5.73 | Fall 2018 | Graduate

Quantum Mechanics I

Lecture Notes

ses # topics  
1–9: One-Dimensional Problems
1 Course Outline; Free Particle; Motion (PDF)  
2 Infinite Box, \(\delta(x)\)  Well, \(\delta(x)\)  Barrier (PDF - 1.0MB)  
3 Probability Density: Motion, Position, Spreading, Gaussian Wavepacket (PDF - 1.6MB)  
4 Stationary Phase and Gaussian Wavepackets (PDF)  
5 Continuum Normalization (PDF)  
6 Linear Potential; JWKB Approximation and Quantization (PDF - 1.4MB)  
7 JWKB Quantization Condition (PDF - 1.1MB)  
8 Rydberg-Klein-Rees: \(V(x)\)  from \(E_{vJ}\)(PDF - 1.4MB)  
9 Numerov-Cooley Method: 1-D Schrödinger Equation (PDF)  
10–19: Matrix Mechanics
10 Matrix Mechanics (PDF - 1.1MB)  
11 Eigenvalues, Eigenvectors, and Discrete Variable Representation (PDF - 1.1MB)  
12 Matrix Solution of Harmonic Oscillator I (PDF - 1.1MB)  
13 Matrix Solution of Harmonic Oscillator II (PDF - 1.3MB)  
14 Perturbation Theory I (PDF - 1.2MB)  
15 Perturbation Theory II (PDF - 1.2MB)  
16 Perturbation Theory III (PDF - 1.2MB)  
17 Perturbation Theory IV (PDF - 1.1MB)  
18 Variational Method (PDF)  
19 Density Matrices I (PDF)  
20–29: Central Forces and Angular Momentum
20 Density Matrices II (PDF - 1.0MB)  
21 3-D Central Force Problems I (PDF - 1.5MB)  
22 3-D Central Force Problems II (PDF - 1.6MB)  
23 Angular Momentum Matrix Elements from Commutation Rules (PDF)  
24 J-Matrices (PDF - 1.3MB)  
25 HSO + HZeeman: Coupled vs. Uncoupled Basis Sets (PDF - 1MB)  
26 HSO + HZeeman in ⎜JLSMJ\(\rangle\)  and ⎜LMLMS\(\rangle\)  by Ladders plus Orthogonality (PDF)  
27 Wigner-Eckart Theorem (PDF - 1.2MB) 
Lecture 27 Supplement 1: Angular Momentum Eigenvalues (PDF) (Courtesy of Dudley Herschbach. Used with permission.) 
Lecture 27 Supplement 2: Simplification of hyperfine Hhf by Wigner-Eckart Theorem (PDF) 
Lecture 27 Supplement 3: A User’s Guide to Angular Momentum Theory (PDF - 2.2MB)
 
28 Hydrogen Radial Wavefunctions (PDF - 1.1MB)  
29 Begin Many-Electron Atoms: Quantum Defect Theory (PDF - 1.0MB)  
30–39: Many Particle Systems: Atoms, Coupled Oscillators, Periodic Lattice
30 Matrix Elements of Many-Electron Wavefunctions (PDF - 1.3MB)  
31 Matrix Elements of One-Electron, \(F(i)\), and Two-Electron, \(G(i,j)\)  Operators (PDF - 1.2MB)  
32 Configurations and Resultant L–S–J States (PDF - 1.4MB)  
33 L-S Terms via L2, S2 and Projection (PDF - 1.0MB)  
34 \(e^2/r_{ij}\)  and Slater Sum Rule Method (PDF - 1.3MB)  
35 Spin Orbit: Many Electron ζ(N,L,S)↔Single Orbital ζ\(_{nl}\)  Coupling Constants (PDF - 1.2MB)  
36 Holes; Hund’s Third Rule; Landé g-Factor via W-E Theorem (PDF)  
37 Infinite 1-D Lattice I (PDF - 1.0MB)  
38 Infinite 1-D Lattice II (PDF - 1.1MB)  
39 One-Dimensional Lattice: Weak-Coupling Limit (PDF - 1.0MB)  

Course Info

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Fall 2018
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Lecture Notes