**I. Introduction** |

1 | Syllabus, Overview | |

2 | Basic Physics of Galvanic Cells, Electrochemical Energy Conversion (PDF) | 2011 Lecture 1: Basic Physics of Galvanic Cells (PDF) 2011 Lecture 2: Electrochemical Energy Conversion (PDF) [Newman] Chapter 1. [O'Hayre] Chapter 2. |

3 | Electrochemical Energy Storage (PDF) | 2011 Lecture 3: Electrochemical Energy Storage (PDF) [Huggins] Chapter 1. |

**II. Circuit Models** |

4 | Equivalent Circuit Dynamics | 2011 Lecture 4: Dynamics of Equivalent Circuits (PDF) |

5 | Impedance I | 2011 Lecture 5: Impedance spectroscopy (PDF - 1.6MB) [Bard] Chapter 10. [O'Hayre] Chapter 7, sec. 3.4. |

6 | Impedance II | 2011 Lecture 6: Impedance of Electrode (PDF) |

7 | Impedance III |

**III. Thermodynamics** |

8 | Statistical Thermodynamics, Regular Solution Model | 2011 Lecture 7: Statistical Thermodynamics (PDF) |

9 | Nernst Equation, Open Circuit Voltage | 2011 Lecture 8: The Nernst Equation (PDF) [Newman] Chapter 2. |

10 | Fuel Cells and Batteries | 2011 Lecture 9: Fuel Cells and Lead-Acid Batteries (PDF) [O'Hayre] Chapter 2. |

11 | Pourbaix Diagram (PDF) | 2011 Lecture 9: Fuel Cells and Lead-Acid Batteries (PDF) Prentice, Geoffrey A. Chapter 3 in *Electrochemical Engineering Principles*. Prentice Hall, 1990. ISBN: 9780132490382. |

12 | Metal Acid Batteries, Lemon Battery Demo (PDF) | |

13 | Li-ion Batteries, Pseudocapacitance (PDF - 1.3MB) | 2011 Lecture 10: Li-ion Batteries (PDF) 2011 Lecture 37: Pseudocapacitors and Batterie (PDF - 2.1MB) [Huggins] Chapters 2 and 6. |

14 | Ideal Solution Model, Linear Sweep Voltammetry (PDF) | 2011 Lecture 11: Reconstitution Electrodes (PDF) [Huggins] Chapters 3 and 6. |

15 | Regular Solution Model, Phase Separation | 2011 Lecture 11: Reconstitution Electrodes (PDF) |

**IV. Kinetics** |

16 | Reactions in Concentrated Solutions | 2011 Lecture 14: Faradaic Reactions in Concentrated Solutions (PDF) Bazant, M. Z. "Theory of Chemical Kinetics and Charge Transfer Based on Nonequilibrium Thermodynamics." *Accounts of Chemical Research* 46, no. 5 (2013): 1146–47. |

17 | Faradaic Reactions | 2011 Lecture 12: Faradaic Reactions in Dilute Solutions (PDF) 2011 Lecture 13: Butler-Volmer Equation (PDF) Bazant, M. Z. "Theory of Chemical Kinetics and Charge Transfer Based on Nonequilibrium Thermodynamics." *Accounts of Chemical Research* 46, no. 5 (2013): 1148–49. |

18 | Butler-Volmer Equation | [O'Hayre] Chapter 3. [Newman] Chapter 8. [Bard] Chapter 3. |

19 | Electrocatalysis (PDF) | 2011 Lecture 15: Ion Adsorption and Intercalation (PDF) Bazant, M. Z. "Theory of Chemical Kinetics and Charge Transfer Based on Nonequilibrium Thermodynamics." *Accounts of Chemical Research* 46, no. 5 (2013): 1155–57. |

20-21 | Electrochemical Phase Transformations (PDF - 1.5MB) | Bai, P., D. A. Cogswell, et al. "Suppression of Phase Separation in LiFePO4 Nanoparticles During Battery Discharge." *Nano Letters* 11, no. 11 (2011): 4890–96. |

22 | Homogeneous Charge Transfer (PDF) | [Bard] Chapter 3, sec. 6. |

23 | Heterogeneous Charge Transfer (PDF) | Bazant, M. Z. "Theory of Chemical Kinetics and Charge Transfer Based on Nonequilibrium Thermodynamics." *Accounts of Chemical Research* 46, no. 5 (2013): 1149–50. |

24 | Charge Transfer at Metal Electrodes (PDF) | Bai, P., and M. Z. Bazant. "Charge Transfer Kinetics at the Solid/Solid Interface in Porous Electrodes." *Nature Communications *5, no. 3585 (2014). Zeng, Y., R. Smith, P. Bai, and M.Z. Bazant. "Simple Formula for Marcus-Hush-Chidsey Kinetics." *J. Electroanal. Chem.* 735(2014): 77-83. |

**V. Transport Phenomena** |

25 | Concentration Polarization | 2011 Lecture 16: Concentration Polarization (PDF) [O'Hayre] Chapter 5.2. |

26 | Transient Diffusion | 2011 Lecture 19: Transient Diffusion (PDF) [Bard] Chapters 7 and 8. |

27 | Warburg Impedance | 2011 Lecture 20: Warburg Impedance (PDF) [Bard] Chapter 10. |

28 | Forced Convection I (PDF) | 2011 Lecture 17: Forced Convection in Fuel Cells (I) (PDF) [O'Hayre] Chapter 5.3. [Newman] Chapter 17. Deen, William M. *Analysis of Transport Phenomena*. Oxford University Press, 1998. ISBN: 9780195084948. Braff, W. A., C. R. Buie, et al. "Boundary Layer Analysis of Electrochemical Cells." *Journal of the Electrochemical Society *160, no. 11 (2013): A2056–63. |

29 | Forced Convection II (PDF) | Braff, W. A., C. R. Buie, et al. "Boundary Layer Analysis of Electrochemical Cells." *Journal of the Electrochemical Society *160, no. 11 (2013): A2056–63. |

30 | Forced Convection III | 2011 Lecture 18: Forced Convection in Fuel Cells II (PDF) |

31 | Transport in Solids | 2011 Lecture 21: Solids and Concentrated Solutions (PDF) Bazant, M. Z. "Theory of Chemical Kinetics and Charge Transfer Based on Nonequilibrium Thermodynamics." *Accounts of Chemical Research* 46, no. 5 (2013): 1147. |

32 | Concentrated Solutions, Bulk Electrolytes | 2011 Lecture 22: Transport in Bulk Electrolytes (PDF) [Newman] Chapter 11. |

33 | Homogeneous Reaction-diffusion (PDF) | |

34 | Ion Concentration Polarization | 2011 Lecture 22: Transport in Bulk Electrolytes (PDF) 2011 Lecture 23: Ion Concentration Polarization (PDF) [Newman] Chapter 11. [Newman] Chapter 4. |

35 | Double Layers, Supercapacitors | 2011 Lecture 24: Diffuse Charge in Electrolyte (PDF) 2011 Lecture 25: Diffuse Double Layer Structure (PDF) [Newman] Chapter 7. |

36 | Transport in Porous Media | 2011 Lecture 32: Percolation (PDF) 2011 Lecture 33: Macroscopic Conductivity of Composite (PDF - 1.5MB) 2011 Lecture 34: Transport in Porous Media (PDF - 1.5MB) |

37 | Scaling Analysis of Energy Storage | 2012 Lecture 36–37: Scaling Analysis of Energy Storage by Porous Electrodes (PDF) |

38 | Porous Electrodes (Overview) | 2011 Lecture 35: Porous Electrodes (I. Supercapacitors) (PDF - 1.1MB) 2011 Lecture 36: Electrochemical Supercapacitor (PDF - 1.3MB) 2011 Lecture 37: Pseudocapacitors and Batteries (PDF - 2.1MB) [Newman] Chapter 22. Ferguson, T. R., and M. Z. Bazant. "Nonequilibrium Thermodynamics of Porous Electrodes." *Journal Electrochemical Society* 159, no. 12 (2012): A1967–A1985. |