8.06 | Spring 2018 | Undergraduate

Quantum Physics III

Video Lectures

The videos in this course are broadly divided into three parts:

Part 1. Time Independent Perturbation Theory and WKB Approximation.

In this section, we discuss in detail non-degenerate and degenerate time-independent perturbation theory. As an application and illustration of the methods, we study the fine structure of the hydrogen atom as well as the Zeeman effect, both in its weak and strong forms. We develop the Wentzel-Kramers-Brillouin (WKB) approximation, useful for time-independent problems that involve potentials with slow-varying spatial dependence.

Part 2. Time Dependent Perturbation Theory and Adiabatic Approximation. 

In this section, we begin by developing perturbation theory for time-dependent Hamiltonians. We then turn to Fermi’s Golden Rule, and then to the interaction of light with atoms, focusing on the processes of absorption, stimulated emission, and spontaneous emission. We discuss charged particles in electromagnetic fields and derive the Landau levels of a particle in a uniform magnetic field. We study in detail the Adiabatic approximation, discussing Landau-Zener transitions, Berry’s phase, and the Born-Oppenheimer approximation for molecules.

Part 3. Scattering and Identical Particles. 

The final part of the course begins with a study of scattering. We discuss cross sections and develop the theory of partial waves and phase shifts. An integral reformulation of the scattering problem leads to the Born approximation. We then turn to the subject of identical particles. We explain the exchange degeneracy problem and develop the machinery of permutation operators, symmetrizers and anti-symmetrizers. We discuss the symmetrization postulate and discuss the construction and properties of multi particle bosonic and fermonic states.

lec # topics
Lecture 19: Scattering
L19.1 L19.1 Elastic scattering defined and assumptions (15:35)
L19.2 L19.2 Energy eigenstates: incident and outgoing waves. Scattering amplitude (25:02)
L19.3 L19.3 Differential and total cross section (20:20)
L19.4 L19.4 Differential as a Sum of Partial Waves (17:46)
Lecture 20: Scattering (continued 1)
L20.1 L20.1 Review of Scattering Concepts Developed So Far (9:02)
L20.2 L20.2 The One-Dimensional Analogy for Phase Shifts (16:57)
L20.3 L20.3 Scattering Amplitude in Terms of Phase Shifts (14:59)
L20.4 L20.4 Cross Section in Terms of Partial Cross Sections. Optical Theorem (13:13)
L20.5 L20.5 Identification of Phase Shifts. Example: Hard Sphere (18:01)
Lecture 21: Scattering (continued 2)
L21.1 L21.1 General Computation of the Phase Shifts (18:14)
L21.2 L21.2 Phase Shifts and Impact Parameter (27:38)
L21.3 L21.3 Integral Equation for Scattering and Green’s Function (30:26)
Lecture 22: Scattering (continued 3). Identical Particles
L22.1 L22.1 Setting Up the Born Series (21:07)
L22.2 L22.2 First Born Approximation. Calculation of the Scattering Amplitude (13:02)
L22.3 L22.3 Diagrammatic Representation of the Born series. Scattering Amplitude for Spherically Symmetric Potentials (21:41)
L22.4 L22.4 Identical Particles and Exchange Degeneracy (19:41)
Lecture 23: Identical Particles (continued 1)
L23.1 L23.1 Permutation Operators and Projectors for Two Particles (22:22)
L23.2 L23.2 Permutation Operators Acting on Operators (11:44)
L23.3 L23.3 Permutation Operators on N Particles and Transpositions (29:39)
L23.4 L23.4 Symmetric and Antisymmetric States of N Particles (11:34)
Lecture 24: Identical Particles (continued 2)
L24.1 L24.1 Symmetrizer and Antisymmetrizer for N Particles (16:48)
L24.2 L24.2 Symmetrizer and Antisymmetrizer for N Particles (continued) (24:53)
L24.3 L24.3 The Symmetrization Postulate (11:37)
L24.4 L24.4 The Symmetrization Postulate (continued) (continued) (20:49)

lec # topics  
Lecture 10: Fermi’s Golden Rule
L10.1 L10.1 Box regularization: density of states for the continuum (20:31)  
L10.2 L10.2 Transitions with a constant perturbation (19:01)  
L10.3 L10.3 Integrating over the continuum to find Fermi’s Golden Rule (19:37)  
L10.4 L10.4 Autoionization transitions (11:30)  
Lecture 11: Fermi’s Golden Rule for Harmonic Transitions
L11.1 L11.1 Harmonic transitions between discrete states (15:12)  
L11.2 L11.2 Transition rates for stimulated emission and absorption processes (17:12)  
L11.3 L11.3 Ionization of hydrogen: conditions of validity, initial and final states (20:54)  
L11.4 L11.4 Ionization of Hydrogen: Matrix Element for Transition (22:20)  
Lecture 12: Hydrogen Ionization (completed). Light and Atoms
L12.1 L12.1 Ionization Rate for Hydrogen: Final Result (16:23)  
L12.2 L12.2 Light and Atoms with Two Levels, Qualitative Analysis (14:31)  
L12.3 L12.3 Einstein’s Argument: the Need for Spontaneous Emission (19:31)  
L12.4 L12.4 Einstein’s argument: B and A coefficients (9:42)  
L12.5 L12.5 Atom-light interactions: dipole operator (11:10)  
Lecture 13: Light and Atoms (continued). Charged Particles in Electromagnetic Fields
L13.1 L13.1 Transition rates induced by thermal radiation (17:50)  
L13.2 L13.2 Transition rates induced by thermal radiation (continued) (16:35)  
L13.3 L13.3 Einstein’s B and A coefficients determined. Lifetimes and selection rules (13:54)  
L13.4 L13.4 Charged particles in EM fields: potentials and gauge invariance (21:50)  
L13.5 L13.5 Charged particles in EM fields: Schrodinger equation (8:38)  
Lecture 14: Charged Particles in Electromagnetic Fields (continued)
L14.1 L14.1 Gauge invariance of the Schrodinger Equation (21:08)  
L14.2 L14.2 Quantization of the magnetic field on a torus (25:14)  
L14.3 L14.3 Particle in a constant magnetic field: Landau levels (18:19)  
L14.4 L14.4 Landau levels (continued). Finite sample (9:07)  
Lecture 15: Adiabatic Approximation
L15.1 L15.1 Classical analog: oscillator with slowly varying frequency (16:34)  
L15.2 L15.2 Classical adiabatic invariant (15:07)  
L15.3 L15.3 Phase space and intuition for quantum adiabatic invariants (16:23)  
L15.4 L15.4 Instantaneous energy eigenstates and Schrodinger equation (26:46)  
Lecture 16: Adiabatic Approximation (continued)
L16.1 L16.1 Quantum adiabatic theorem stated (13:02)  
L16.2 L16.2 Analysis with an orthonormal basis of instantaneous energy eigenstates (14:31)  
L16.3 L16.3 Error in the adiabatic approximation (14:21)  
L16.4 L16.4 Landau-Zener transitions (19:30)  
L16.5 L16.5 Landau-Zener transitions (continued) (14:18)  
Lecture 17: Adiabatic Approximation: Berry’s Phase
L17.1 L17.1 Configuration space for Hamiltonians (15:27)  
L17.2 L17.2 Berry’s phase and Berry’s connection (25:04)  
L17.3 L17.3 Properties of Berry’s phase (11:12)  
L17.4 L17.4 Molecules and energy scales (17:57)  
Lecture 18: Adiabatic Approximation: Molecules
L18.1 L18.1 Born-Oppenheimer approximation: Hamiltonian and electronic states (24:48)  
L18.2 L18.2 Effective nuclear Hamiltonian. Electronic Berry connection (20:02)  
L18.3 L18.3 Example: The hydrogen molecule ion (27:01)  

lec # topics
Lecture 1: Time Independent Perturbation Theory
L1.1 L1.1 General problem. Non-degenerate perturbation theory (22:55)
L1.2 L1.2 Setting up the perturbative equations (16:07)
L1.3 L1.3 Calculating the energy corrections (6:25)
L1.4 L1.4 First order correction to the state. Second order correction to energy (13:43)
Lecture 2: Time Independent Perturbation Theory (continued)
L2.1 L2.1 Remarks and validity of the perturbation series (22:26)
L2.2 L2.2 Anharmonic Oscillator via a quartic perturbation (20:54)
L2.3 L2.3 Degenerate Perturbation theory: Example and setup (25:19)
L2.4 L2.4 Degenerate Perturbation Theory: Leading energy corrections (6:50)
Lecture 3: Degenerate Perturbation Theory
L3.1 L3.1 Remarks on a “good basis” (17:37)
L3.2 L3.2 Degeneracy resolved to first order; state and energy corrections (29:10)
L3.3 L3.3 Degeneracy resolved to second order (18:27)
L3.4 L3.4 Degeneracy resolved to second order (continued) (11:34)
Lecture 4: Hydrogen Atom Fine Structure
L4.1 L4.1 Scales and zeroth-order spectrum (25:49)
L4.2 L4.2 The uncoupled and coupled basis states for the spectrum (17:10)
L4.3 L4.3 The Pauli equation for the electron in an electromagnetic field (18:10)
L4.4 L4.4 Dirac equation for the electron and hydrogen Hamiltonian (14:59)
Lecture 5: Hydrogen Atom Fine Structure (continued)
L5.1 L5.1 Evaluating the Darwin correction (12:49)
L5.2 L5.2 Interpretation of the Darwin correction from nonlocality (21:46)
L5.3 L5.3 The relativistic correction (19:15)
L5.4 L5.4 Spin-orbit correction (8:30)
L5.5 L5.5 Assembling the fine-structure corrections (15:21)
Lecture 6: Zeeman Effect and Introduction to the Semiclassical Approximation
L6.1 L6.1 Zeeman effect and fine structure (13:06)
L6.2 L6.2 Weak-field Zeeman effect; general structure (10:08)
L6.3 L6.3 Weak-field Zeeman effect; the projection lemma (19:09)
L6.4 L6.4 Strong-field Zeeman (9:49)
L6.5 L6.5 Semiclassical approximation and local de Broglie wavelength (23:29)
Lecture 7: The Semiclassical WKB Approximation
L7.1 L7.1 The WKB approximation scheme (22:50)
L7.2 L7.2 Approximate WKB solutions (19:01)
L7.3 L7.3 Validity of the WKB approximation (17:00)
L7.4 L7.4 Connection formula stated and example (21:09)
Lecture 8: WKB (continued). Airy Functions and Connection Formulae
L8.1 L8.1 Airy functions as integrals in the complex plane (17:53)
L8.2 L8.2 Asymptotic expansions of Airy functions (19:36)
L8.3 L8.3 Deriving the connection formulae (22:30)
L8.4 L8.4 Deriving the connection formulae (continued) logical arrows (14:44)
Lecture 9: Time Dependent Perturbation Theory
L9.1 L9.1 The interaction picture and time evolution (26:32)
L9.2 L9.2 The interaction picture equation in an orthonormal basis (15:06)
L9.3 L9.3 Example: Instantaneous transitions in a two-level system (29:23)
L9.4 L9.4 Setting up perturbation theory (6:35)

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