5.111SC | Fall 2014 | Undergraduate

Principles of Chemical Science

Unit I: The Atom

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Unit I focuses on the building block of matter – the atom. Throughout this unit we reflect on the fundamental question of how we can understand and describe something that is too small to see. The unit starts with the amazing discovery of the electron and the nucleus and the subsequent realization that the classical laws of motion (classical mechanics) do not adequately describe the behavior of something as small as an electron, requiring the development of new laws of motion (quantum mechanics). Viewers can watch as hydrogen creates a spectrum of light waves, prompting the consideration of why only certain colors are generated and not others; i.e. why only certain energy transitions are possible. The Schrödinger equation is offered up as the key to explaining these colors as well as many other experimental findings. By the end of this unit, viewers should be able to apply the concept that there are discrete atomic energy levels and should be able to calculate binding and ionization energies for electrons. They should be able to describe wavefunctions (orbitals) and write electron configurations.

Image excerpted from Lecture 1 Notes Lecture 1: The Importance of Chemical Principles

Image excerpted from Lecture 2 Notes Lecture 2: Atomic Structure

Image excerpted from Lecture 3 Notes Lecture 3: Wave-Particle Duality of Light

Image excerpted from Lecture 4 Notes Lecture 4: Wave-Particle Duality of Matter; Schrödinger Equation

Image excerpted from Lecture 5 Notes Lecture 5: Hydrogen Atom Energy Levels

Image excerpted from Lecture 6 Notes Lecture 6: Hydrogen Atom Wavefunctions (Orbitals)

Image excerpted from Lecture 7 Notes Lecture 7: Multi-electron Atoms

Looking for something specific in this course? The Resource Index compiles links to most course resources in a single page.

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Topics

Image excerpted from Lecture 1 Notes 

  1. General Course Information and Policies
  2. Course Material Overview
  3. Introduction to the 5.111 Teaching Team

Lecture Video

Professor Cathy Drennan introduces this series of lectures about basic chemical principles. She describes her path to becoming a chemist and reveals her first impression of the discipline of chemistry. Goals for students of this material are presented as well as some examples about how real world problems can be solved through the applications of chemical principles. Teaching assistants for the course are introduced.

Lecture Notes

Notes for Lecture 1 (PDF)

Textbook Reading

This material, which is a review of fundamental chemical principles, will not be explicitly covered in class. The intent of assigning this reading is to provide a review of relevant high-school-level material.

TOPICS 5th EDITION 4th EDITION
Matter and Energy Section A.1: pp. F1–9 Section A.1: pp. F1–10
Section A.1: pp. F17–F21 Section A.1: pp. F18–21
Compounds Section C: pp. F22–28 Section C: pp. F23–28
The Nomenclature of Compounds Section D: pp. F29–36 Section D: pp. F30–36
Moles and Molar Masses Section E: pp. F37–43 Section E: pp. F38–44
Determination of Chemical Formulas Section F: pp. F45–50 Section F: pp. F46–50
Mixtures and Solutions Section G: pp. F51–58 Section G: pp. F52–59
Chemical Equations Section H: pp. F60–63 Section H: pp. F61–64
Reaction Stoichiometry Section L: pp. F85–92 Section L: pp. F85–91
Limiting Reactants Section M: pp. F95–103 Section M: pp. F93–100

Significant figures are important. Rules for scientific notation and significant figures are available in the back of our textbook in Appendix 1, pages A5-A6. You are also responsible for knowing the following SI prefixes: n (nano, 10-9), μ (micro, 10-6), m (milli, 10-3), c (centi, 10-2), and k (kilo, 103).

Problems and Solutions

Review problems to complete before continuing to lecture 2. Students are expected to know this material, which is not covered in class.

5.111 Review Problems (PDF)

Solutions for 5.111 Review Problems (PDF)

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Topics

Image excerpted from Lecture 2 Notes 

  1. Discovery of the Electron and the Nucleus
  2. The Need for Quantum Mechanics

Lecture Video

The backscattering experiment of Rutherford is recreated in the classroom setting. Ping pong balls are used to represent alpha particles and Styrofoam balls connected to a series of strings represent nuclei in a piece of gold foil.

Lecture Notes

Notes for Lecture 2 (PDF)

Clicker Questions

Lecture 2 Clicker Questions (PDF)

Textbook Reading

TOPICS 5th EDITION 4th EDITION
Force and Energy Sections A.2–A.3: pp. F9–13 Sections A.2–A.3: pp. F10–13
Elements and Atoms Sections B.1–B.2: pp. F15–17 Sections B.1–B.2: pp. F15–18
The Nuclear Atom Section 1.1: pp. 1–3 Section 1.1: pp. 1–3

Problems and Solutions

Problems for Lecture 2 (PDF)

Solutions for Lecture 2 (PDF)

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Topics

Image excerpted from Lecture 3 Notes 

  1. Light as a Wave, Characteristics of Waves
  2. Light as a Particle, The Photoelectric Effect

Lecture Video

The idea that light is both a wave and a particle is introduced. The properties of waves are described and the applications of diffraction are presented.

Lecture Notes

Notes for Lecture 3 (PDF)

Clicker Questions

Lecture 3 Clicker Questions (PDF - 1.3MB)

Textbook Reading

TOPICS 5th EDITION 4th EDITION
The Characteristics of Electromagnetic Radiation Section 1.2 – focus on pp. 10–12 Section 1.2 – focus on pp. 10–12
Radiation, Quanta, and Photons Section 1.4 – focus on pp. 10–12 Section 1.4 – focus on pp. 10–12

Exploring the Molecular World with X-Ray Diffraction

Cathy Drennan explains how she and her lab apply the principles of constructive / destructive interference, and other characteristics of light (including energy, frequency, and intensity) in their research using X-ray crystallography to determine the three-dimensional shape of proteins. Cathy’s lab captures “snapshots” of proteins in action with a focus on proteins with medical or energy/environment-related applications.

Catherine L. Drennan’s Personal Story

Cathy Drennan explains how her dyslexia, and other people’s low expectations of her because of it, have not prevented her from excelling in science and becoming a full professor at MIT. In fact, her “disability” has given her a unique set of visualization skills that allow her to better understand protein shapes and how they fit together.

Problems and Solutions

Problems for Lecture 3 (PDF)

Solutions for Lecture 3 (PDF)

Acknowledgement

Excerpt of “ROY G. BIV” by They Might Be Giants, courtesy of Idlewild / Disney Sound, used with permission. From Here Comes Science, 2009.

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Topics

Image excerpted from Lecture 4 Notes 

  1. Light as a Particle (continued)
  2. Matter as a Wave
  3. The Schrödinger Equation

Lecture Video

The idea that matter (and thus an electron) has both particle-like and wave-like properties is introduced, and chemist Darcy Wanger Grinolds introduces us to quantum dot technology. We also start to consider the impact that the Schrödinger equation had on our understanding of the atom.

Lecture Notes

Notes for Lecture 4 (PDF)

Clicker Questions

Lecture 4 Clicker Questions (PDF)

Textbook Reading

TOPICS 5th EDITION 4th EDITION
The Wave-Particle Duality of Matter Section 1.5 Section 1.5
The Uncertainty Principle Section 1.6 Section 1.6

Labeling Tumors With Quantum Dots 

Quantum dots are tiny semiconductor crystals with vivid colors that can be used as visual labels in biology and medicine. Quantum dots excited by UV radiation emit light with an energy and color that is determined by the size of the quantum dot. Darcy Wanger describes how the characteristics of atomic energy levels relate to the color of quantum dots, and how quantum dots may someday be used as markers in surgical procedures.

Darcy Wanger’s Personal Story 

Darcy Wanger describes her realization that science is not something “done—in the past tense” by people long ago, but rather an exciting pursuit that requires social interactions to solve current real-world questions.

Problems and Solutions

Problems for Lecture 4 (PDF)

Solutions for Lecture 4 (PDF)

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Topics

Image excerpted from Lecture 5 Notes 

  1. Binding Energies of the Electron to the Nucleus for a Hydrogen Atom
  2. Verification of Hydrogen-Atom Energy Levels
    1. Photon Emission
    2. Photon Absorption

Lecture Video

In this lecture, we look at the visible spectrum produced by the hydrogen atom. A series of lines of different colors appear and we consider why the hydrogen atom produces this particular spectrum.

Lecture Notes

Notes for Lecture 5 (PDF)

Clicker Questions

Lecture 5 Clicker Questions (PDF)

Textbook Reading

TOPICS 5th EDITION 4th EDITION
Atomic Spectra Section 1.3 Section 1.3
Wavefunctions and Energy Levels Section 1.7 up to equation 9b Section 1.7 up to equation 9b
The Principle Quantum Number Section 1.8 Section 1.8

Problems and Solutions

Problems for Lecture 5 (PDF)

Solutions for Lecture 5 (PDF)

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Topics

Image excerpted from Lecture 6 Notes 

  1. Wavefunctions (Orbitals) for the Hydrogen Atom
  2. Shape and Size of S and P Orbitals
  3. Electron Spin and the Pauli Exclusion Principle

Lecture Video

Where is that electron anyway? In this lecture, the probability of finding an electron at a particular distance from the nucleus is discussed. The concept of wavefunctions (orbitals) is introduced, and applications of electron spin are described. In particular, chemist Ben Ofori-Okai introduces us to the wonders of magnetic resonance imaging, also known as MRIs.

Lecture Notes

Notes for Lecture 6 (PDF)

Clicker Questions

Lecture 6 Clicker Questions (PDF)

Textbook Reading

TOPICS 5th EDITION 4th EDITION
Atomic Orbitals Section 1.9 Section 1.9
Electron Spin Section 1.10 Section 1.10
The Electronic Structure of Hydrogen Section 1.11 Section 1.11

Imaging Viruses With Nanoscale MRI

Ben Ofori-Okai discusses the concept of orbital degeneracy (two orbitals with the same energy) in relation to his research on nanoscale MRI (magnetic resonance imaging). Specifically, he explains how energy level differences detected with nanoscale MRI can lead to the generation of three-dimensional images of biological molecules, such as proteins and viruses.

Benjamin Ofori-Okai’s Personal Story

Ben Ofori-Okai describes his realization that his love of problem-solving in math class could have an application in chemistry research. He urges anyone intimidated by science to give it another shot because it can be a lot of fun.

Problems and Solutions

Problems for Lecture 6 (PDF)

Solutions for Lecture 6 (PDF)

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Topics

Image excerpted from Lecture 7 Notes 

  1. Wavefunctions and Binding Energies for Multi-electron Atoms
  2. Electron Configurations

Lecture Video

After focusing on the hydrogen atom for several lectures, the course moves on to consider atoms with more than one electron. Now, the pull of the positively charged nucleus on the negatively charged electron is harder to predict as shielding comes into play. Also, we try our hand at electron configurations.

Lecture Notes

Notes for Lecture 7 (PDF)

Clicker Questions

Lecture 7 Clicker Questions (PDF)

Textbook Reading

TOPICS 5th EDITION 4th EDITION
Orbital Energies (of Many-electron Atoms) Section 1.12 Section 1.12
The Building-Up Principle Section 1.13 Section 1.13

Problems and Solutions

Problems for Lecture 7 (PDF)

Solutions for Lecture 7 (PDF)

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