Physical Chemistry II | Chemistry | MIT OpenCourseWare

Lecture Notes

Assemblies⇒Ensembles, the Ergodic Hypothesis

Band Theory of Solids

Boltzmann, Fermi-Dirac, and Bose–Einstein Statistics

Calculation Of Macroscopic Properties From Microscopic Energy Levels

Canonical Partition Function: Replace {Pi} by Q

Chemical Equilibrium I

Chemical equilibrium II

Configurational Integral: Cluster Expansion

E, A, and S: Macroscopic Propertiesfrom Microscopic Probabilities {Pi}

Einstein and Debye Solids

Einstein and Debye Solids

Free Electron Theory of a Metal

Internal Degrees of Freedom for Atoms and Diatomic Molecules

Kinetic Theory of Gases – Transport Coefficients

Kinetic Theory of Gases: Collision Dynamics and Scattering

Kinetic Theory of Gases: Effusion and Collisions

Kinetic Theory of Gases: Maxwell-Boltzmann Distribution

Kinetic Theory of Gases: Mean Free Path and Transport

Low and High-T Limits for qrot and qvib

Microcanonical Ensemble: Replace {Pi} by Ω, Q vs. Ω

Model Intermolecular Potentials

Molecular Partition Function: Replace E(assembly) by ε(molecule)

Nuclear Spin and Symmetry Number

Nuclear Spin Statistics: Symmetry Number, σ. Low Temperature Limit for Rotational Partition Function

Polyatomic Molecules: Rotation and Vibration

Q Corrected for Molecular Indistinguishability

Quantum vs. Classical. Equipartition. Internal Degrees of Freedom

Rates of Unimolecular Reactions: RRKM

Rotational Partition Function. Equipartition

Thermodynamics of Solids: Einstein And Debye Models

Transition State Theory I

Transition State Theory II

Translational Part of Boltzmann Partition Function

Virial Equation of State

1–D Linear Chain of Atoms

Course Info

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Departments

Chemistry

As Taught In

Spring 2008

Level

Undergraduate

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