistance flowing
through the source drain

01:15:38.440 --> 01:15:39.580 align:middle line:90%
extension.

01:15:39.580 --> 01:15:41.290 align:middle line:84%
You'll get three
numbers, and you just

01:15:41.290 --> 01:15:43.540 align:middle line:84%
get an idea of the order of
magnitude of those numbers

01:15:43.540 --> 01:15:45.080 align:middle line:90%
and how they compare.

01:15:45.080 --> 01:15:47.740 align:middle line:84%
So if you have time between
now and next lecture, do that.

01:15:47.740 --> 01:15:50.480 align:middle line:84%
We'll go through it at the
beginning of the last lecture

01:15:50.480 --> 01:15:50.980 align:middle line:90%
next time.

01:15:50.980 --> 01:15:53.710 align:middle line:84%
But just an
interesting comparison

01:15:53.710 --> 01:15:56.110 align:middle line:90%
between those three numbers.

01:15:56.110 --> 01:16:03.790 align:middle line:84%
OK, so let me finish up by kind
of summarizing on this topic.

01:16:03.790 --> 01:16:06.990 align:middle line:84%
What we talked about today,
we need good device contacts.

01:16:06.990 --> 01:16:09.990 align:middle line:84%
They have certain requirements--
a low specific contact

01:16:09.990 --> 01:16:12.940 align:middle line:84%
resistance, rho C. Very
good thermal stability

01:16:12.940 --> 01:16:14.940 align:middle line:84%
so when you heat them up,
they don't spike or do

01:16:14.940 --> 01:16:16.560 align:middle line:90%
anything unusual.

01:16:16.560 --> 01:16:18.840 align:middle line:84%
In general, you want
to get a high doping

01:16:18.840 --> 01:16:21.210 align:middle line:84%
concentration of a silicon
right at the interface.

01:16:21.210 --> 01:16:24.090 align:middle line:84%
That will tend to lower the
contact resistance by inducing

01:16:24.090 --> 01:16:27.510 align:middle line:90%
quantum mechanical tunneling.

01:16:27.510 --> 01:16:30.240 align:middle line:84%
However, there is a fundamental
limit on how much doping we

01:16:30.240 --> 01:16:31.800 align:middle line:90%
can activate in silicon.

01:16:31.800 --> 01:16:34.270 align:middle line:84%
This puts a limit on
the contact resistance

01:16:34.270 --> 01:16:37.450 align:middle line:84%
and on the sheet resistance and
on the parasitic resistance.

01:16:37.450 --> 01:16:40.260 align:middle line:84%
In fact, the contact resistance
is really a big problem.

01:16:40.260 --> 01:16:41.850 align:middle line:84%
If you look in the
ITRS, there's a lot

01:16:41.850 --> 01:16:45.350 align:middle line:84%
of concern about
how to lower that.

01:16:45.350 --> 01:16:48.560 align:middle line:84%
The so-called self-aligned
silicide process, or also

01:16:48.560 --> 01:16:51.830 align:middle line:84%
abbreviated salicide, has been
the mainstay of technology

01:16:51.830 --> 01:16:54.290 align:middle line:90%
for many, many years now.

01:16:54.290 --> 01:16:56.360 align:middle line:90%
It has a lot of advantages.

01:16:56.360 --> 01:16:57.380 align:middle line:90%
It's self-aligned.

01:16:57.380 --> 01:17:00.560 align:middle line:84%
It reduces the sheet resistance
of the deep source drain region.

01:17:00.560 --> 01:17:02.270 align:middle line:84%
It reduces the gate
sheet resistance

01:17:02.270 --> 01:17:04.370 align:middle line:84%
because you put
silicide on the gate.

01:17:04.370 --> 01:17:06.560 align:middle line:84%
And it also provides a
local interconnect layer.

01:17:06.560 --> 01:17:10.880 align:middle line:84%
So it's been a very
good workhorse.

01:17:10.880 --> 01:17:13.070 align:middle line:84%
Silicides can also
function as a barrier layer

01:17:13.070 --> 01:17:16.310 align:middle line:90%
to prevent spiking, potentially.

01:17:16.310 --> 01:17:18.170 align:middle line:90%
Silicides do consume silicon.

01:17:18.170 --> 01:17:20.840 align:middle line:90%
That's one problem with them.

01:17:20.840 --> 01:17:23.870 align:middle line:84%
And as you move the metal
closer to the junction depletion

01:17:23.870 --> 01:17:26.608 align:middle line:84%
region, it's a big
problem because you

01:17:26.608 --> 01:17:27.650 align:middle line:90%
tend to get more leakage.

01:17:27.650 --> 01:17:29.900 align:middle line:84%
In fact, this is why people
use deep source drain

01:17:29.900 --> 01:17:34.910 align:middle line:84%
regions to allow a thick enough
region in between the depletion

01:17:34.910 --> 01:17:38.450 align:middle line:84%
region and the point where
the silicide is formed.

01:17:38.450 --> 01:17:40.190 align:middle line:84%
So you can get a
reasonable silicide

01:17:40.190 --> 01:17:42.170 align:middle line:90%
with low junction leakage.

01:17:42.170 --> 01:17:45.650 align:middle line:84%
Because junctions are scaling
to be thinner and thinner,

01:17:45.650 --> 01:17:47.450 align:middle line:84%
especially in
fully depleted SOI,

01:17:47.450 --> 01:17:49.610 align:middle line:84%
people are moving
towards nickel silicide

01:17:49.610 --> 01:17:52.940 align:middle line:84%
because it consumes a lot
less silicon per thickness

01:17:52.940 --> 01:17:56.150 align:middle line:84%
of silicide than, say,
Ti-silicide or cobalt silicide.

01:17:56.150 --> 01:17:58.850 align:middle line:84%
So for fully depleted
SOI, nickel silicide

01:17:58.850 --> 01:18:00.650 align:middle line:90%
has a lot of advantages.

01:18:00.650 --> 01:18:02.900 align:middle line:84%
And the last thing, which
isn't in the summary we just

01:18:02.900 --> 01:18:04.567 align:middle line:84%
talked about, is that
silicides are even

01:18:04.567 --> 01:18:08.580 align:middle line:84%
being considered to be fully
silicide purpose for the gate.

01:18:08.580 --> 01:18:10.670 align:middle line:84%
And that's something that's
in research right now,

01:18:10.670 --> 01:18:14.270 align:middle line:84%
you may see in production over
the next three or four years

01:18:14.270 --> 01:18:15.510 align:middle line:90%
or so.

01:18:15.510 --> 01:18:17.450 align:middle line:84%
So that's all I have
for this lecture.

01:18:17.450 --> 01:18:20.430 align:middle line:84%
Take a look at that simple
calculation example by hand.

01:18:20.430 --> 01:18:25.530 align:middle line:84%
And then next time we'll
meet for the final lecture.

01:18:25.530 --> 01:18:28.290 align:middle line:84%
And again, I announced
it at the beginning.

01:18:28.290 --> 01:18:30.730 align:middle line:84%
The people who are going to
be speaking in the order,

01:18:30.730 --> 01:18:32.440 align:middle line:90%
it's also posted on the website.

01:18:32.440 --> 01:18:36.600 align:middle line:84%
But if you have any questions
about your oral report

01:18:36.600 --> 01:18:39.600 align:middle line:84%
or whatever, please
get back to me.

01:18:39.600 --> 01:18:41.855 align:middle line:90%
OK, thanks.

01:18:41.855 --> 01:18:48.000 align:middle line:90%